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1、Electron-VibronCouplinginChargedFullerene,BerryPhase,andSuperconductivityNicolaManini23January1996AcknowledgmentsThisthesiswasbornastheresultofmanyexcitingcollaborations.AssaAuerbach,ErioTosatti,andSebDoniachsuggestedintherstplacethatBerryphasesshouldbeimp
2、ortantinfullerene.AlbertoParola,GiuseppeSantoro,MarcoAiroldi,MicheleFabrizio,PaoloDeLosRios,andSandroSorellagavecrucialcontributions.Iwouldsaythatthisthesisisatleastastheirsasmine.IacknowledgeusefuldiscussionalsowithFrancoIachello,GanpathyMurthy,GeorgeSawat
3、zky,LuYu,SandroSorella,andStefanoOss.Erio,however,deservesdoublethanking.First,regardingthisthesisitself:alargefrac-tionofideas(andmostgoodphysicalideas)herecameoutinRoom256-SISSA,andsome-timesevenathishome,sharingabottleofgoodwine.However,IfeelIshouldthank
4、Eriomostlyforcommunicatingtomethepleasureandfunofdoingphysics,thecuriosityforthenewsinthephysicsofmatter,oftenunrelatedtotheCstory.Heisagreatteacherand60averygoodfriend.Thisthesisistoolongalready:I'lltrytokeepatleastthankingshort.Iwishtothankallthefriendsan
5、dstainSISSA,andthoseinTrento.JoeandErioknowhowmuchIappreciatetheirproofreading.AspecialthankisformyroommatesAlbertoDebernardi,andespeciallyforFranzDiTolla,whomanagedtoputupwithmyself,theselastthreeyearsinTrieste.MywifeandkidMariaandDavidearealsotobethanked
6、fortheirpatience.Thisworktookawayalotofthetimeandcareofminetheydeserved.Finally,IwishtothankmyparentsMirellaandDinoforanon-numerablesetofreasons,includinggoodtiminginputtingmearound:nottoolate,sothattherearestillniceandfeasibleproblemsinphysics(andpeoplewho
7、care),andnottooearlysince,withouttheRISCcomputersaround,asignicantfractionoftheresultswouldhavebenmuchhardertond,ifnotpurespeculation.TableofContentsAcknowledgments:::::::::::::::::::::::::::::::::1TableofContents31Electron-vibroncouplingandBerryPhase:abr
8、iefintroduction71.0.1WorkPlan::::::::::::::::::::::::::::::::81.1DynamicJahn-Tellereectinmolecularsystems:::::::::::::::91.2Berry'sgeometricalphase::::::::::::::::::::::::::::111.3BerryphaseinJahn-Tel