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1、SpectrochimicaActaPartA:MolecularandBiomolecularSpectroscopy164(2016)110–122ContentslistsavailableatScienceDirectSpectrochimicaActaPartA:MolecularandBiomolecularSpectroscopyjournalhomepage:www.elsevier.com/locate/saaReviewarticleLorenzoLotto'spaintingmaterials:anintegrateddiagnosticappro
2、acha,⁎,GianlucaPoldibacddMariaLetiziaAmadori,SaraBarcelli,PietroBaraldi,MichelaBerzioli,AntonellaCasoli,efbSusannaMarras,GiulioPojana,GiovanniC.F.VillaaDepartmentofBasicSciencesandFundamentals,UniversityofUrbino,p.zaRinascimento6,Urbino,ItalybVisualArtCentre,UniversityofBergamo,viaPignol
3、o123,Bergamo,ItalycDepartmentofChemicalandGeologicalSciences,UniversityofModenaandReggioEmilia,viaCampi183,Modena,ItalydDepartmentofChemistry,ParcoAreadelleScienze17/a,Parma,ItalyeDepartmentofMolecularSciencesandNanosystems,UniversityofVenice,Dorsoduro2137,Venice,ItalyfDepartmentofPhilos
4、ophyandCulturalHeritage,UniversityofVenice,Dorsoduro3484/D,Venice,ItalyarticleinfoabstractArticlehistory:Thispaperpresentstheresultsofacomprehensivediagnosticinvestigationcarriedoutonfivepaintings(threeReceived5November2015woodpanelsandtwopaintingsoncanvas)byLorenzoLotto,oneofthemostsigni
5、ficantartistsoftheItalianRe-Receivedinrevisedform13February2016naissanceinthefirsthalfof16thcentury.Thepaintingsconsideredbelongto1508–1522period,correspondingAccepted28February2016tothemostsignificantyearsofLotto'sevolution.Awidearrayofnon-invasive(reflectancespectrometryandX-Availableonlin
6、e31March2016rayfluorescence)andmicro-invasiveanalyticaltechniques(opticalmicroscopy,scanningelectronmicroscopywithenergydispersivespectroscopy,micro-FTIRspectroscopy,micro-Ramanspectroscopy,gaschromatographyKeywords:Pigmentscoupledwithmassspectrometryandhighperformanceliquidchromatography
7、coupledwithphotodiodearrayPaintingtechniquedetectionandmassspectrometry)wereappliedinordertoprovidealargesetofsignificantdata,limitingasOrganicbindersmuchaspossiblethesampling.ThisstudyhasprovedthatLotto'spaintingpalettewastypicalofVenetianprac-ED-XRFticeofthatperiod,butso