浙江省杭州市七县市2022年高三一诊考试化学试卷含解析

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2021-2022ὃᓄᔁὃ1.ᐰᔁᑖ⌱⚪⌱⚪ᑖᐰᙠ⚪஺⌱⚪ᵨ2B!"⌱⚪Ḅᫀᵨ%⁐'(Ḅ)ᡈ'ᑏᙠ“⚪”./01஺2.2ᵨ%⁐'(Ḅ)ᡈ'ᙠ“⚪”ᐜᑏ456ὃ78஺3.9ᢝᓱ☢=>?⌕ᢚB?⌕CẚஹCFᙠ₝Hஹ⚪ᔁ⚪Iᦔ஺Kஹ⌱⚪LᐳᒹO22PQ⚪஺RQ⚪ᙳTᨵKPVᔠ⚪XḄ⌱⚗Z1ஹ[₝⏚]᪀_`᝞bᨵᐵdefgḄhAOHHOiCOOHOH[₝⏚A.ᑖklmᨵ2nopqB.Imol[₝⏚rNas/ᨬuᡂ4moiwxC.yrz⏣ஹz⏚s/|s/}~.D.yḄᓄஹ⏚ឋ═⏚⁐|ᳮ.2ஹᔣmᨵ5Xlf3moiHIO3rḄlᐭH2S,|ᨵS᪆ᐭH2S,Ḅ⁐ᑣᙠ᦮PlLZA.ᐳᑮ0.96g¡B.ᐭH2sḄ¢£¤336mLC.¡ᐗ¦ᐜ§¨©§ªᓄD.«¬ᵯk®ᦪ¤3.0X10-2ᑘ3ஹ±²ᐗ³´BOH
2Ki=5.9X32ஹK2=6.4Xlf5
஺ᔣ10mLµBOH
2l¶·¸¹º»⏚BOH
2ஹBOH
*ஹB”Ḅ¹ºᑖᦪ§½pOH[pOH-lgcOHZ]ᓄḄᐵ¿᝞bÀÁdefgḄhA.ÂÃaᜐÅ/·ᐭḄ»⏚Ḅ¢£¤5mLB.Æ·ᐭḄ»⏚Ḅ¢£¤10mLÇÈᙠcCr
cBOH
+
cH*
cOK
cB2+
C.ÂÃbᜐcOH
=6.4X1
FD,Æ·ᐭḄ»⏚Ḅ¢£¤15mLÇÈᙠcCÉZ+cOlT
cH*
cOH-
cB*
+cBOH
*Z+cOO4ஹÁᑡᵯÍÎÇ02ᙠf᩽ÐᵯḄhLZ

11Ni-Cd»wo<■1z1...........................A.Ñ═ᵯÍB.wÒᧇᵯÍC.ÔᵯÍD.Õ╍ᵯÍA.AB.BC.CD.D5ஹᓄs/שØÙÚᨵᓄḄhজkᦪÜঝᑖkᦪÜঞᐗ¦n}টᱥáḄ®áঠᱥáḄn}A.জটB.জঞঠC.জঞটD.জঝঞট6ஹÁbhãäᑴ´eᙠæçèéêæçḄëìíXbᑣÁᑡîïfgḄhLZA.ðIIñḄòkó`¤Na++NH3+H2O+CO->NaHCOi+NH+234B.ðDIñᑮḄᨔ¢hNa2cO3TOH2OC.Ax¢hCO2,Bx¢hNHbD.ðWñõḄö⌕ᨵ÷ஹøùஹ]ᨔ7ஹúᔍüýᡃḄÿ
ᙠஹஹஹὶ☢ḄḄᡂᓄ"ᨵḼ%ᑗὶ'஺)ᑡ+,-.Ḅ/02A.“45ᓝ78”:;<>?‧᜜⊤☢CᵨḄEFG᪀◌JḄK⌕ᡂᑖ/ấ⏚PB.QRSᜧ᫑CᵨEឋWXYZ[■ῖ^_Ḅ/᜜`ᵯbḄ▢᩽ef,C.ᡃhijkᡊᶍᐝopqrstuvᓟxyzᐝoḄK⌕ᡂᑖ/ᨔ|ấD.ᓄ"ᩞᧇᙠᓅᜧᐶḄᢵᜧᵨᐸEkὊῖ⇨ᩞᧇ8ஹ¡¢╅¤ᔠ¦0§¨ᐸᐗª2╅Ḅᑖᦪ஺¬"®᝞):ag╅¤ᔠ¦¼½Æᙠ᝞Çᡠ±²Ḅ³ឋᵯ´µ¶ᵯCᐸᐙᑖ¸¹஺)ᑡ+,┯»Ḅ/■■■ik1kᔠ¦¼½--¿ឋᵯÀµ------ÁÁὊEFEÂḄ%ÃÄᘤA.Gᒕ|Ḅ

2B.ÉÁ⌕eÊᐙËC.ÌÍᵨÁÎÏÉÁÐÑD.G|ᜧag9ஹᓄᔠᱥQX
ஹOXY
ஹFz
ḄᑖÓÔᙳCH)ᑡ+,-.Ḅ/
56OA.XஹYஹZᙳWC⏚ឋE═⏚×ØÙÚ⁐B.ZḄᑖÜ᪀|ÝᨵXÞßàáC.ZḄâãÎᱥÝᨵàá0§ὃ⇋æ|Ü᪀2D.ßᑖÓᡠᨵçèÓᙳᜐ7ê☢10ஹNA⊤ëì`íîïᦪḄð)ᑡ+,-.Ḅ/02A.25࠷,pH=lḄH2sØÙH+Ḅᦪ0.2NAB.ïFïÂ)56gñòóôõḄöᔠÁ|¨ᨵ4NA÷çèÓC.᪗ùúû)1L2LCHC13¨ᨵḄèÓᦪ2.5NAD.ïF)Imolüý⏚ËAlþÿᵯᦪ3NA11ஹ,0.1000molLrḄ⏚⌲ᐭᑮ20.00mLO.lOOOmol-L-1Ḅ,ḄpHpOH:pOH=-lgcOHᡠ⏚Ḅᐵ᝞"ᡠ#$ᑡ&'()*Ḅ+,-A."a+b=14B./0J012ḄVHC1
=20.00mLC.0AஹBஹCஹD30Ḅᙳ5ᙠ᝞ᐵ7cCr
-cNH4+
=cH+
-cOH-
D.8ᙠ9:;<=>?2$"Ḅ/0JᔣA12ஹBCDEFGHIᱥKᩩM7“C$O(PQR'$ᐗTᓭVᨵXYὅ[\]$[^_`$abc]d$eO⍒ᦔh஺”ᦻ“QR'”ḄlᳮᑡnoḄ+,-A.pឋrsB.ᵨudvudwᱥC.◀aKNChḄNaClD.◀ayRz13ஹᨵBn{Ḅᓄ}?2~(A.ᑖ?2B.ᣚ?2C.?2D.ᡂ?214ஹ᝞"ᡠ#$ᙠ~Ḅᴻᔜ~$ᵨᘤoTᙠᐭ〉Ḅ⏚$ᑡ&'()*Ḅ+

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3ஹSiO2Â-ᑴᜓÅÆÇ⏚È[A12SO4
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2ᑡ&'┯ÖḄ+A.ÔÓIஹ□Ḅ¿⌕ᡂᑖᑖØSiOzஹCaS04B.8¯pHÙ4,ᑣÛÜÝÈᐗÞḄÁßàC.ᔾᦈÊËeḄÁᨵḄãä5åD.æᐰ:ᑖ®ḄS02ÂᔾᦈḄSO?16ஹ1᣸éᙠ2sê⍝=Ḅᵯ$(Û*Ḅ+A.ᵯᡠᙠḄᵯìB.ᵯḄíîïᔣC.ᵯðḄñòD.ᵯðḄóôïᔣ17ஹᑡõᓄÍÎö÷ᐳùúḄ+,-A.ûüᓄấᰚᓄB.ÿᓄC.ᓄᰚᓄD.Ớᓣ18ஹᑡḄB.Ḅ᪀CH2=CH2C.NH3Ḅᵯ"#$N%ᵯ%&D.'()*Ḅ+⌮'(-◤/*0'("ᓣ1"'(2᳛4519ஹ᝞789╅;ᓴ=ᓫ&X?'(Ḅ@AᓄBC7஺ᑡḄEF

4-364MgHs)•oa,-524MqBri(s).sy641MgCh(s)w<1124MgF(s)A.ᵫMgCLᑴIMg)*JKB.*LMឋOMgl2>MgBr2>MgCh>MgF2C.P1QᓄឋOF2

5A.□᩽ᑮH2sO4B.□᩽'(Mn2-2e+2HO=MnO2+4H2C.ᣚ□ᣚD.ᵯᨵ2moie"ᡂ55gMnஹ\⌱⚪(ᐳ84ᑖ)23ஹ(14ᑖ)ᓄᔠᱥᵬᵫᐗ=ᡂ஺¡ᓄUẆ£¤ᢥ᝞7¦K§£ᐸᡂ:ªR^;h«Wᑖ&@«¬ḄP_®"ᐸh¯_Ḅ°⌕ᡂᑖ²஺³´µᑡ¶⚪O(1)ᵬḄᓄU஺(2)ᵬ·ᰦ¹'(ḄᓄUVK.(3)ªRᓄᔠᱥᵬ"ᨵ»ᐗ=Ḅᓄᔠ¼ᨬ¾¼"¿»ᐗ=Ḅᓄᔠ¼ᨬ5À¼"ᑣᰦ¹'(ÁQᓄḄᐗ=TÂ~ÃᱥḄᱥ&Ḅ@²Ä.24ஹ(12ᑖ)AÅmᨵCஹHஹOÆᐗ=ḄÇ✏ÉÊᱥ"ËÌÍzÅᨵ»ÎIÏÐ஺ᔜᱥ&ÒḄ«ÓᓄᐵÕ᝞7ᡠB஺Ö×ØHSO24HªRODsJ/Ù'(ᑮE,Eᑖ(C9H8Ch)nHᑖCi8Hl6஺6I◀mᨵÎÌÍ᜜ÂmᨵÎÜᐗÍ஺(1)ᑏÞAḄᑖOA0

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7,ᓄᔠ°氢.单,酸,盐,化质物প²³´µᵨNH4a0Ca(OH)2ᑴ+¶[MḄᓄ஺ফᑡ¸ᑺ:/ᵨ¹ºNHḄO.3A.»`⏚B.½¾ᮞC.NaOHÀ%(3)PÁN%ஹÂ[ஹ7Ãᧇ3ÅÆ⏚ᑖÇÈজNH3-NOḄᓄ.ঝNOTNOZḄ²³ÉÊO஺ঞNO2+H2OTHNO3Beᓄᑺ0ÃᑺᱥËḄZÌÍ»(4)¨1B²³´&ᵨC@ᱥËdNOÎϬᓄÆ⏚iÐ⁐ÑÒᑣMᱥËḄᓄoমÔ⌕dNH3-N2,ÖÃᳮØᑡ¸ᑺWÙḄO஺A.02B.NaC.NH4CID.NO227ஹ(12ᑖ)ᵞ¶⏚ÛÜ(H2NCH2COO)2FeOC@Ý⊡Üᑺ஺ßᓄàáâᵨ᝞¨ᡠå(ᜳᢝèᘤḕᶍ)ᑴᜓᵞ¶⏚ÛÜ஺ᨵᐵᱥËឋË᝞⊤ᡠå:᧕E7ñEò⏣ஹôõ⏚ᙠôõ⏚öE8÷ᜧᵞ¶⏚(H2NCH2COOH)ᙠò⏣BḄE8÷஺ùú⏚᧕E7Sò⏣⏚ឋûüᨵüÃឋ஺ᵞ¶⏚ÛÜ᧕E7ýEò⏣ஹôõ⏚஺²³Èï᝞:

8I.ᡭíKiஹK,ᔣcsᐭ_®"ïMc¯_Á᣸ñ"òb/ᐭᑮc஺3H.ᙠ50࠷ឤ1ᩩöᵨ÷øᤅúᘤ-üᤅú"ᯠᔣcþ/NaOH"ÿ
pH5.5ᱥᐙᑖ஺.ᡂᔣcᔠ
ᐭ⏣ᡂ⁐!"#ஹ%&'()*!()*+ᓄ'-*஺./0ᑡ2⚪415ᘤbḄ89:dḄ;ᵨ:=஺2>?I!b
ᐭᑮcḄA;:_>?IIBC⁚
pHEFᑣᡠ'()*IᨵᩖL_NᑏᓄPQR஺3cᡂᵞT⏚VWḄᓄPXYQ:40ᑡᐵ[\]^Ḅ_`┯bḄ:=NcᑏdeR஺a.>?IfᵫdhiᑈklmḄn᠒ᩭᑨrstḄul:ᔲ᣸xb.ᔠ
ᐭyz⏚Ḅ;ᵨ:■|Fe2+}~ᓄc.>?IIIᐭ⏣Ḅ;ᵨ:ᵞT⏚VWḄd.>?m%&ᵨ;%&ᑺ5ᵨF⏚ᙠᵞT⏚ḄX`)*ḄᵞT⏚Ḅ஺]^!ᡠ'()*ḄᵞT⏚ᑖkᩭᵨ[4_஺28ஹ14ᑖRᜩlḄk¡¢£⌼ᡂ¥᩽ᜧḄᓻ©஺Ẇ«N஺¬ஹSO,COᜧl®¯lḄᜐᳮᐹᨵ³2⌕µ¶஺1ᑭᵨ¸¹º»`fῃ◀¾lḄSO?஺জᙠ¸¹º»`Na?SO3
;Àᔾᦈ
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ᔾᦈSO?Ḅ"YpHÆ஻NSO:஻NHSOJÈᓄᐵ᝞0⊤491:91:19:91PH8.27.26.2ᵫ⊤ᑨrNaHSOs
Ë_____ឋNc“⏚”ஹ“¹”ᡈ“”RᵨᓄPÐ⊝ÒᳮÓ4ঞÕᔾᦈ
ḄpHÖÀ6◤〈ᵯÚÛ஺ÛܵÝ᝞0:

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:4ᑏkHSOᙠ□᩽æᵯḄᵯ᩽Q4,Õ▢᩽é
pHᓣ8ëᔾᦈ
Û캻ᑭᵨ஺(2)ᵨCH,íᓄîÒNO,fëï◀ð~ᓄᱥḄ®¯஺ñ᝞4CH+4NO(g)=4NO(g)+CO(g)+2HO(g)AH=-574kJ.moE14222CH(g)+4NO(g)=2N(g)+CO(g)+2HO(g)AW=-1160kJmor'4222Bᵨ᪗óôõ04.48LCH,îÒNO2N2,᦮÷"YøùḄᵯÄúᦪÀ(ýþÿ
ᦪḄᵨN4⊤)ḄkJ»(3)ᔠᡂᡠ◤ḄᑴᜓᐸḄ!"#$CO(g)+HO(g)^^CO(g)+H(g)M<0222%ᩩ'()CO(g)*H?O(g)+,-.1:2/0123ᘤ567"#8ᑮ:⊝<=>CO(g)*H2O(g),-.16,ᑣ:⊝
ᦪK=0029ஹ(10ᑖ)BCDEF⌕ḄᨵIᓄKᧇ஺ᑭᵨBCᔠᡂOPQOHC(CH2)4CHORST6(ᓝHN(C“)5V)ḄᔠᡂWX᝞Z:OHOH\]$জV1Y1f,*+-d-fgஹh/Vঝn+NHOH-»-C=N-0H+HO22ij(ᑡl⚪$(1)ᵫAᑴoBḄ"#pqCḄrstu.

102
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᪆௃A.³₝⏚ᑖ~-COOHஹ-OHஹ¶¶·¸E¹º»⌱⚗A┯½¾B.³₝⏚ᑖ~º*¿"#Ḅ¹º»ÀÁRÂÁÃ111moi³₝⏚*Na"#ᨬÅ6ᡂ2moi⌱⚗B┯½¾C.³₝⏚ᑖ~ᨵḄÂÁஹÀÁºᑖÆ*⏣ஹ⏚56Èᓄ"#"#pqÉ⌱⚗CÊ˾D.³₝⏚ᑖ~ᨵ¶¶·¸Ì*Í56Îᡂ"#*Ï═⏚Ñ56Òᓄ"#⌱⚗D┯½஺jᫀ⌱C஺2ஹDூ
᪆௃A.HKh*ÓÔÕḄÖᐭH2S,HIO3ᐹᨵÒᓄឋº)ÚᓄÒᓄᨬÛ6ᡂÚᓫÜRHI,᪷Þᵯ~àឤஹK~àឤ>ᑮHIO33H2s3S,ᡠ+5X10-3moiHK
3âãὑåæ>ᑮÚᓫÜD0.48g,ᦑA┯½¾B.èᨵᢣê᪗ìíî£ïðñᡠ◤H2sḄ,-ᦑB┯½¾C.òDHICh*H2s"#óDỚᓫÜ*H2s"#H2sõâÒᓄᦑC┯½¾D.᦮¬᪷Þᵯ~àឤஹK~àឤ>ᑮHIO33H2s3s÷ø÷6øãὑ5XlOfmoiHKhùú0.03molᵯ~ûüûüᵯ~ýᦪ3.0X1
-2NA,ᦑDÊ˾ᦑ⌱D஺3ஹC

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13C.zᨵ1oH,ᑣwᱥᨵ1o(Ḅ6ᱥqrᙠwqrfᙠḄqrfᐳ2oᦑCAB"D.y3sp3ᩖᓄḄqr¡3qr¢£☢¥᪀Ḅ§ᑣᡠᨵqrᐳ8☢ᦑD┯!"ᦑhᫀC10ஹBூ
᪆௃A.¨©ª«¬\rᦪsᦑA┯!"B.®¯°±Ḅᨬ³´ᙳCH2,ᦑ56gFᔠᱥ4moic¶qr·ᦑ4NAqrᦑBAB"C.᪗¹º»¼CHChTᵨ_᥅¿«¬ᱥEḄᦑC┯!"D.ÀÁ¼Â:Ã⏚y)ÄᓄÅᐰ'(©ª«¬ÇÈḄᵯrᦪᦑD┯!"hᫀ⌱Bூ0Ê௃⚪Ḅ᧕┯0D,⌕ÎÏÀÁ¼ÐஹÂ⍗ᑮ:Ó⏚ᡈ:Ã⏚y)Äᓄ'(ÕÖ×Ø஺11ஹBூ
᪆௃A.ÙA0B0(ḄE5᪷za=-lgc(H+),b=-Igc(OH-),c(H+)c(OH-)=1(Û4«¬+b=-lgc(Ha+>c(OH-)=—lgl0-14=14,A⚗AB"B./0J0(Ḅ0pH=7,(ÜTᓄÝḄFᔠV(HC1)V20.00mL,B⚗┯!"C.AஹBஹCஹD£0ḄᙳMᙠᵯ₹Kឤc(Cr)+c(OH_)=c(NH+)+c(H+),u´Þc(C<)wc(NH4+)=c(H+)4-c(OH-),C⚗AB"D.'(àá'(âᙠãáäy)fg'(äḄÁ;ᓣæḄᵯç;èuᜧc(OJT)êᜧ,pOHëìpHêᜧÙḄ/0JᔣîÈD⚗AB"hᫀ⌱B஺12ஹAூ
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᪆௃ᐹᨵᓄឋᨵḄᓄᨵḄஹᡂᑣ"#$ᑖ&'(ᩭ&*ᓽ஺ூ
௃A.$ᑖ&,-./ᨵᐗ1Ḅᓄᔠ34ᓄ5ᨵᐗ1Ḅᓄᔠ34ᓄᑣ"#$ᑖ&A6ᔠ⚪89

14B.ᓫ<=KI>ᣚ@Ớᓫ2°´,µALISON,ᐭ·⏚┛ª¹º»⁚pH=3.6,CaCCh+H2SO4=CaSO4+CO2T+H2O,½CaSO4¾¿ᦑ°±IIḄᡂᑖCaSCh,A⚗z{9B.pH»4,¿´,ᨵÀᑖḄÁÂ|=t᪷Â|ᡂtᓄÁÃÄ#ÅÆ¿´,Áᐗ1ḄµÇÈB⚗z{9C.ᔾᦈ´,S˵ᨵH+ஹAI3\OH-ஹSO?-,ᔾᦈSO'ºᡂSO32-,ÀᑖSCV-&ᡂHSO3-,¿2´,µᨵḄÂ|ÌÍ5ÎC⚗z{9D.SO2ÏᔾᦈºᡂSO32-,SO3?-"Ð.ÏÑ[ᓄSO42-,½(Òᐰᑖ&ḄS()2ÔÍᔾᦈḄSC>2,D⚗┯Ö9*ᫀ⌱D஺16ஹB

15ூ
᪆௃᣸Øᙠ2sÙ⍝ÛḄᵯ|ᑣ'ᑨÞᐸᙠàKᵯ|áS#âᵯ|ãḄäåᳫäᡠ'ᵯ|ãèéê¢ᔣì"#{.ᵯ|Ḅíî¢ᔣᦑ⌱B஺ூPQ௃ï{SÙ⍝Ḅäåஹ'Wèéê¢ᔣN&⚪ᐵ`᣸Øᙠ2sÙ⍝ÛḄᵯ|ᑣ'ᑨÞᐸᙠàKᵯ|áS#âᵯ|ãḄäåᳫäᡠ'ᵯ|ãèéê¢ᔣì"#{.ᵯ|Ḅíî¢ᔣ¡(ᑖ᪆஺17ஹAூ
᪆௃|ᨔuᰚᓄòóᐳ3`Â|ᨔuᰚᓄᡈᵯÂᙳòóÂ|`ᑖ|ᨔu÷᝱4ᓄùẚûᑖ|ü]ᵨýþᵯ&<¿Í"ᵯÂᑣ"ẚûᓄV`'(ᩭ&*஺ூ
௃AஹKᓄấ
ᨔᰚᓄᐳ⌱⚗ABஹᓄḄᑖᵨ⌱⚗B┯Cஹᓄᰚᓄ⌱⚗C┯DஹỚᓣ"Ḅᑖᵨ⌱⚗D┯#ᫀ⌱A஺18ஹBூ
᪆௃A.&
2&Ḅ'ᦪ)8,ᦑ+᪀-./)ট
AB.12Ḅ+᪀34)CH2=CH2,BC.NH35678Ḅ59:;ᵯ=)ᐸ?7@ABᡂN%•%O,ᡠE:;ᵯNH3FᵯG'C┯D.@AIJḄK⌮@AMK:◤⌕PJQ:RBᓣSTU⌮@AV᳛ᙳPYD┯ᦑ#ᫀ⌱B஺19ஹDூ
᪆௃AஹZ[/\ᑖ᪆ᑨ_Mg?CLḄ:`S6MgCb,Z[:`aឤᑨ_ᡠEᵫMgCbᑴeMgᔾJ@AA┯Bஹᱥ'Ḅ:`hihjk᪷[/mᦪ[ᑖ᪆ᓄᔠᱥḄJjkឋpq)rMgl2C12>Br2>l2,C┯2

16DஹZ[/\Mg(s)+C1(I)=MgCh(s)AH=-641kJ/mol,Mg(s)+Br(1)=MgBr(s)AH=-524kJ/mol,uv222&wxy4z{v|xy4}MgBn(s)+CI2(g)=MgCh(s)+Br(g)AH=-117KJ/moLD2#ᫀ⌱D஺20ஹAூG᪆௃MnO2A.ᵬH2O2,ᙠMn(hᓄᑺᩩRB@A2H2O2^=2H2O+C)2TBᡂ02,ᦑAB.1⏚ᐹᨵᢵRឋK:RBḄ@Aᨵ2HCl+Na2SiO3=2NaCl+H2SiO3,ᦑB┯C.ᑖ9ᧅᙊ¡ᘤ£K:¤¥9☢§9☢a£K:¨ᢝ£ªᦑC┯D.«ᔠ¬AkSi?NaOH59@ABᡂH,᪷[¤®¯°±²ᔠ¬MgḄ³`=)AkSi´:?NaOH259@ABᡂH2,2Al+2NaOH+2HO=2NaAlO2+3H2T,Si+2NaOH+H2O=Na2SiO3+2Hf,ᦑD┯22#ᫀ⌱A஺ூµ¶௃╅ấ´KE¹tᓄºRB@A»I¤¹஺21ஹBூG᪆௃H2sᐹᨵ¼
ឋ:½¾tᓄᑺtᓄH2sḄ759ᕈ⏚ឋ:ÀRB@AEÁG#Â⚪஺ூÄG௃A.RB2112s+O2=S[+2H20@A59ᵫ⏚ឋª)ឋᡠE⏚ឋzÅᦑA┯B.RB2H2S+C12=S1+2HC1@A59⏚ឋƾᦑBC.RB2H2S+SO2=3S1+2H20@A59ᵫ⏚ឋª)ឋᑣ59Ḅ⏚ឋzÅᦑC┯D.Pᐭ¹tᓄº59BᡂÉᓄº59Ḅ⏚ឋzÅᦑD┯ᦑ#ᫀ⌱B஺22ஹCூG᪆௃᪷[/-£┤Ëᵯ᩽)▢᩽▢᩽ÎRB¼
@AᵯG'59□}ᵯᵯ᩽@A)rMn2++2e=MnÐÑᵯ᩽)□᩽Ðᜫ{ᵯÓᓄ)|tᓄÐᵯ᩽@A)rMn2+-2e+2H2O=MnO+4H\[ÁG⚪஺2ூÄG௃A.᪷[ᑖ᪆▢᩽ᵯ᩽@A)rMn2++2e=Mn,□᩽ᵯ᩽@A)rMnr-2e+2HO=MnO2+4H\▢᩽ÔḄSCh?&ÕÖ2×ᣚÙÚᐭ□᩽Ô=Á□᩽ÎᨵMnCh᪆¤□᩽Ô}ᑮH2so4,ᦑA

17B.᪷[ᑖ᪆□᩽@A4)Mn2+-2e*2H2O=MnO2+4lT,ᦑBC.ᵫA⚗ᑖ᪆▢᩽ÔḄSth?-ÕÖ×ᣚÙÚᐭ□᩽Ôᑣ×ᣚÙ)▢×ᣚÙᦑC┯D.▢᩽ᵯ᩽@A)rMn2*+2e-=Mn,ÝᵯÞᨵ2moi/Óßà▢᩽BᡂImolMn,ᐸ'`)ImolX55g/mol=55g,ᦑD#ᫀ⌱C஺ூµ¶௃á⚪᧕┯µC⌱⚗ᑨ_É⏚᪷Ḅßãxᔣ▢᩽□zå;æ┯ᑨ_çè)▢᩽◤⌕⊡ᐙ□□᩽ëBḄ¹ᦪìíÉ⏚᪷Aᔣ□᩽ßã஺|ஹF⌱î⚪(ᐳ84ᑖ)23ஹAgOCN2AgOCN=2Ag+Nf+2COt122ூG᪆௃ñò«óᑖ'`ôḄõöᐸ«÷Ḅø⌕ᡂᑖù&ᵫÁKò«ú&tᓄû஺᪷[üy/KòúḄᱥ'Ḅ`)O.Olmol,&tᓄûḄᱥ'Ḅ`)n(CO)=ýþ*᜜⌨=0.02mol,ᵫᵬCஹNஹOḄᦪ1:1:1,ᓄᔠᱥᵫᐗᡂᓄᔠᱥᨵᐗḄᓄᔠᨬ!"ᐗḄᓄᔠᨬ#$%&ᵬ'᧕)*ᰦ,*ᡂ-ᱥ.ᑣᵬ01ᨵ234ᐗ5ᵬḄᓄ6721Vf+84xxR(CNO)x,RḄ89.:M,᪷<=02R(CNO)x=2R+2xCO+xN,ᨵ^-------=——ᡠAM=108x,230.015x=L2,3,……Cx=lDM=108,REᐗCxF2ஹ3……DGᨵ90Ḅ34ᐗḄ89.:Hᔠ⌕JᡠAᵬAgOCN஺ூMN௃(1)ᵫᑖ᪆ᵬḄᓄ67AgOCN,ᦑSᫀUAgOCN(2)ᵫᑖ᪆VEᓫ.,Y2Zᓄ[\]^,ᑣᵬ)*ᰦ,=0Ḅᓄ6_`72AgOCN=2Ag+N2T+2COf,ᦑSᫀU2AgOCN=2Ag+Nt+2COt;2(3)᪷<ᰦ,=0_`7ᰦ,=0aZᓄḄᐗ]ᐗᐳ2moLcdᱥEᓫ.e2Zᓄ[ᐳ4mol,ᑣᰦ,=0aZᓄḄᐗfcdᱥḄᱥ.Ḅ:g12,ᦑSᫀU12஺YZ-fCH-CHiji24>C9H10O3/CH,h-COOHFi=0(ᡈlᓄ=0)@

18OH+CHCHCOONa+2H2O32ூ
᪆௃Ar)*stḄZᓄ=0uvw᪀yᨵ-CH2OH,Dz{|}=0~ᑮE,Eᑖ7(C9H8஺2|DḄᑖ7C9H8஺2,Dy[[ᵫAᙠ⏚oᵨ)*=0*ᡂD,AyᨵCஹHஹO-ᐗḄ✏*ᱥᨵFiAyᨵAᙠ⏚oᵨ*ᡂḄI◀yᨵ2᜜cyᨵ2ᐗ0)*Ḅlᓄ=0AyᨵAḄw᪀0ঠ^HCHQH,UD▬E~^^^COOHCOOH(OTCOOHIC[H,=0AstZᓄd*G,G⏚Fi:CHKHO,G|UCHCSOH,4fG)*lᓄஹ^^COOH^^COOH-CHICHIOOCCHI—=0d*H,᪷

19A—FḄᓄ6_`7ifojr6HCH201,+022@2KMnO+16HC1=2KCl+2MnCl+5Clt+8HOᡈKC1O+6HC1=KC1+3CLT+3H2O2SC12+2HO==S+422232SO2T+4HC1õᑴᑖÒ÷ᧅḄùúûü⏚ᒴþÿᐭᰚḄᐙᑖஹᡂSC12◀SC12ᨵᔾᦈCLஹSC12#$Ḅ%&ூ
᪆௃(1)জ()*ᩩ,-ᵨKMnOᡈKC1O0HC11ᵨᑴ343ঝSCL45463(2)789:;Ḅ<=ᑴᑖ>?ᧅḄAB0C⏚ᒴFG஺(3)-I=ᑴᑖ>?ᧅḄABᩭK⁚ḄM᠒3(4)SC1ḄOPQ59C,60CRᓄ◀32(5)CLஹSCL#$ᨵTUVW᛻஺ூ
௃(1)জ()*ᩩ,-ᵨKMnOᡈKClOj0HC11ᵨᑴᓄYZ[72KMnCh+16HC1=2KCl+24MnCl+5CLT+8H2OᡈKC1O+6HC1=KC1+3CLT+3H2O23ঝSCL4546\2SC12+2HO==Sj+SO2T+4HC12

20(2)789:;Ḅ<=ᑴᑖ>?ᧅḄAB0C⏚ᒴFG஺(3)C%&]^_`&aᰚbc☠e>☢ᐭᰚḄᐙᑖஹᡂSCho(4)SChḄOPQ59࠷,6()'CRᓄ◀஺D%&]*4g(60࠷)Ḅ1ᵨQ◀SCL(5)CLஹSCL#$ᨵTUVW᛻஺%&D-hiᙠḄkP\ᨵᔾᦈCLஹSCL#$Ḅ%&26ஹ2NHCl+Ca(OH)^CaC12+2NH3T+2H2OA4NH3+5O2lf=4NO+6H2Om⁐opqr⁐1422H2O2ADூ6᪆௃(1)NH4clCa(OH)2vᔠ)*xCaCLஹNH3ஹHO2(2)yQz{|ឋo~⏚53(3)ᙠbyᓄᓄxNO,NOxNCh,NO24ᔾᦈ9ᑮHNO3஺᪷ᵯឤஹz{ឤ:Z[ᑨᓄᑺஹᑺḄᱥḄḄ᪷ᱥḄ⁐ᑨ3(4)ᵨz{ᱥNOᓄ7⏚c⁐WxᱥmUV3(5)⌕NH3-N2,Nᐗ¡Ḅᓄᔠ¢ᵫ-3¢p70¢yᓄ)ᐭḄᱥ¤ᨵ¥Ḅᓄឋ஺ூ¦6௃(1)NH4clCa(OH)2vᔠ)*5§ᑖ6xCaChஹNH3ஹHO,Z[7\22NHCl+Ca(OH)2^CaC12+2NH3T+2H2O4(2)yQz{|ឋoh⏚5(h|¨(hᵨ0⏚©ª-«ᵨ|¬ᮞஹNaOH®o©ªᦑᔠᳮ⌱⚗QAবজN%02ᙠᓄᑺiᙠᩩ,)*5ᓄxNO³4ḄᓄYZ[7*4NH3+5O2_2_4NO+6HO32,)*ঝNOᙠ¶·¸¹᧕ChxNth,NOQm⁐oNO2Qqr⁐oᡠ«Ḅ¼½Q¾ᑮoᵫm⁐p7qr⁐3ঞNO24ᔾᦈ9ᑮHNO3,Z[7\3NCh+H2O=2HNO3+NO,ᙠ¤]NCh¿1ᓄᑺÀ1ᑺᓄᑺᑺᱥḄÁ712஺(4)Â]¼½¶ᵨz{ᱥNOᓄ7⏚c⁐Wᑣ¤ᱥḄᓄY[7HO22(5)⌕NH3TN2,ᵫaNᐗ¡Ḅᓄᔠ¢ᵫ-3¢p70¢yᓄᑣ)ᐭḄᱥ¤ᨵ¥Ḅᓄឋ஺A.O2-«N%ᓄ7N2,AÄᔠ⚪Æ3B.ÇÈNaᐹᨵ¥Ḅឋ(hᓄN%,B(Äᔠ⚪Æ3C.NH4cl]Nᐗ¡ᓄᔠ¢ÊQ-3¢(hyxËC(Äᔠ⚪Æ3

21D.NO2]Nᐗ¡ᓄᔠ¢ÊQ+4¢hyxËDÄᔠ⚪Æ3ᦑᔠᳮ⌱⚗QAD.ூPÌ௃Í⚪ὃÏÐËᐗ¡ḄᓫÒᓄᔠᱥḄᓄஹoḄᑴÓஹ©ªஹᓄḄᵨ#஺ÔÕNᐗ¡ḄᨵᐵᱥḄឋஹ×Øஹᓄ]ᵯ9ᜫᐗ¡ᓄᔠ¢ḄᓣÛஹÜÝḄᐵÞஹᱥḄ1ᵨᐵÞ#ßẠáâ³ßÍᳮãQÍ⚪6äḄᐵå஺27ஹæçèé■ëì^c]ᵞy⏚îïᓄᐵðK,ᡭòKFe(OH)3222H2NCH2coOH+FeSO4+2NaOH=(H2NCH2coO”Fe+Na2so4+2H2Oadóxô&azõḄö÷⏚]ᤅùúûü9ᵞy⏚Ḅö÷⏚ý>ூ6᪆௃ᐜᡭòKiஹK3,ïÿ
⏚ᡂ⏚ᑁḄ᣸ᐵK3,ᡭK2,Ḅ!b"#$%ᐭc"c"'(ᵞ*⏚+,-./⏚ᙠ50cឤ2ᩩ45ᵨ78ᤅ:ᘤ<=ᤅ:ᯠᔣc"@ANaOH#$B#$pHC5.5DEFᱥᐙᑖJᡂAᐭKLM⏣OPᵞ*⏚Ḅ#QRSTFᐸ᪆WXᑮḄZ"[ᨵᵞ*⏚ᩖ^_ᵨ`a⏚bc஺ூfQ௃(1)᪷ibḄj᪀ᱯm_nᐸopqrsd"tuvᐭ$☢x5_xyᡂ$z■|}ᐭc"ᵞ*⏚~ᓄফᐵK3,ᡭK2,Ḅ!_b"#$%ᐭc"pH_ᡂFe(OH)2(3)ᱥᨵᵞ*⏚ஹ⏚xNaOH,nᡂᱥᨵᵞ*⏚jᔠᐗឤ_no2H2NCH2coOH+FeSO4+2NaOH=(H2NCH2coO)2Fe+Na2so4+2W0(4)a.᣸ᨵᑈWḄ᳛ᔲ᣸Kᐵᦑa┯b.᪷i⚪_n./⏚ᐹᨵ¡ឋ_x■|£¤¥~ᓄᦑb¦§c.᪷i⚪_nᵞ*⏚᧕#©Lª#©M⏣ᡠxAᐭM⏣_xOPᐸ#QRFᐸS#$"᪆Wᦑc¦§d.ᵞ*⏚᧕#©LᵨLbc⌼ᡂᜧ-Z®ᜫᦑd┯°±ᡠ²⌱ad(5)ᵞ*⏚+ᵞ*⏚ᙳ᧕#©Lµᵞ*⏚ª#©`a⏚Tᵞ*⏚ᙠ`a⏚"ᨵ¶·Ḅ#QRᡠx_¸Z©¶·-Ḅ`a⏚"ᤅ:¹bcXᵞ*⏚Ḅ`a⏚#$஺ூmº௃Q»¼⚪Ḅᐵ½¾⚪¿ÀḄᳮQÂÃÄ5bcZᡠᵨḄbc$⌕-,Ḅ#QZT-ÆḄ#Qᩖ^஺

2228ஹ2OH+SO=SO32+HO⏚ឋHSCh-[ᙠᵯ^_⊝HSChPlF+SCV•bc_⊝HSOj+lhOWlhSCh+OH-,228HSO3-Ḅᵯ^d?ᜧ#bcd?HSOj+HzO-Ze=SO2+3H+1.6N173.4-4Aூc᪆௃(1)জᓄijᓄklᡂni⏚kb
opqᵯcᑏᓄstঝ᪷w:;xni⏚j᪷^yz?ni⏚᪷^yz?Ḅ{|ᜧ}+~:;Ḅ⏚ឋঞ□᩽HSO3-ᜫᵯylᓄফᑭᵨ~(3)᪷wᓄbḄLᔠdt_⊝ᔜWᱥḄᱥḄ!z?
᪷w_⊝ᦪt஺ூc௃(1)জ⏚ឋᓄᱥlᡂ¡b
ᡠ£ᓄijᓄklᡂni⏚kb
Ḅ^ydt2OH+SO2=SO32+HO,ᦑ,ᫀ2OH+SO2=SCh2+H2O2ঝᙠni⏚jk:;x¤⌕£HSOT[ᙠ
HSCh-Ḅᵯ^¦§q
ᡠ£n(SO3>)n(HSCh-)«l1,᪷w⊤©H
ªni⏚j᪷^yḄᱥḄ!ᜧ#ni⏚᪷^yḄᱥḄ!
ni⏚jk:;ᕈ⏚ឋ
ni⏚j᪷^yᙠ:;x¬[ᙠbc_⊝[ᙠᵯ^_⊝
ni⏚jk:;ᕈ⏚ឋ®¯HSO3-Ḅᵯ^d?ᜧ#bcd?
ᦑ,ᫀ⏚ឋHSCh-[ᙠᵯ^_⊝HSO3PH++SO32-bc_⊝HSO3-+H2OUH2so3+OH,HSO3-Ḅᵯ^d?ᜧ#bcd?ঞ᪷w°±
□᩽ni⏚j᪷^yᜫᵯyblᡂi⏚᪷^yj^y
ᵯ᩽tDHSO+HO-2e=SO2+3H+,ᦑ,ᫀHSO+HO-2e=SO2+3H+324324(2)²HDজCH4(g)+4NO2(g)=4NO(g)+CO2(g)+2H2O(g)AH=-574kJ/mol,ঝCH4(g)+4NO(g)=2N2(g)+CO2(g)+2H2O(g)AH=-1160kJ/mobᑭᵨ~³জ,ঝµCH(g)+2NO2(g)=N2(g)+CO2(g)+2HO(g)AH=-867kJ/mollmolCH424_448L¶·8moiᵯy
n(CH)=——:----------=0.2mol,᦮N¹dx¶·Ḅᵯyºᦪ0.2molx8N.A/mol=1.60NA,»422AL/molḄ!0.2molx867kJ/mol=173.4kJ,ᦑ,ᫀ1.6NA;173.4(3)¼(ᐭḄᓄḄᱥḄ!z?amol/L,ᑣH2O(g)ḄᱥḄ!z?2amol/L,Ꮇ¼_⊝ᓄḄᱥḄ!z?xmol/L,H2O(g)ḄᱥḄ!z?6xmol/LCO(g)+HO(g)¿ᓄᑺ-CO2(g)+H(g)22ÁÂ(mol/L)a2a00(mol/L)a-x2a-6xa-xa-x_⊝(mol/L)x6xa-xa-xᑣ(a-x)(2a-6x)=l1,cµDx=0.2amol/L,ᡠ£_⊝
c(CO)=0.2amol/L,c(H2O)=1.2amol/L,

230.8ax0.8஺88c(H2)=c(CO2)=0.8amol/L,K=----------------=—,ᦑËᫀoÍ஺0.2஺x1.2a3329ஹÎÏ1,2-ÑÍ⏣CsHnONOHC(CH2)4CHO+4Ag(NH3)2OH-^>NH4OOC(CH)4COONH4+4Agi+6NH3+2H2O112CH3cH?Br.NaOH⏋Ó$ÔCH,=CH,___>QHOHHsIOtrÕÖஹ
ஹ"ឋூQ᪆௃0HᵫØÍÙḄj᪀jᔠᩩ4জ_nÛÜÝAᡂᡂAo,,AÝÎÏᡂBoீ=)BÝ~ᓄXᑮCo.C¥H5IO6~ᓄXᑮOHC(CH2)4CHODÝঝ"ḄXᑮE,0N-OH_nAÝ~ᓄᡂD,ᦑDo(3ஹEo0(6)xáMâo¡ᧇᑴᜓᵬÙçMâÝÎÏᡂMèMèÝজḄᡂMÍ⏣MÍ⏣ÝজḄᡂᵬÙ஺ூfQ௃0H(1)ᵫAᑴéB0ëᓄoìíoîÎÏCoH,CḄᓄïðñoî1,2-ÑØÍ⏣,ᦑËᫀoîÎÏI,2-ÑØÍ⏣;N-OHN-OH(2)EḄj᪀óo:,ᦑËᫀo:বᔠᡂö÷6Ḅᓫ!ùúûḄᑖ¤oCGHUON,ᦑËᫀoîC6HONn(4)ØÍÙü*#$Ḅᓄïo:OHC(CH)4CHO+4Ag(NH3)2OH-^NH4OOC(CH2)4COONH4+4Agl+6NH3+2HO,ᦑËᫀo:22OHC(CH)4CHO+4Ag(NH)2OH-^NH4OOC(CH2)4COONH4+4Agl+6NH3+2H2O23

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