浙江省杭州市示范名校2022年高考化学四模试卷含解析

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13D.d.ḄᑖefᑮᵬhஹJij+Ḅᑮk.ஹ᯼.ஹm.jn.%o.ᯠqn.rstuvOfᑮᵬhஹJij0ᑖwxt᯼Ḅyevfᑮ4ᦑD┯ᦑ⌱C஺6ஹDூ᪆௃ᵫ{|ᓄ}v~NO2%COAB>ᡂCO2%NO]{ᓄABbNO(g)+CO(g)=CO(g)+NO(g)AH=(134-368)kJ/mol=-234kJ/mol,ᑣABᱥᑁ>ᡂᱥᑁ234kJ,ᓽ22NO2(g)+CO(g)=CCh(g)+NO(g)+234kJ,ᦑD,-ᦑ⌱D஺ூ௃ABḄ|HABᱥḄ$->ᡂᱥḄ$᪗ᱥ᝱%BABḄ|ᑨᓄ,஺7ஹCூ᪆௃᪷¡¢£⌲¥ᑖ᪆ஹ¦ᳮ¨©ª¡«-¬ᔠᱥḄᡂᡂᑖ஺ூ®௃A.aᓄᐵ°}6±A_dᮞ)|³´ᑣA[ᨵCXh,X[ᨵNa2c03஺µ⁐·¸B|ᡂ¹⋎⁐ᑣµ⁐·¸B[ᨵFe(0H)2,(XA[ᨵFeCb,X[ᨵFe,©H6±A[»ᨵH2,A⚗,-B.X½t{¾⏚AB>ᡂ·¸A,ᑣX["NazSiCh,·¸AbHzSiCh,B⚗,-C.(XB[¿ᐭÁ⏚Â%ÃÁ⏚>ᡂµ⁐·¸C,ᑣCbAgCL(XB[ḄCl-vᐰᩭž⏚ᑣX[ÆᨵMgCh,µ⁐·¸B[v+ᨵFe(OH)2,C⚗┯D.ÇEᑖ᪆ȱ¬ᔠᱥX[Æ"ᨵFeஹNa2co3ஹNaSiO,vᨵMgCJD⚗,-஺23É⚪⌱C஺8ஹCூ᪆௃AஹxtË}ABH%HL¢ÌÍ□ᑮᓄḄaᓄᦑAÏÐ,-Bஹ᪷ËABbHO=Hf+1/202t,SO2%hÑᑮÒᓄᑺḄÔᵨᦑBÏÐ,-22CஹAB1+AB11+ABIII,fᑮHO(l)=H2(g)+l/2O2(g)%H=(-213+327+172)kJ•moÕ=+286kJ•moF1,ᡈ2ὅ2HO(l)=2H2(g)+O2(g)AH=+572kJ•mol-1,ᦑCÏÐ┯2DஹZkH+½Ú᝱%Û᝱ᨵᐵÜtÝÞÌ)ᑖᑴFḄßᓄAH|ᦑDÏÐ,-஺9ஹBூ᪆௃

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21COOHCOOHCOOHCOOH+CHjCOOHঞëìWVOHQX)ᵭ*+Ḅᓄ²³´2.ஹNHICHjC=OCH,C=OAMnO,25ஹV2KMnO4=K2MnO4+MnCh+CMᡈ2KC1O3-^2KCl+3ChTNHCkCa(OH)ôᮞz`ᡈ42CHtCHᑖèöᧅ%ôᮞe=Ḅ*+$ᜧRḄqùúᑖC%ᡂNH3BDûbxÑ┵ýþÖÿḄᐭ┵ூ
᪆௃(1)ᑴ⏚"ᡈ$⏚"%&ᓄ═Ḅ)ᔠᱥ,(2)-./+=ᑭᵨNH4cl%Ca(OH)2ᐳᑴ56789:ᵨ;<ᮞ>?,(3)@2+ABᵨCᑴᜓEFḄᨵHIᯋKᘤbᑖANᧅ9<ᮞP5:Ḅ:67QRᜧTḄUV5:ᑖW9ᡂNH3(4)জA.Y5:ᢵQ5[\]C^,B.5᩽᧕aC:┵bc>?,C.4NH+5Ofifi^4NO+6HO,2NO+()2=2NO2ᑖ᪆,322D.67e67fgᢝi,ঝkBl┵miḄᐭ┵n஺᝞qrnᑣtuvwix⁐ᵫ5{ᓄᓄ|⌼ᡂ~^ᓄ|⌼ᡂ஺ூ
௃(1)ᑴ⏚"ᡈ$⏚"%&ᓄḄ)ᔠᱥᓄAMnO,A2KMnO=KMnO4+MnO2+O2T,2KCIO3--------2KC1+302Tᦑᫀ2KMnC>4=KzMnCh+MnCh+ChTᡈ42MnO,2KCIO3—2KC1+3O2T?ফ-./+=ᑭᵨNH4a%Ca(OH)2ᐳᑴ5ᓄCa(OH)2+2NHCl=CaC12+2NH3t+2HO,8ᱥḄ:ᵨ;<ᮞ>?ᦑᫀNH4CI.Ca(OH);<ᮞ,422ব@2+A-ᵨCᑴᜓEFḄᨵHIᯋCaC2+2HO^Ca(OH)2+CH=CHf,KᘤbᑖANᧅ92

22<ᮞP5:Ḅ:67QRᜧTḄUV5:ᑖW9ᡂNH3,ᦑᫀIᡈCHmCHᑖANᧅ,9<ᮞP5:Ḅ:67QRᜧTḄUV5:ᑖW9ᡂNH”(4)জA.Y5:ᢵQ5[\]C^ᦑA┯,B.5᩽᧕aC:┵bc>?ᦑB,C.Q9Ḅ674NH3+5O2Úêᑺ4NO+6H2஺,2NO+O2=2NO,ᦈ5┵Y\ᨬ29ᡂNO2ḄY\⁐ᦑC┯,D.67e67fgᢝiᦑD,ᦑᫀBDঝnkBl┵miḄᐭ┵᝞qrnᑣtuvwix⁐ᵫ5{ᓄᓄ|⌼ᡂ~^ᓄ|⌼ᡂ᝞Rnix⁐¡uIḄ¡¢ᔠᳮ,ᦑᫀnkBl┵miḄᐭ┵஺26ஹ¥ᨵ¦89m89ḄCO2%HO(g)ᐰ¨᣸ᐭIஹªD«¬a(ᡈᵬ)Co(OH)C03222±⁐2Fe2++H2Ch+2H=2Fe3++2HOA1(OH)>Fe(OH)3ᢓᑴCOChḄ:W³QY´ஹµᓾ·ᨔ23ூ
᪆௃(1)ᵬ¹ᴻ»¼I¥ᨵ¦89ᓽ;¾⏚¿ᑖWÀÁ,(2)ÂÃটÅÅÆᐭ^ᦪᑖÈm9ᡂḄCO2%H2Oᐰ¨᣸ᐭIஹªÉÊËÌT·q,(3)ᙠ«¬aD,ÎeḄ;<ᮞÏ᧕ᔾᦈ^Ḅ:³%&ᓄ¾,(4);¾⏚¿᪵Ò3.65g,67IḄÓT80.00g,67|ÓT80.36g,ÔÕÖ9ᡂ:ḄT,67ªḄÓT62.00g,67|ÓT62.00g,ÔÕÖ89&ᓄ¾ḄT×ᑮC஺ḄÓT%CoÙÚᱥÓḄT᪷ÔCoஹHஹCᐗÝÞឤàᩭâã;¾⏚¿Ḅᓄ,(5)äᨵC஺(A10)2Ḅ¹ᴻEᵨå-./"ᐗÝḄᯚ⁐67¹ᴻ±⁐çèéᐝḄ>᡾,2(6)ᔣä¿íᧇᐭïTðñ⏚FeஹAl%ðñ⏚679ᡂFeCbஹAICI3ஹC0CI2,ᔣaAᐭò:%CoCCh,ò:ᐹᨵôᓄឋfmö÷øÚᓄ÷øÚøÚ672Fe2++HO+2H+=2Fe3++2HO,ᐭCoCO,2223ù⁚aAḄpHû7.6,VFe(OH)3ஹAl(OH)39ᡂüýᯠ|ïççÿFe(OH)3ஹAl(OH)3,ᨵCoCl,ᯠᔣᐭ⏚ᢓᑴC0CI2ᯠᵨஹᓾᨔ!"ᑮCOC1«6HOd222জ%&ᐹᨵ&ᓄឋ*&ᓄ+,ឋ-./ঝᐭCoCO31pH5.2"7.6,ᑣ34I5"Ḅ7ᡂᑖFe(OH)3ஹAl(OH)3;ঞC0CI2:⏚;<□-.>?@ᕈ⏚ឋᐭ⏚*ᢓᑴ/ট34IICஹᓾᨔஹ஺ூ
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23(1)FᵬHᴻJKLMNOPᨵQRSTᓽ?@ᕈ⏚ឋᐭ⏚*ᢓᑴᡠgᐭ⏚1᦮PH2î3Ḅ°ḄᢓᑴCoCL/ট342¶@·¸@Ḅ3434!¹ஹᓾᨔ஺27ஹS+2H2so£)3_3sO2T+2H2Oº»¼ClOz,½¾ᐸÀᐙᑖᔾᦈ2C1O2+2OIT+H2O2=2C1O2-+O2+2HOᑖÂᧅᔾᦈÄ}~Ḅz&ᓄÅ2Na2(h+2SO2=2Na2so3+O22ூ᪆௃ᵫ}~2NaClCh+SO2+H2so4=2CK)2+2NaHSO4ᑴᜓC1O,CIO2ËḄNaOH@}~ᑴNaC஺@ÌÍ_2ஹᓾᨔஹÎ"ᑮNaClO,Ïᑖ᪆ÐপÒ(3)d2(4)Aᑴᜓz&ᓄÅËNazChᙠB}~CᔾᦈÄ}~Ḅz&ᓄÅDᦈÓᑮḄQ®§ÔÕÖḄᩈᩩÙÚÛÜᨵ&QSTDᦈÓTᡂḄ&QÏᑖ᪆Ð஺ூÝ௃(1)CK)2TᘤḄ}~ß⏚àËz&ᓄÅᙠÅ⏚4ᵨáT&ᓄ+,}~âÅãஹÅ⏚ägTᡂz&ᓄÅ

24}~ḄCVS+2112so4()_A_3sO2T+2H20,ᡠgᵨÅãஹÅ⏚æç,ᧇḄS02,ᦑÐᫀ:S+2H2sO«)A3SO,T+2H(2)}~êTᘤëᨵìlCICh,^ᐭ_QgbᐸYᐰ᣸¼½¾ᐸÀᐙᑖᔾᦈᦑÐᫀ¹º»¼CKh,½¾ᐸÀᐙᑖᔾᦈ/(3)ᔾᦈᘤ%&ËC1O2ᙠ<ឋᩩíáT&ᓄ+,}~TᡂNaClO,}~Ḅ-.CV22C1O2+2OH+HO2=2C1O2+O+2HO,ᦑÐᫀ¹2cleh+2OH+H2O2=2C1C)2++O2+2H2O;222(4)জ᪷MNîrsH2s04ïᘤᑖÂᧅ/C@Ḅ4ᵨᔾᦈÄ}~Ḅz&ᓄÅ/ᦑÐᫀ¹ᑖÂᧅ/ᔾᦈÄ}~Ḅz&ᓄÅ/ঝDᦈÓᑮḄQ®§ÔÕÖḄᩈᩩÙÚÛÜᨵ&QSTᡠgBTḄ}~*z&ᓄÅË&ᓄà}~Tᡂ£Å⏚à&Q}~ḄCV2Na2O2+2SCh=2Na2so3+O2,ᦑÐᫀ¹2Na2()2+2SO2=2Na2so3+O2஺ூðñ௃ò⚪Ḅ᧕┯ð(4)ঝCVḄõᑏ⌕øù᪷⚪ùTᡂú&QûÏO*}~TᡂÅ⏚à஺28ஹH++OH——H2O2H++CO2-^HO+COtNa>S>Cl:CL+HzS-SJ+2HC1,üß⏚Ḅ⏚ឋýÅ⏚322Ḅ⏚ឋ:(HC1Ḅþÿឋ
H2s)NaOHNa2cChNa2cO3NaHCCh5.85gNa2cChᔠḄᜧ᡽ᦣᔾᦈḄூ᪆௃CO2ᐭNaOH!CO2⌲#$%&'(Ḅ)*ᑖ᪆&,Ḅᡂᑖ஺/012ᑣ(ᡂḄNaHCCh45ᑖ஺ூ6௃(1)“7⏚9:”ᙳ=᧕Ḅᵯ,ᙠABCD&*Eᑏ஺ᑣGH⏚ᑖIJ“9:”)*ḄABCD=H++OH-=0ஹ2H++CO2-=HO+CO2T«32(2)NᕜPQRᐗTUVᑮXYBZ[\]^_஺“7⏚9:”&`a7ᕜPḄᐗTᨵcஹdஹeᐸYBZ[ᵫᜧᑮ_Ḅhi=Na>S>CLবNᕜPQRᐗTUVᑮXᐗTklmឋ\]$ᑣdḄklmឋ
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c஺(4)ᔣzO.lmolNaOHḄ&ᐭCO,{ḼC(hḄ$%&ᐜ~'(9)*(l)2NaOH+CO2=Na2co3+H2O,2(2)NaCO3+CO2+H2O=2NaHCO3o)*~/012ᑣNaHCCh45ᑖᡠᨵvজNaOH2Na2c03dঝNa2cO3;ঞNa2cO3NaHCCh;টNaHCCh஺J⏚12ᑮ=NaCL!eABឤᨵNaOH-NaCl,ᑣNaCl,5.85g஺(5)Na2cO30ᓣsᑣ஺ᒹ᡽ᦣ(ᔾ)ᔠ()9᡽ᦣᔾ_

25ᔠᑣ஺0H29ஹஹNaOH%)*(ᡈ)*)CHO0HCu+02+2HOC10H15NO5A2OHOH-PC'H-(LCXHCHaCHiOH-r-2--CHUCHOInCu.Aঝrᩩூ᪆௃‘JBnᙠNHSḄᵨ'()*(ᡂC^BrHBr(௃“ᙠNaOHஹ%ᩩ'(CHO.CHO)*(ᡂ(y)H0")HᙠCuஹAᩩ'(¡ᓄ¢ᓄ)*(ᡂa;(\JNaC7CHஹH+ᵨ,0H'(%ᡂ)*ஹ⏚ᓄ)*(ᡂ¤yOHOHOH2JH2OᙠHgSO4Ḅ¡ᓄᵨ'(%ᡂ)*ஹ¦᪀ᓄ)*(¨oYa©JC%NH2ᙠrᩩ'OHOH(%ᡂஹῃ)*(ᡂ0^\(«¬OY'CH,'(%ᡂ)*(ᡂூ6௃OH(1)F=0^^,zᨵḄv®Ḅ¯°=ஹ஺±ᫀ=ஹ³¬Ḅ)*ᩩNaOH%)*´µ)*(ᡈ)*)EḄ¶᪀·D=0HNaOH%¬)*(ᡈ)*)¬CHO¸ᩩ'(¡ᓄ¢ᓄ)*(ᡂ஺ᓄ¹)*CD=(3)ᙠCuஹCH0CH0OH,ஹCu+6t22+°2-2+2H2OO±ᫀ=2+2H1O(4)ᦪᡈ½¾¿TḄᑖBD=GoHisNO஺±ᫀ=CioHisNO(5)HGḄNÀᱥÂz⏣ÄÅÆÇÈÉᑖB,
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GᑖBË2“CH2”ÌÍÎÏÐᨵÑÒᑣHḄv¶᪀(ᶍÔÍÎ)=-CH=N-CH2OHஹ-CH2cH=N-OHஹ-CH(OH)CH=NHஹ-CH(OH)-N=CH2ஹ

26-N=CH-CHOH,ᐳᨵ5Ö4ὃ⇋JH¶᪀Ù஺±ᫀ=5;2য\!⚪ÜÝÞ⌕ᔠᡂà᪗ᨵâᱥ◤ᐜᑴCH஺ᑭᵨCH3cHÖæçèᑭᵨéêH?OHR-OC-R---------►R-CH=CH-R,ᑴ],%íîᑮà᪗ᨵâᱥ஺ᔠᡂïð=:rᩩ^OHOH-eOWH3rCH3CH2OH--7»CHCH^CHOI\L/k^_±.•CH.CHOH(!!¸ঝHTᩩூÿ௃ᑏᔠᩩḄᱥḄ᪀ᐜᨵḄᯠ!!"⌕$%&'ᔠ▲ᑴᩩḄ᪀᣸◀ᣵᨵ-./0123456┯8ᐸ:;ᙠ=>஺