湘豫名校2023届高三化学8月入学摸底试题卷附答案解析

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12᠒nIḄᓄᜧnḄᓄD⚗஺6.Cூ"᪆௃ᱥ&Y(SC>2,ᐸᑖ/0S1M3ᜐ5063᝱ᦑSO?;ᐹᨵ>ᓄឋ@ᐹᨵABឋA⚗DE⏚G⏚HḄIᡂKL0MNH2s஺3ᔣH2s04ḄUᓄB⚗DWXYCuḄ[ឋ\]⍗_E⏚`abcᓄC⚗┯eDX1H2SஹY1SO2abh0iᑮSᓫ&l2HS+SO-3S4<+2HO,ᐸ0SO?p>ᓄᑺH2spABᑺᑣ0>ᓄᑺsABᑺḄᱥ&Ḅt222uv1ll2,D⚗஺7.Cூ"᪆௃ᑖz⃓|}~ᑖ~ᧅYᘂᑖ⌕☠ḄᑁA⚗┯eDᑭᵨᐗᨬ3>ᓄᱥᓄᱥḄ⏚ឋ]ᑨᐗ[ឋ]⏚`(ᐗᨬ3ᓄᱥᓄᱥ`ᑨᐸ[ឋlCl>C>Si,B⚗┯eD⏚ஹ⏥,_E⏚Ḅ¢ᔠ~¤¥¦ᔣ§¨┐ᑭᵨ⛳«¬⏚ᦈ¯°ᑖz⏚±C⚗Dᑴᜓ´>ᓄµ¶Ḅ·¸ᨵ¹º»⌕ὃ⇋■>ᓄ¿0ᵨCC1,■>ᓄ`ᔠᳮÂḄÃÄᜧ5D⚗┯e஺8.Bூ"᪆௃M0Æ>ÇÈᨵÉÊ«⏨̬¬ÍÌ0`Æ>A⚗┯eᵫ¿
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Mᙠ_E⏚ᩩÞßsCH3co0Hab±ᓄbᡂN,±ᓄ5|âD⚗┯e஺9.Bூ"᪆௃᪷å⚪çèéêX(BᐗஹY(CᐗZ(0ᐗW(Fᐗ஺᪷åîᕜðᐗB/ñòóôᔣõö÷øùḄúû
B/ñòlB>C>O>F,A⚗D᪷åîᕜðᐗü[ýឋ⌴ÿ
BḄឋCᑣᓫᓄᱥḄឋBHFC3~4,B⚗┯᪷<]^78II_3FeO+H2~2FJO4+HZT,I&OjᓄᑺFeOjnLᑺC⚗┯ᵫ78II3FeO+H2OFeQ4+H2T78Hᙠ᪗112Ll6ᡂ1.12LH2ᵯMḄᱥḄ_:-----rx2=0.1mol,D⚗9:஺22.4Lmor'11.CூZ᪆௃ᵫ]^xzFeO3ᓫᜧὅ¡☢£¤ᐸᐙᑖ78¨©ªὅḄ78«᳛A⚗9:᪷<ᓄnL78®¯°IIz±²ᩩ´l5678Ḅᓄµ¶·¸_TiO+2C+2C1=TiCl+2C0,B⚗9:᪷<º»ঝTiCl,᧕¾Z3╅788_ᙌÁ22413

13Â780ᙠ±²ᩩ´lÃÄC⚗┯ÅƲlTi3⏚178MgÉÊËÌ⏚ᡈËÎ⏚ᦑᵨËÌ⏚ᡈËÎ⏚◀ÑzḄÒ╅ᓫD⚗9:஺12.DூZ᪆௃Ó]^ÔÕ᝱I2×ØᡠÚ᝱I-᝱II-ᔾÜÝ·A⚗┯:Ó]^ÔÕÞÝ·zßᨵCOᑖMz᩽ឋDḄqáâᨵCO?ᑖMz᩽ឋDḄ$ᡂBஹC⚗┯᝱1-᝱111-ᙠåᓄᑺ⊤☢ÃÄḄåᓄᑺçØè78Ḅéᓄ2¨©è78«᳛D⚗9:஺13.CூZ᪆௃᪷<ê᩽ëzIF"OHḄì¶ᔣM᩽îᵯïḄð᩽ᐸᵯ᩽78¸_2HO+2e-=H?+2OH-,A⚗9:᪷<⚪òᑖ᪆ëa"ëbᙳ_□õMöᣚëÎøzNa,22úëaᵫÎøᔣ4ø1,4ø1zu6OH,¤4ø1zNaOHÉûüýþᜧ4ø2ᵭNa,bᔣᡂNaOHB⚗ᵫB⚗ᑖ᪆2NaOH,C⚗┯ᕒ᜜ᵯ&ᨵ2moiᵯ+,-./ᨵ2moiNaᔣ1,1᩽ᨵ2moiH'ᔣ/ᓽ5ᑮImolH2sD⚗஺14.AூA᪆௃ᵫCDᙠl~3minᑁH2ḄᱥLḄMᓄO3mol,PQV(H)6MO1-3MO1o.75mol-L1-min1,A⚗Vᙠ8~10minᑁHḄᱥLḄMY2mol,Z[Q272Lx2min.]^_`a⊝c᝱,B⚗┯e8min.H,ḄᱥLḄMY2moifὑH2ḄᱥLḄMY8moi-2mol=6mol,᪷kᓄlmnoCO(g)+3H(g)=CH30H(g)+HO(g)222tuM/mol6800wᓄM/mol2622a⊝M/mol4222a⊝.xc(CO)=2mol-L-1,c(H2)=lmoLz,c(CHOH)=lmolI71,c(HO)=lmol.L-1,ᑣ232K=0.5,C⚗┯eVᵫC}c~]^_`a⊝c᝱ᑣQ.v(H?)=3(CH3OH),D⚗┯e6BூA᪆௃᪷k_CuOஹ80ᙳᑖCU(NHJ21(⁐)ஹCU2(NII)2+(⁐)஺ᔠᱥᐭMᐙᑖ-5ᑮ⁐ᐙᑖ₩5ᑮ⁐34⁐ᨵCU(NHJ21(⁐)ᑖ₩.¡¡ᓄwᓄY¢c/lNIIj)/'(⁐),ᵫQDᔠᱥᨵC&O,¥CuO,A⚗V¦⁐§¨X^ªYCu,«ᐭᐙᑖ₩.¬,®]^ᡂCUYNHJ)/"(⁐)PQ§¨ᔠᱥ¯Cu?O°Cu,B⚗┯eVᐭ®ᐙᑖ₩ᡂCU2(NH)J2*(⁐)ḄᓄlmnoY314

142Cu+O+8NH+2HO=2¢CU²NH³J2*+40H-,C⚗VCuO,Cu?Oᙳ¶ᑖ2323¢CU²NH3³2·²⁐³ஹ¢CU2²NH³J2*²⁐³¸₩-n¬.¡°®]^3¢CU2²NH³·2+²⁐³ᦑºᱥ-n»¼ᐙᑖ₩½¾¿ᡂ⁐ᑣÀÁÂÃᐸᡂᑖD34⚗16.DூA᪆௃᪷kC}a~.pOH=-lgc²OH-³^=12.6,ᑣÇOHj=10ÈÉAc²H'³=1014,pH=1.4,A⚗VB~.LYNaHX,᪷kNaHX=Na++HX.ஹIIXUX^+H'ஹH2OUOIU+H+,L+Êឤc²H+³=c²X2-³+c²0H³,ᑣ6̳=c²H+³-c²0H³,B⚗V᪷kÍÎ.⏚ឋḄᓄC~ᕈឋC~ᕈឋC⚗xd~.ḄLYNa?X,X?-AᕈឋÓ᪷kH^X=IT+HX-HXÈÕᵯÖ¥AᦑNa?X¥×ᙠHX,Xᑖ+᪷kᱥᧇÊÙc²Na+³=2c²HX-³+2c²X2-³,D⚗┯e஺2ÚஹÛ⌱Ý⚪xᐳ52ᑖᒹáâὃ⚪°⌱ὃ⚪äåᑖ஺æ17T9⚪Yâὃ⚪èéê⚪ὃëâìíî஺æ20~21⚪Y⌱ὃ⚪ὃ᪷k⌕ðíî஺²È³âὃ⚪xᐳ3⚪ᐳ37ᑖ஺17.²13ᑖ³¢îᫀ·²1³òCu?+wᓄYCuSôõ»ö◀ø²1ᑖ³²2³CuS°S²1ᑖ³2CuS+30-2CuO+2SO²2ᑖS+O24SO?¥ᑏ5ᑖ³22²3³¡ᓄF*ᡂFe”²1ᑖ³2Fe2-+HO+2H+=2Fe5-+2HO²2ᑖ³NiO²1ᑖᡈNi²OH³2222þᐸÿᔠᳮᫀ2.8„pll<6.91ᑖ40.003ᡈ0.002982ᑖ51ᑖᨔ1ᑖூ!᪆௃1$%⏚╅ᨔ()*ᨵCM*ஹFe2\Fe"ஹCa2\Zi?'9ᩖ;<=>ᨔ(?@ABᐭI§S,HIJKHS+Cu2+=CuS>L+2H\H2s+2Fc"=SJ+2Fc"+2H',UᔠA☢BᐭHQ?,HX2YᐭHSḄ[⌕]Ḅ^_Cu2i`ᓄbCuScde◀gh22Uᔠ1Hi>jk1Ḅ[⌕ᡂᑖ^CuSmShnjk1ᐙᑖᯏq>ᯏqjk1IJKḄᓄrstub2CuS+30=2CuO+2SOmS+0?=SO:2223JKHxyBH2O2Ḅzᵨ^|ᓄFe2+IᡂFe"}2Fe2*+HO+2H+=2Fe3++2HO,Bᐭ~22215

15ᑺXḄ]Ḅ^᦮pH,_Fe>?!IᡂFe(0H)3cde◀g>ᦑᡠBXH^NiOஹNi(OH)zᡈNiCO,9>Uᔠiজ>᦮pHḄb2.8pH<6.9h(4)ὃ⇋)ᶇḄc(Ca2+)x>ᡠBNiF,Ḅbc(NiF)=:3+0.0005x2=0.003molL1,¡ὃ⇋)ᶇḄdCa?)x>2\/c(NiF)=x1+(0.0005-1x105)x2=0.00298mol-L1}2(5)¥zIVbUᨔ¥z>ᙠ¨>B©ᨔxஹªᓾUᨔஹ¬jஹ®ஹ¯°A±ᑮ³KḄ´%⏚┞ᨔ(஺18.(13ᑖ)ூᫀ௃পCO(g)+CH,(g)=2CO(g)+2H(g)M=+247kJmo»(2ᑖ)22(2)জᜧ½(1ᑖ)2¾(3ᑖ)¿ᔣÁÂ(1ᑖ)ঞÄÅ(1ᑖ)Æ(1ᑖ)9(3)জÆÇ(1ᑖ)ঝ46(3ᑖ)ூ!᪆௃(1)✌ᐜᑏCH,mCO2ḄÌᓄÍ᦮JKbCH1(g)+CO2(g)=2CO(g)+2Hz(g),Î᪷ÐÑÒÓÔ>জ+2XঞÕঝ±CH(g)+CO(g)=2CO(g)+2H2(g),42A//=75kJ-mol_1+2x(-1HkJ-moØ‘)-(-394kJ-mo»)=+247kJ-mol'1(2)জᵫÛÜHi,yÞᵬàḄ`ᓄ᳛ǽâ⊙`ᓄ᳛,JK¿ᔣäå>ᡠyÞæᜧ½æ;ঝ᪷ÐèéuêëH±;CO(g)+CH(g)E2C0(g)+2Hz(g)24íî/mol0.10.10`ᓄ/mol0.050.050.1â⊝/mol0.050.050.1(0.1?1(o.iYJஹ஺?ñτò_4php(0.05AI(0.05ஹ9Ro.3MyX0.3J᪷ÐJKCO2(g)+CH/g)W2CO(g)+2H2(g),A^-+247kJmolᙠâ⊝xᓣ÷ø>â⊝ùᔣᔾ©Ḅ¿JKsᔣÁÂ}ঞ᪷ÐJKC()2(g)+CH4(g)=2CO(g)+2H2(g),AW=+247kJmol¿JKsᔣbᔾ©JK>ûᙠüýþÿᘤᐭ0.2molḄII?CO⌮ᔣᑣ16

16!"#$ᙠ&'&ᵨᩩ*+Ḅ஺-OZmolH202molCO0ᐰ2ᓄ4O.lmolCH,0.1molCO,ᑣ7ঝ&ᦔᙠ1100°C;ᑮ=⊝?᝱2,cBCOzDEF#2B3DজᵫJKLPtᵯ᩽ᡂRSPt$□᩽ᵯ᩽U$2H2O-4e--4H++BD2T▬\]^ḄPHF_#ঝ`ab$▢᩽CO?ᙠ▢᩽dᵯ/•ᡂᵬ⏚ᵯ᩽U$CCD2+2e+2H==HCOOH,j2k2moiᵯm▢᩽n]^opq46g஺19.B11ᑖDூwᫀ௃B1Dz⚠|}B1ᑖDMnO+4HC1=MnCl+Cl?+2HOB2ᑖD2222B2D⛳B1ᑖDᢵḄᓄS7ᘤMNaOH]^⏚Ḅ᳛B2ᑖDB3D■'ᓣᡂNaQO3,■ᡂḄ⏚¡!ᑖ¢B2ᑖD£S7NaOH]^ᐙᑖ¥¦§¨᳛஺©ªSḄ᜜⍎B1ᑖD£C127ᡂḄNaOH®ᡂNaClO,¯°ᧇḄᑭᵨ᳛B1ᑖDB4Dᙠ³´D¶m+.·¸¹£³´D7᜜º»¼B1ᑖDூ¢᪆௃B1DᘤMḄ¾¿4:⚠|}Á³´AᡂSÃÄnÅᵨRᓄ═Ç⏚Ḅ^ᑴᜓ,ᓄÉÊU4MnO?+4HCI=^=MnCl+ClT+2HOÁ222B2D³´AᑴÌḄᱥÎᨵHC1ÐSᢵḄᓄS7z⚠|}NaOH]^Ñ⏚Ḅ᳛³´B$◀ÔHC1Ḅ³´ᐸÖᨵ⛳#B3D×ᔠÙÚজঞLC1?NaOH]^Ü]^'Ý.ÞᡂNaClO,,ᡂḄ⏚¡!ᑖ¢ßà⌕ᙠâãz⚠|}¼SḄS¹ᜮ4åæᳫèKqᜧS7NaOH]^Ḅ¥¦☢ë£ὅᐙᑖ¥¦■SᩭEî#×ᔠÙÚঝLᡂï⏚NaOH,ðᙠz⚠|}^☢ñòóôõ⁐Sᑣᵫz⚠|}ñ.÷ᐭBCNOD3H3ø,ÝÊù◤Eû¼ᐭCl2£ᡂḄNaOH®ᡂNaClO,¯°ᧇḄᑭᵨ᳛#B4Düᑴᜓ³´Dᜐÿ
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