陕西2022-2023学年高三化学上学期期初检

《陕西2022-2023学年高三化学上学期期初检》由会员上传分享，免费在线阅读，更多相关内容在教育资源-天天文库。

▷
ᜧ▬ᓅ2023ᓄ⚪ᵨᑮḄH-1B-11C-120-16A1-27S-32Ti-55Ni-59Cu-64Ba-137ஹ⌱8⚪(:;⚪<ᨵ>⌱⚗@ᔠ⚪B,:;⚪3ᑖEᐳ42ᑖ)1.IJᐺLMᓄNO,PQRᱥTUᐸWᓄឋḄYA.Z(Au):“]^_`ab”B.def(S):“ᓄ....gஹhஹi,᜻ᱥ”C.dᮞ(CaO):“mnoREᓽqrst”D.dvw(CaCCh)“⁐fEmz⏀(|)}ᑵᑣ”2.ᵨNA⊤ᦪḄ,Pᑡ┯ḄYA.16gᵬ⏣ḄᑖᨵC-HḄᦪ1.5NAB.25࠷E1LpH12ḄBa(0H)2ᨵ0H-ᦪO.OINAC.ImolZn£¤¥e⏚§¨©ªᐰt,¬ᡂ®TḄT¯(᪗±²³P)22.4L23125U+0n4D.´N᪶§¨:9JtBa+ᦇM+3»ᑣlmol^Mᦪ55%3.Pᑡᔜ¿Àᙠ¤ᜧᐳÃḄYA.ᙠ0.1mol/L|⏚SC)42-ஹNHÅஹBLஹH+B.ᙠ0.1mol/LÆn:Ag+ஹCu2+ஹNO-ஹSO2"33C.ᙠ0.1mol/LÈᓄÉFe3+ஹÌஹBa2+>HCO3D.ᙠ0.1mol/Le⏚ÎH2PO4ஹPO3-ஹNa+ஹNO-434.PᑡÐÑḄY

1A.CU(OH)•C11CO3ḄhḄᑖᦪÓÔCU(OH)-2CUCO223B.FeOÕaᙠÖ®×q,ØÙ^WᓄᡂFe3()4C.P2O5ᵨÚÛÜÝÞᑺD.SO2àáâEãᵨÔᩔåஹæç5.Pᑡ§¨ḄÀèéê┯ḄYA.ëìᐭBa(OH)2îïðᨬᜧ2A13++3S02-+3Ba2++6OFT=43BaSOJ+2A1(OH)I43B.NaOH£óH2c2O4§¨:HCO+20õ=C0i-+2HO22422C.ö⏣£÷52஺7⏚ឋ§¨3CH3cH20H+2CrO^+16H+t3CHCOOH+4Cr3++2311HO2D.úÈᓄûḄ¥ᑴᜓnᔠþWᓄÿ:
4++(%+2)HO==TiO-%H0+4H2226.ᨵᜐḄᕜᐗ4BஹCஹ0ஹ"ᐸ$B&'ᨬ᜜*ᵯ'ᦪ-ᵯ'*ᦪḄ2.,C-01ᐗ,0.1mol•71ḄDḄᨬ9:;ᓄᱥḄ>ᓄᱥ?@pH<1,CDᐗḄ&'EFG&'HᦪḄᐵJ᝞LᡠN஺PᑡRS┯UḄ-原子半径B.ᵫCஹEXDᐗYᡂḄᓄᔠᱥḄ>?@\]^>Ḅᵯ_C.ᨬ9:;ᓄᱥ`aḄ>ᓄᱥḄ⏚ឋ:B

27.nop>qrGsta:3B72+8NH-H0=NT+6NHBr+8H0OP☢yz{s|32242}~s|ஹs|ᑮNF^BrᨔḄ&ᳮG\ᑮḄḄ-A.ᵨᵬ◀s|$ḄsB.ᵨᑖ_ᵬ$taḄᔠ@C.ᵨ?@ᑮNHdBrᨔD.ᵨᑖ_s|G|8.ߟ¢£¤taᩩ¦§,ᐸ¨©ᐹᨵ&'«¬ឋ,N᝞PL஺Pᑡ®¯┯UḄ-A.I$ᡠᨵ±&'q\ᐳ³☢B.´ta1µᡂtaC.II\¶·µ¸ta¹\º⏚ឋ9╎⏚¼?@½⁐D.III\ºsḄ¿Àᓄ±?@Á⁐9.HO(1),ÃপᙳqÆ὚ᵯ_È2&0প=OFT+Ê0+ஹ2NH(1)^NH2+NHjoP236+8-6+:&Ìτ
ᡝjCH,CH,+Br+H+OH——>CHCHOH+HBrᑡtaG32È...............È32&ᳮḄ-A.MgN+6HO=3Mg(OH)+2NH32223

3B.SiCl+8NH(1)=Si(NH)+4NH4cl4324C.3C1+8NH=6NH4CI+N232D.PC14-3HO=H3PO3+3HC13210.Pᑡ®¯ÕÖḄ-A.×ØÙ;ᓄᑺ}᝞À⏚¼ஹ9Û⏚¼Üᐸᔠᱥ\ẆÞᔲᑣq\áâᰦäB.åæᑴᜓé⏚Ḅ⌕ëᜓÌìí᮱ஹïðñᔾᦈᛞC.×Øõ᝱01;ᓄᱥᑖᦣøᴻ$qᑴ⌼ᨵ⁐øᴻD.·ᱥûü$ýþᑭᵨ
ឋḄᓄᓄឋ11.ᑭᵨKMnO4!᝞#,%ᑡ'(┯*Ḅ+O.lmolKNfnO,⏚|ᑣ—T|TᓫHG⏚ឋMhA.G.Hᙳ1ᓄ2ᱥB.KMnO45+1ᓄᑺ7+89ᑺC.ᙠ<=>,═ᐗABCᨵEFG᝱D.G.HḄᱥJḄKLMN0.25mol12.UFᣓWXYCO2Ḅ=>᝞#ᡠ[஺]%^0.1mol•L-iKOHcᔾᦈCO?,ghᐭCO?ᡠjkḄclmᓄMn0ᢵpqᶍ,cstᱥFḄuv஺w=czH2c஺3|+czHC01|+czC0g|஺H2cO3ᵯᦪᑖKal=4.4X10-7ஹz2=4.4X107஺%ᑡ'(┯*Ḅ+

4A.KOHᔾᦈ82ᡠᑮḄcc(HCO])>C(HCO)23B.KOHᐰᓄK2cO3,cc(OH-)=c(H+)+c(HCO])+2c(HCO)23C.KOHcᔾᦈCO2cw=0.111101-1c0(142(03)஺((032-)D.᝞#ᡠ[Ḅ“ᔾᦈ”“ᓄ”=>cḄ]vᓣ13.pH+UFᵨ9ᵯ9ᳮKcpHḄ¡ᘤ஺᝞#ᡠ[^£ᴻᵯ᩽(ᙠᱯᑴ£ᴻↈ©ᳫᑁ¬®¯uvḄHC1c,°᣸ᐭAg-AgClᵯ᩽)M²UAg-AgClᵯ᩽᣸ᐭ³c´ᡂᵯ,pH.ᵯḄᵯ¶·E¹ᙠᐵ»:pH=(E-ᦪ)/0.059஺%ᑡ'(¿ÀḄ+Ag.AgClᵯ᩽(O.lmolL4HCl)—Ag-AgClᵯ᩽(S.OmolL4KCl)$%ᕜ'(ᴻↈ+ᳫ!"#A.pHÁÂᵯNᓄᓄÃNB.᝞Ä£ᴻↈ©ᳫᑁᵯ᩽Ḅᵯ·Å,ᑣ<ᵯ᩽ÇÈÉ:AgCl(s)+e=Ag(s)+Cr(0.1mol•LT)C.ᑖÎs®¯pHḄ᪗ÐcMѯcḄᵯḄᵯ¶·,nѯcḄpHD.£ᴻ©ᑁ᜜ÓÔuvḄÕÖ×jkᵯ¶·Ḅmᓄ

514.
ᐗAMḄÓ1ᓄᱥM(OH)(s)ᙠØḄÙÇÈ:2M(OH)(S)=M2+(aq)+2OH-(aq)>M(OH)(s)+20H-(aq)=M(OH)4"(aq),25࠷,22-Ige.pHḄᐵ»᝞#ᡠ[,cM2+ᡈM(0H)4--uvḄà஺%ᑡ'(┯*Ḅ+A.áâপä⊤-Igc(M2+).pHḄᐵ»B.M(0H)2ḄKspæ1xIO"C.ᔣc(M2+)=0.1mol/LḄcéᐭNaOHcBpH=10Q»ᐗAMì⌕^M(OH)2(s)¹ᙠD.ᔣC[M(0H)4=0.1mol/LḄcéᐭïl0.4mol/LḄHC1ð,»ᐗAMì⌕^M2+¹ᙠñஹòó⚪(3õ⚪ᐳ43ᑖ)15.(15ᑖ)ộ(Te)øùᵨúû□NஹᵯÔஹýþï⚞
Ḅᔠᦈᑭᵨ⌕஺,ᓄḄ(⌕ᡂᑖCuzTe,%ᨵ'(ḄAgஹCu)-./ẠḄ12᝞4:6ᓄAg2s9:;Cu;Te<=ᑡ?⚪:

6(1)ᑏDEᐗGᙠᐗGᕜJ⊤-ḄLM_______________________o(2)“⏚R”T2-UᡂTeOS()4ḄYZ[2\஺(3)^_`(p(Ag2s0Q=7.70x10-5,(AgCl)=1.8X10-nᔣAg2s:-pᐭKsprs⏚,Ag2sO,tᔲᐙᑖwᓄAgCl,xTyz{|(4)ᵯ~◀
ஹồḄᐵ᝞⊤஺ᵯ~(min)᳛6᳛1025%0.1%2040%0.2%3062%0.4%4065%2.0%জᵯ~▤▢᩽Ḅᵯ᩽\ঝᨬᵯ~30min,஺(5)ᔣ“:H”-xᐭSO?,Te(IV)Ḅr¡6.0g/L=¥ᑮ0.24g/L,ᑏDTeOSO4UᡂTeḄᓄ§[2\,ᐸ-TeᐗGḄᦈ᳛(©ᶍ«¬®ᓄ,¯°ᵨ±ᑖᦪ⊤³,´ᶇ¶Lᨵᦔᦪ¸)o(6)᦮ºT2-»¼½ᑭᵨḄᱥ¿(Àᓄ§\)஺16.(14ᑖ)ᾙ᪺⏚Ã⁐ᓫÆᨔ¬,ᙠUÈUÉ-ᨵ⌕ᵨ஺ÊËÌÍᵨ᝞=[Îᑴᜓᾙ᪺⏚`CHOCH=CHCOOHK2c+(CH3CO)2O+CH3COOHÊËÑÒ:

7ÑÒÓÔᑖÕ(/4.0mLÖᵬØÙ10.0mLḄÚ⏚Û(CH3co)2஺ÝÞ100mLßàḄᙊâã1ä-
åpᐭ'æçèé⏚ê
pë145ᑖìí2¯î
ïëðñwᐭò⚠ᙊâãä(èôõôöᵨ)-
÷øèôõôöíôö
ùò⚠ᙊâãä-Ḅᒕûᱥwᐭãü-
ýᓾ
pᐭÿ30L10%3ᓄᕈឋᐭᐭ〉ឋ5min,&'()஺)+ᓾ-ᵨ4/0⏚⏚ᓄ⏚ឋ+ᓾ2ᨔ4ᐰ6᪆8-9):;<=9>-஺?@Aᙠ80࠷EFE>G@A4.44g஺KL:জOPOQḄSᳮUVOPWᐭᨵYZᔠᱥ]᧕ᢵ`ḄᨵYᡂᑖcOPdeOf8ᩭ,hijᑮᑖlmnḄoḄ஺ঝqᐵᱥsḄឋstOPOuvwxyzᑡ|⚪t(1)ᐰḄᵨU0(2)2OPOfḄoḄU஺(3)3ᓄḄᵨU஺(4)49)ᢥ᝞vw,(ᑡᡂ9)஺⌱ᔠ〉Ḅ,ᢥḄ⊡ᐙ᦮:o

8ᙠᧅᐭḄ)f¢£¤ᜮfজᐵ¦¤ᜮ;ঝ£ᜧ¤ᜮ;ঞª«¬Zᔠᱥ;ট®9>(5)¯°4<=:;Ḅ±²o(6)´µ¶·ᵨ“9)”º»W()Ḅ¼½Uo(7)´µ¶ᡠGᾙ᪺⏚Ḅ@᳛Ão17.(14ᑖ)ÃÄÅCO2ÈÉ᛻⌼ᡂḄÌÍ,ηᵨ“CO2Ïᓄᑴᵬ⏣”±²VᐸÔÕᓄᑭᵨ஺´×Ø4ÙÚÛzÜÝ×ØtI.CO(g)+3H(g)TCHOH(g)+80©ã223n.CO(g)+&(g)TCO(g)+HO(g)21H222xyzᑡ|⚪:(1)×ØRIIḄInK(Kç⊤ᓄéê⊝ìᦪ)c(îïḄ᎔ᦪ)Ḅñᓄ᝞ᡠò஺dHi0(ô“ᜧõ”ᡈ“÷õ”ᡈ“øõ”)ᓣúîï,×ØCO(g)4-2H2(g)-CH30H(g)Ḅᓄéê⊝ìᦪ(ô“üᜧ”ᡈ“Ä÷”ᡈ“ýñ”)஺

9(2)þ°×Ø4ᙠᩩ
⊝
ᑡḄᨵoA.ᜧCOḄ,IḄ⊝ᔣᔣB."#$,I%IIḄஹ⌮(᳛*+,C.ឤ$ឤ.
ᐙᐭ12,IḄ⊝ᔣᔣD.ᜧ45,I%II678ᑮ⊝Ḅ:;<=(3)ឤ4
ACO2%CᢥEFG1I3Jᔠ,ᙠ<=MᓄᑺPᵨ
RSI%H,ᙠU=Ḅ:;VᑁCH30HḄ⌱Zឋ%\᳛]$Ḅ^ᓄ᝞`஺CH30HḄᱥfḄgᐸcICH30HḄ⌱Zឋ=X100%ḄCO?ḄᱥfḄgজᙠklᩩ
ᔠᡂᵬ⏣ḄqrᩩsA.210࠷B.230࠷C.MᓄCZTDMᓄᑺCZ(Zr-1)Tঝᙠ230z{k,ᓣ}$CO2Ḅ~ᓄ᳛ᜧᵬ⏣Ḅ\᳛"#,s

10ভឤ$ឤ4.ᘤcᐭ2moic஺2%4moIHRSI%H,452,Po,ᙠ30TCRS,8⊝:,CO2Ḅ~ᓄ᳛50%,.ᘤEF+,20%஺ᑣ8ᑮ⊝:CḄ~ᓄ᳛IIḄ⊝ᦪK=ᶇᨵᦔᦪ஺ஹ⌱⚪ᐳ15ᑖ¡¢CḄ2⍝⚪c⌱¤⚪¥18.ூᓄ¨¤¤⌱©3:ᱥf«᪀ឋf®15ᑖᐰᳫ✌²ᙠ350³´:(Ḅᝍ¶᱐¸ᐶº}»ᑡ¼k½ᡲ5GᢈÁᡭ⌼ḄÄ}ÅÆÇÈÇÉ,ÊËÌÄ}ÅͺḄÎ:;ÏÐÑÒ஺ÓÔ¥
ᑡÕ⚪I15GÖᱏØ⌕ᩞfs}Ûấ஺Ý᝱SiàáâᵯàḄ¶ä᝱ᨵåæᐸᵯà᣸èé⊤ë®Neî3s?3p/óôÌo2}Ûấᑴᜓ÷øcùᨵSiHCbஹSiC14ûc;\ᱥSᡂ஺üý:SiHChÿ“>”ᡈ“ீ”SiCUᵯḄᑏ1ᓽ஺ᵯឋ:H>Si,ᑣSiHC%ᐙᑖ'(Ḅᓄ*+,--30ᐶ2345ᩞ7ᵨᑮMnஹC஺ᐗ>஺জMnḄ@Aᔠᱥᓄ*-DMnCO5CH3CNH,IᑡKLMNḄOPQR஺A.CHCNMnVAWX,YZ[ᵯ\ḄOCV3B.MnVḄAWᦪ6C.CHCN`CVḄᩖᓄbcsp2ஹsp33D.CHCN`஺hᐔhᦪjkl5:23ঝrCo2+=65pm,rMn2+=67pm,tuMnCC3lC0CO3Ḅᑖ(wxP“3”ᡈ“y”(zV{____________________஺4X~600Ḅᑡ5◤ᵨᑮᩞᧇ஺ᩞᧇTiNᐹᨵNaClc᪀᝞ᨔᦪᨔaDlD=IO-10m,ᐸ`▢N3-ᵨ☢+ᨬᚮ3+N3-¡¢£ᳫ¥¦§cᑣrTi3+D,¨©ᓄªḄxg-cm-3ᑡ®¯-ᓽ஺

11•N3-OTi3+Q,O-•—19.ூᓄ*—@⌱´5:ᨵµᓄ*¶ẠD(15ᑖ)ᓄᔠᱥFOᑴᜓ½ᦋᗐṑḨÂᱥḄ`Ã,ᐸᔠᡂÅÆ᝞IÇÈÉIᑡÊ⚪ÇFWCOOHCH30H-FYY^COOCHJCH3I-CLI-ஹ/___________QA.~~~trueᨵµÌÍH2c=(CHCH2BrᨵµÌÍᐭ/ஹ"°ÒᵫAᔠᱥ1)[(CH)CHCH]A1H/3222Í02)NaICVRuÔᓄᑺVV^C00CHr3(DAtBḄ×ØbcO஺(2)ᓄᔠᱥB᪶ᐳÛÜÝḄᔾᦈàᨵá஺(3)ᓄᔠᱥCḄ᪀â-஺(4)D-EḄä,`åæVḄçèéO,åêᓄḄçèéOo(5)ëìὃ⇋ïḄWðñ᪀ᑣᓄᔠᱥFḄòᑖñ᪀ᨵ஺(6)A->DஹDtEóE-FḄô᳛ᑖö70%ஹ82%ó80%,ᑣAtFḄøô᳛஺(7)PdAᔠᱥÔᓄEtFûᓄ`C-Brhüý,þèÔᓄ×ØজÇ×ØজÇ(>B9H)…B°c஺஺0-^COOCH3

12ᨵᑖᓄজḄឋᵬஹẆᑖ!ᔠᡂ$ᨵᑖs-1%᪀᝞()*+஺ᙠᔠᡂSTḄ-./ᵬ0ᵨ$Pdᓄᑺ3ᙠ4ᓄ-./ᵨ56ᑺ◀Pd;80ᵨ9:ᓄᑺ஺Ẇ%;<*=ᨵᵬ>ᑮḄ@Aᓄজ஺S-1᪷CDEFGᵬஹᔠᡂḄs-1@AᓄឋHIJKḄLMN