化学2022-2023学年度高三入学考试

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2022-2023ᐭὃᓄ⚪⚪:⚪:ᡭᓺ:᪥!"#ᵨᑮḄ'()*+D-2N-140-16Na-23P-31Cl-35.5Fe-56Co-59,Iᔁ.ᐳ42ᑖ12ஹ⌱5⚪:6ᜧ⚪ᐳ148⚪9:⚪3ᑖ9ᐳ42ᑖ஺:⚪<ᨵ28⌱⚗?ᔠ⚪A⌕C஺1.ᓄDEFGHஹIJ"ᢝLMNOᑗ'ᐵ,SᑡUV┯XḄYA.Zᜩ\]^_`ᵨḄᐝbᩞᧇYấB.XfghiJjkElm,"noᜧ+Gp᝘rmC.stuv"wxஹyஹz{Ḅs|ᑺ9~"ᵨw᛻ḄmᑺD.Ḅlℳᩞᧇ2219-ᔠg,"2Ḅ*+2.SᑡᓄḄYA.CCCḄ:B.ᨵᱥḄ:2-ᵬ¢£¤OII/C\C.ᵬ¥Ḅ¦᪀¨!HII^2D.Mg2+¦᪀©ª«!

13.®¯S,Sᑡᔜ±²)2#ᙠᢣµ¶ᜧ+ᐳ·ḄYA.0.1mol/LḄNH4HCO3µ¶!K+ஹA௃3+ஹN02ஹCÈB.Kw/c(H+)=KT஺Ḅµ¶3:NH9Na+ஹCu2+>Cl-C.DAlÔÕ#Ö×H2Ḅµ¶!Cu2+ஹK+ஹNO3-ஹSO2-4D.ᵫÛᵯ²ÝGḄc(H+)=IO—2mol/LḄµ¶Ûa+ஹCÈஹSO2->S2~34.àáâãäåæç®ᦪḄé,SᑡUVḄYA.®¯®êS,20gD3()+ìᨵ10n8ᵯ)B.᪗îS92.24LCCI4ᡠìᐳðñḄᦪAY0.4NAC.0.1molNDò+Ḅ×ᐙᑖÔÕ,GᡂNõᑖ)ḄᦪAâ0.2NAD.100mLpH=1ḄH2sO4øHC1Ḅùᔠµ¶9H+ḄᦪAY0.01NA5.ᨵᱥMḄᑖ)¨âC5H10O3,ü#DNaHCC)3µ¶ÔÕÖ×CO2ýl,1molMDò+ghþÔÕ"Gᡂ1molH,ᑣM
Ḅ᪀Ḅᦪ2A.9B.10C.12D.146.ᑡHA!⏚ḄA.#$%NaA()ḄpHᜧ,7B.HA-Na2cO3()12,45CO267C.1mol•<ெHAḄ>()?@⁐BC()DED.ᵨHA()GHᵯឋK%LᐝNᨩ

27.PQRᕜTᐗV/ஹBஹCஹDஹEḄᨬZ[\ᓄᱥ_2Ḅ>ᓄᱥᑖaXஹbMஹZஹW,BRᕜTcdᐗVefghiᨬᜧḄᐗV%#$XஹYஹZஹWᙳ
-M12,AஹBஹDஹEḄfgkᦪlᐸ_20.1moI/LXஹYஹZஹW()ḄpH᝞oᡠq஺ᑡstuḄfgkᦪA.DḄvᓫ6᝱yᓄᱥḄz{ឋᜧ,EḄ6᝱yᓄᱥz{ឋB.AஹBஹC|ᐗVvᓫ}ghiḄᜧ~kC>B>AC.YḄ()-ZᡈWḄ()ᑖa5e12,_2ḄezᙠᦪD.Y-WᱥḄᓄ8.ᑡKஹᡠᑮḄᙳtuḄ

3⌱⚗KᑁKᨔ7(,¡⏚¢%£A()DE¥ᨔ7D¤KSCN()ᵨᓡ§¨ᜳª~ᙽᵨṺᡭ¯°±²ᰚᓄ¶£Bᰚ¸¹A1DËÌÍÎ\ᓄᡂCO?Ḅ67ÇᐭÈÉBᮞ>9.ÐÑÒÓ(Cu)fᧇᑴᜓCuClḄÚÛÜÝ᝞஺H2s(kNaNOsNaSO.Naa23ÑÒÓ|MßI__-B⌲&ஹäåCuClÁNa2s0"Ḅæᔠ)èQ:CuClê⁐ëì%í(,>%¶(,î⏣%ᙠðñḄò6e᧕Î\ᓄ஺ᑡs┯õA.“(ß”
ᵨzò6ᡈø஺2ùúNaN03B.“°û”ᵨᑮḄüᴻþᘤᨵ
ᧅஹஹᴻC.“”Ḅ:2CM++S02-+2C1-+20H-3=2CuCl1+SO42-+H02D.)*CuClḄ+᳛-./,12ᵨ4⏣67ஹ89:;10.<=*>┞ᵯAḄBC2Li+FeS===Fe+LiS,LiPF-SO(CH3)2ᵯL26MNᵨOᵯAᵯPᵯLQR⏚ឋUVWXᑮᓫMNiḄ\]^_᝞aᡠc஺eᑡghijkḄl

4A.ᵯ᩽YLiB.ᵯLnop,bpNaClqrḄᱥMḄtu/viwxyC.X᩽CFeS+2Li++2e-===Fe+LiS2D.zvap□|}ᣵNvaஹbᔠW,ᑣᵯLBoCᦋ11.eap,C%⊤cᱥᙠpḄᑖQtNᔠeaḄl«00t400tA.4NH(g)+5O(g)A4N0(g)+6HO(g),JH=-808.7kj/mol322B.NO(g)=N0(g)+N0(g),4H=+41.8kj/mol232C.3NO(g)+H0(l)U2HNO(1)+NO(g),dH=-261.5kj/mol223D.C0(g)+C(s)=2co(g),AH=+171.4kj/mol212.ᓄ(VCI2)l⌕Ḅᨵᔠᡂᑺ,ᐹᨵḄᔾឋ஺y¡¢nVCI3ᑖLᑴᜓVC12,eᑡgh┯¦Ḅl

5ᵬ4¨©A.ᴻ«mḄᵨ:®⊝°±N²r³ᑭµeB.ᵬ^_p·+1molN,¹ºᵯᦪ¼3N2AC.^_ᔠᳮḄ¾¿³À:aTCTb—d—eTfD.ÇpḄᑺ1ÈVCaCk13.ÊË✏⏚lÍ⇾ÏÐÑᱥp)ÒᑮḄ⏚ឋᱥMNᐸÔ᪀᝞eaᡠc,eᑡÖ×jkḄlB.OᱥM>²ØVᡈ*═⏚Ûqrº⁐,i>ÝFeChqrß⁐C.1molÊË✏⏚Ýà,ᨬâãὑ9molH2D.1molÊË✏⏚ÝætNaOHqr,ᨬâãὑ6molNaOH14.çètḄFeSÝætḄué⏚,êëXqrpQᨵFe3+-SO4ᡂNO>NOḄíᔠ°11.2Lî᪗ðñòóNôõ°Ýçèö஺2î᪗ðñòóíᔠê¢ᐭVpN2ᡠᨵ°øᐰúVᔾᦈᡂé⏚,zᔣqrpýᐭætḄNaOHqr,øᐰê,+þ⋎⁐
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10.7g,ᑡḄ

6A.!"Ḅ#⏚ḄᱥḄ0.9molB.&ᔠ()*NO2+NOḄ),-.3:2C./!"0*12Ḅᵯ4ᦪ0.6NAD.6ὑḄ8(),6.72L(᪗;)IIᔁ(ᐳ58ᑖ)=ஹ>⌱@⚪:ᐳ5D⚪EFG58ᑖ஺15.(10ᑖ)JKL┞N4ᵯOḄᨵᦔᜐᳮTUᐙᑖᑭᵨYZஹ[\]᛻ஹ■`ab஺UcdᐺfḄ⏚g-
ᜐᳮi⏚┞(LiCoOz)ᵯOḄj0஺klᙠ┞N4ᵯO᩽ᩞᧇi⏚┞Ḅ⊤☢ᒹ⌚cu8ᓄw,xyz{ᐸ}ᵨ~஺废旧8ᓄw钻酸)ᑖ⌱锂电池Li2cO3U⚪:(1)ᙠᜐᳮ᩽ᩞᧇlJᐸẆEḄ(2)“”!"Ḅᓄ0(3)ᙠ“*”,⌱ᵨ⏚,ᑣ◤ᑴ⏚ᨬ¡⌱ᵨ¢£¤⏚஺A.¥⏚B.=8ᓄC.=8ᓄ¦D.§¨⏚

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i”!"ḄN40஺(6)Co(0H)2ᙠ°(*ᯏ²Ḅ³)´ᶇ᳛·¸¹ºᓄ᝞¼ᡠ¾,500࠷ᒕÁ³)Ḅᡂᑖ(Ãᓄ)B(500T.86.38%)908C4(2905C.89.25%)\C(1000,80.65%)11A02004006008001000¸¹Ä16.(13ᑖ)ÆÇᓄÈ(NaN3)cd⌕ḄᓄÌÍÎTᵨÏᔠᡂᢙÑᜮÓÔÑÕᱥᵨÖ×ØÙᐰ(ÛḄ(Z஺ÜÝÞTkUj0ᑴᜓÆÇᓄÈàáâᐸã¹஺U⚪äI.ᑴᜓæçÈ(!"èᳮ:2Na+2NH3±2NaNH2+H2)ÜÝëì᝞¼ᵬ஺îïäæçÈ᩽᧕ñò᧕ó°(8ᓄ(1)ôᘤaḄöoÜÝ÷ø,"ᐜᡭ÷ᑖûüᧅ}þæñÿᐭ
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8(2)জBḄ⌱ᵨ஺A.PPO25B.ᮞC.⏚D.ᓄঝB,CᡂḄ!"#Ḅ$%&(ᵨᓄ()*+⊤-)஺II.ᑴᜓNaN3ব2IᑴᜓḄNaNHz340ᙠ210-220࠷Ḅᩩ89$%ᡂNa^ஹNaOH;<,$%=ᘤ?⌱ᵨ@ᴻᩞCḄDE(ᵨᓄ()*+FG)HI.IJNaN3ḄKLMNOP0.1500gNaN3᪵
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9ঝ·¸ᩩ89
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½¾IXஹ¿ZḄᱥCḄPᑖÀ&2m01ஹ3.6molஹ2mol.ᑣÂ$%᜜Ä(Å“>”ஹ“<”ஹᡈ"=”);(2)}γ$%,ÏÐÑÒ©⊝iÓZḄÔᑖÕP,Ö×ØÙ$%µ᳛ḄÚÛ—(ÅÝÞ)¶a.ᓣÒLb.2©⊝iÓḄZ(g)ᑖàzᩭc.ᔣ©⊝iÓã¦ᐭÄJPZ(g)d.¦ᐭÄJPä<ÐåᜧiÓæçe.ᦋ&ᙠឤæ=ᘤ$%f.Øᐭᔠ〉ḄéᓄᑺII.êÐCO?ஹz&DᧇᔠᡂCH30HḄ$%Dᳮ&:C02(g)+3H(g)=CHOH(g)+23HO(g)4H=-49.5kJ-molT,³$%ᵫîïᑖð$%᪀ᡂt2òÄð:C0(g)+H(g)=CO(g)+HO(g)dHi=+40.9kJ-moL222òóð:CO(g)+2H2(g)=CH30H(g)AH=-90.4kJ-mol-12ôG9ᑡö⚪t(1)ÄJᩩ89
ᔣij&2LḄឤ=¥=ᘤ¦ᐭ1mo௃CO2;3molHzᔠᡂCH3OH,$%§ᑮ©⊝,=ᘤCH30H(g)&0.4mol,CO&0.2mol,Âz0⁐)ḄúL&mol-L-1,òóð$%Ḅ©⊝ᦪK=o(2)?¸æç9,ᢥ᯿n(CO):n(H)=1:3ᢗᧇ,þIJCO2Ḅ©⊝°ᓄ᳛ÿ
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10PlஹP2ஹP3ᵫᜧᑮḄ
Ti#$%ᩩ'()*+,-.Ḅo18.210ᑖ567ᕜ9ᐗ;<ᐸᓄᔠᱥᨵABḄᳮᓄឋE<ᵨ⌶$HIJᑡL⚪:215O᝱QR᪶᜜ᵯRḄVWX᝱ᨵY$ᵯRᡠᜐᨬ\]^_⍝ḄaXO225NRdHRfgaᡂiYjk$᝞:NH3ஹNHlஹNHmN2Hᵯᴄ\N2H┐q,ᙠMHjvNRḄᩖᓄxy,zᵨᕖ+}qᵯR~ḄᑖRᨵ2ᑏ-Y5235LiFeP254ஹLiPF>LiAsFedLiClqf⏣┞RᵯḄᵯ᩽ᩞᧇ஺ᵯᵯ6#,Li+⏣ᑖRvḄᔣ᩽Ḅ᝞ᡠ2v▢R¢£5஺¤¥ᩩ¦J$ᵯ᩽ᩞᧇ2§“LiPF6”ᡈ“LiAsF6"5vḄLi+¬$O245PCh]aᡂRᨔ~$°ᨔ~Ḅ±xᨔ²᝞ᡠ:

11³RO´Rµᨔ²¶·apm,NA¸¹º»¼½ᦪḄ¿,ᑣ°ᨔ~ḄÁ
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12NO,ÕHI(1)ᓄᔠᱥAḄØÙKḄÛ]ÜØÙo(2)ᓄᔠᱥEḄÞ᪀ày-(3)/-KḄãäåæ-çèᡂéᐗêXᓄᔠᱥḄëãä,°ëãäḄᓄìxyo

13(4)BḄ¥ᑖí᪀~vî,ï✏ᓄᔠᱥḄñ]òèóôãä,õêö÷ᨵçøùOḄYúᨵY஺(5)ᑏ¥#ûᔠJᑡᩩ¦ḄᓄᔠᱥCḄ¥ᑖí᪀~ḄÞ᪀ày(üᒹþ±~í᪀~)জᒹ
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-COOHஹ-NO2ঞ
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