江苏省南通市如皋市2022-2023学年高三上学期期初教学质量调研化学试卷(带解析)

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ḕᓭ᝞2022-2023ᦟẆᓄ⚪ᔁᑖ100ᑖὃ75ᑖᵨᑮḄH1C12N14016S32C135.5Mn55Zn65⌱⚪(ᐳ36ᑖ)ᓫ⚗⌱⚪⚪ᒹ8!⚪"!⚪2ᑖᐳ#16ᑖ஺"!⚪%ᨵ'⚗(ᔠ⚪*1.ᐸᓄᔠᱥḄᓄᐹᨵ"⌕$ᵨ஺'ᑡ)*+,Ḅ-A.ᐗ0ᙠ2ᯠ45ᙳ7ᓄᔠ᝱9:;ᙠB.=>5᣸@ASO2E9ᡂ⏚HIJ⏚HḄpHEMNOPQRSTC.VW'XH2s04\]^ᱏ`ᓄ-abX⏚ᐹᨵῃdឋD.ᑖᦪb49%ஹlmb1.4g.cm-3⏚IᐸᱥḄXmb2.8mol.L“ூzᫀ௃Bூ}᪆௃ூ}௃A.ᐗ0ᙠ2ᯠ45\7ᓄᔠ᝱9:;ᙠI\7᝱Ḅ9:;ᙠI᝞-SᓫIᦑA┯B.SO2dᡂ⏚R]HdḄ⏚ឋPIMḼNOPQI⏚>ᓄᡂ⏚I⏚ឋPRpHSTIᦑB+,C.XH2s04\]^ᱏ`ᓄ-abX⏚ᐹᨵᓄឋIᦑC┯D.⏚ḄᱥḄXmbc=100°P=I00஺*L4x49%mol/L=7.0mol/L,ᦑD┯M98ᦑ⌱B2.'ᑡᙠᢣᩩ'\ᜧᐳ;Ḅ-A.¡ᐭAFeSCU¦§5¨Cu2\Mg2+ஹBrஹSOB.¡ᐭA®¯°KA1(SO4)2-12H2஺´¦Ḅ§5¨Ba2\NH¨ஹChNOC.¡ᐭANaClO¦Ḅ§5¨Na+ஹFe2\CH3co0ஹCPD.¡ᐭAHIḄ§5¨K+ஹFe3+>ClrSO¨ூzᫀ௃Aூ}᪆௃ூ}௃A.Fe2\CiP+ஹMg2+ஹBrஹSOᔜ½O¾¿$IÀ7ᜧᐳ;IᦑA+,B.Ba?+ÂSO

1;¿$ᡂ⏚ÄÅÆI¾\ᜧᐳ;IᦑB┯C.CIO-ÂFe2+ÇᓄÈÉ¿$I¾\ᜧᐳ;IᦑC┯D.IÂFe3+ÇᓄÈÉ¿$I¾\ᜧᐳ;IᦑD┯zᫀ⌱A஺3.'ᑡÊË:Ìᑏ+,Ḅ-A.ÎÏÐᢗᐭd5¨2Na+2H+=2Na++H?TB.ᔣAICI3§5¡ᐭANaOH§¨A13++4OH=A1O-+2HO2C.ᔣÓd5ᐭASO2>Ô¨2NH.HO+SO=2NH+SOf+HO3222D.ᔣNaNChÕឋ§5¡ᐭ╅ר3Mg+2NO+8H*=3Mg"+N2T+4Hqூzᫀ௃Bூ}᪆௃ூ}௃A.ÎÏÐᢗᐭd5ÊË:b2Na+2H2O=2Na++2OHTH2T,ᦑA┯B.ᔣAICI3§5¡ᐭANaOH§IÊË:bØÙ+4€Ú=Û02+2Ü0,ᦑB+,;C.ᔣÓd5ᐭASO2>ÔIÊË:bNH/HQ+SC)2=NH¨+HSO,ᦑC┯D.╅bÕÎÏI¾EÝÕ¿$IᦑD┯ᦑ⌱B஺4.ᙠÞᩩ'I'ᑡᡠàᱥOḄᓄᙳ\áâḄ-A.NaCl(aq)co>NaHCO(s)NaCO,(s)32B.FeC"aq)—^~>Feã>FeQ”C.MnO^->C1h-->HC1O22D.CH3CH2OH----Ag(XI-l)2°"——>CHUCHO—CHὡH-CNAOHூzᫀ௃cூ}᪆௃ூ}௃A.åᓄЧ5ᐭÓ>Âæᓄç¿$ᡂç⏚èÐIéê¿$ᱥÓ>IA┯B.ëÂåᓄ^¿$ᡂåᓄ^ÂåᓄëIB┯C.æᓄ═ÂXí⏚¿$ᡂå>Iå>Âd¿$ᡂîå⏚Âí⏚Iᓄ\áâIC+,D.ï⏣¾\ÝñÓ§¿$Iï⏣Ý>ÇòᓄᓄᡂïóID┯ᦑ⌱¨Co

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MnO+2e-2+4H+=Mn2++2H2O,᩽{SO_c^_◞-~ᑮn{ᦑII{

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ûêRNaSO.1OH,O+4C'M'>4CO+NaS+1()HO«ᐭ
⏣NaS,◀ᓄ24222ᱥ᯼ᵨ95%
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7ூᫀ௃Dூ᪆௃ூ௃A.⏚`r*+ᡂ⏚%⏚ஹ⏚~ᓄᡂ⁐s%A┯7B.ᓽhqrᓄ%rᓄhj⏚ᡂ~ᓄh%~ᓄhhᡂ~ᓄh%hTKSCNdf⁐%B┯7C.syᡈ£ᑖy%df¤⁐%C┯7D.|ᑴ~y`Gᨵ~yᡂḄ¥~⏚%¥~⏚ᐹᨵឋT{d¦⁐%D@Aᦑ⌱D஺12.ᵯª«₝⏚hC3®⏚h┞ᵯªḄ°ᧇ%ᵨC᯿³´µᑺ·஺PQ¸¹᝞)*+ᑴ[FeC2O4஺Fe?++H2czC\uFeCzOqÇ+2È,Ê˸(;4K(HC20)=6xlO-2>K((HC2O)=6xl0\al24a24Ks(FeCO4)=lxl0-6,)ᑡØÙ@AḄDP2A.0.10mol-L-1Na2c2O4d0.10mol-L-1NaHCzCUdᡠGÞßàáâᐰ³äB.NaHC2O4yḄRåæ34HCO+HO^CO;+HO+24223C.¸(;0.10mol-L-1NaHCzCUdᕈëឋD.¸(;*+Fe?++H2czOLFeC2஺%J+2H+Ḅí⊝ïᦪK=3.6ூᫀ௃ADூ᪆௃ூ௃A.Na2c`C2஺4ñᙠyí⊝%NaHCzCU`HCQ4ñᙠᵯí⊝yí⊝%ᡠGÞßàáᨵNa+ஹH+ஹOH',CO,HCO,H2C2O4.H2O,õὅâᐰ³ä%A@A224B.NaHCzCUyḄRåæ34HCO+HOHCO+OH-,B┯7C.NaHCzCMdḄᵯí⊝242224ïᦪ3Ka2((HC2O4)=6xl(y5,¸(;yí⊝ïᦪ3K.=ú^^^=û'=JX10ý<,KC(HCO)ÿ6x10~624ᑣᵯᜧᕈ⏚ឋC┯D.Fe?++H2c2O=FeCqJ+2H+Ḅ(⊝*ᦪ44K-"Hb_c(H')'c(HGO)c(CQ,)__6xl02xbxlO-5-c(Fe2+)c(HCO)c(Fe2+).c(CO').c(HC,O).c(HC,O)^(FeCO)2242244sp24ᦑ⌱,ADo

813.9:;<=>⌕ḄᨵAᓄCDᧇCFGHI:ஹK:LDᧇᑴN9:Ḅ᝞P:CHSgU+CHSgU2CHSgUAH=akJmor',<]Pᔣ_`LVLcdeᘤgᐙᐭ1mol482436C4H8SgUk1molC2H4SgU,lmC3H6Ḅ_`ᑖᦪopḄqᓄ᝞rgsIᡠv஺Pᑡyz{-Ḅ;A.C4H8SgU|}Ḅ~ᓄ⊤vLC4HsSgU+6O2SgU=4COSgU+4HOSgUH=-2539kJ/mol22B.a=148C.PḄ(⊝*ᦪL64D.rgsH;ᐸᩩ<]ᙠூᫀ௃BCூ᪆௃ூ௃A.|}~;1molᱥC4H8SgUᐰ|}CO2¡_k᝱£¤~¥;2539kJ,¦§;¡᝱ᐸ|}~Ḅ~ᓄLC4H8SgU+6O2SgU=4CO2SgU+4H2OপAH=-2539kJ/mol,A┯B.᪷ªᱥ|}~m~ᓄL,জC4H8SgU+6O2SgU=4CChSgU+4H2Oপ4=-2539kJ/molঝC2H4SgU+3O2SgU=2CO2SgU+2H2OপkJ/molঞC3H6SgU+4.5O2SgU=3CO2SgU+3H2஺প”=-2049kJ/mol,᪷ª±²]³´জ+ঝ-ঞx2,᦮ᳮmC4H8SgU+C2H4SgUU2c3H6SgUA“=+148kJ/moLᡠHa=148,B{-c.᪷ªC4H8SgU+C2H4SgUU2c3H6SgUº,;»¼¡_ᱥḄ¥§qḄ஺½ᑮ(⊝C3H6Ḅ_`ᑖᦪ;80%,ᑣ”SC3H6U=2moiX80%=1.6mol,ÂὑC4H8SgUஹC2H⍎UÅ;0.8mol,ᦑ(⊝”SC4H8U=”SC2H4U=1mol-0.8moi=0.2mol,ᵫeᘤḄe`;VL,ᑣ½ᑮ(⊝ᓄ

91.6mol)2VL(⊝*ᦪ=64,C{-;0.2mol0.2mol----------x-----------VLVLD.ᓣÉ᳛Ë̽ᑮ(⊝ᡠ◤pÎÏÐᓄ(⊝ᔣᔾᦈḄ{ᔣÓÔÕÖC3H6Ḅ_`ᑖᦪ×ᜧØrÙ§ÚᔠᦑÜsH§;ᙠP஺ᦋqᩩ;×ᜧÞßàᡈâᵨÞäᓄᑺD┯ᦑᔠᳮ⌱⚗;BCoç⌱è⚪14.᪷ªêëìᑏᡈîïð஺S1UBMOSBi2MoO6U;<=ᦔᐝäᓄᑺᵨᐝäᓄôõö÷⏚ឋᩩPôõöḄDᳮ᝞Prᡠv஺জøs᪾ᑁBMOôõöḄðîïL,ঝᑏ¤5ØõöḄû,஺S2UüᓄýHþgᑏ¤û,oூᫀ௃S1Uজ.C6HQH+7O2>6CO+3HOঝ.3c6H5OH+28O+28H+=18CO2t+23HO2222AgCl+2NH3=[AgNH]++C1-ூ᪆௃ூ!"1#௃জ᪷&'()*+᪾ᑁBMO012Ḅ456789ᱥ;12<=>)?ᡂᱥ;A=ᓄC6co2+3+0ᦑOᫀJ7C6H5OH+7O2>6co2+3+0ঝᵫ'R()C6HsOHRT5=ᓄ?ᡂD

10)JᧇᑴᜓBi2s3Ḅ5᝞:FeChஹHC1Fe>⏚CHCSNH32SஹSiO2ᕜVA஺BiḄᵯV᣸XJ஺(2)Biᐗ¡GBi3+¢X£ᙠ\[6)ᑏ¦Bi2s3ᡠ§?89ḄUVW5X7o(3)¨Ḅ[6c(Bi3+)=0.4mol-L-',c(Fe3+)=4.0xl0-2mol-L',c(Fe2+)=1.2mobLl,ᑣJ°■²᪆³=ᓄᱥ´µ)◤¶ᑴ[ḄpH¹;஺(º(Ksp[Bi(OH)3]=4xlOE,Ksp[Fe(OH)3]=4xl0ᔩKsp[Fe(OH)2]=8x10¾6)(4)v¦¿À§?Áᣚ89ḄUV;஺(5)=ᓄᡠÃᱥ;&2஺3,⏚[ᡠÃᱥ;Bi(NO3)3,᝞ÅÆᵨ>=ᓄ)ÇÈᵨ⏚⏚[ÉRÃᑮBi(NO3)3,ᐜᵨ>=ᓄÌᵨ⏚[ḄÍÎ;o(6)bᓄ¦)ᔣBi(NCh)3[ÐᐭbÒÓ⏒Õ(CH3CSNH2),R᪆Bi2s3´µ)Ö×ஹØÙRÃÚÛḄBi2s3,bÒÓ⏒ÕḄÜ᪀XR⊤ßJ஺ூOᫀ௃(1)6s26P3(2)BiS+6Fe3+=2Bi3++6Fe2++3S23(3)pH<2(4)Bi3+(5)âx⏚Ḅãὑ)å■²?ᡂᨵæ>çA=ᓄèHS(6)H—N—Hூ᪆௃ூᑖ᪆௃o┱q(r⌕tBi2s3,vtᨵxyFezChஹSiChᩖ)6ÐᐭIHFeCbஹHC1,FezCh[\ì⏚?ᡂFeCb,Bi2s3TFeCb=ᓄJS,FeCbTvJFeCL;4ÃîSஹSiO,6tᨵBiCbஹFeCLஹFeChÐᐭFe)ïBi?+vJBiñ>ïBi=ᓄJG2஺3,Ð2⏚[?ᡂBi(NO3)3,ᵨCH3CSNH2bᓄ)R?ᡂBi2s3஺ூ!"1#௃Biᙠᕜ⊤6ò\ᕜVA,ᑣBiḄ6ᵯVóᨵ5ôᵯV)BiḄᵯV᣸XJ6s26P3஺OᫀJ76s26P3;ூ!"2#௃Biᐗ¡GBi3+¢X£ᙠ\[6)ᑣ¦Bi2s3¿FeC13§?=ᓄv89)?ᡂBiCbஹFeCbஹS)ᡠ§?89ḄUVW5X7Bi2s3+6Fe3+=2Bi3++6Fe?++3S஺OᫀJ7BiS3+6Fe3+=2Bi3++6Fe2++3S2;ூ!"3#௃

11¨Ḅ[6c(Bi3+)=0.4molU,ᑣ0.4x~(OH-)=4xlO-3i,(OH)=lxlO-10,pH=4c(Fe3+)=4.0x10-c2mol-L',ᑣ4.0x10-2x(?(OH-)=4x10-38,(OH)=lxlO'2,pH=2c(Fe2+)=1.2mol-L',ᑣ1.2x/(OH-)=8xl(yc0c(OH)=1.7xlO«,pH=6.2„ᑣJ°■²᪆³=ᓄᱥ´µ)◤¶ᑴ[ḄpH¹;7pH<2஺OᫀJ7pH<2ூ!"4#௃ᵫᑖ᪆R()v¦¿À§?Áᣚ89ḄUV;û3+஺OᫀJ7Bi3+ூ!"5#௃=ᓄ¦)§?89J74Bi+3O2=2BiO3>BiO3+6HNO3=2Bi(NO3)3+3H2O᝞ÅÆᵨ>=ᓄ)ÇÈᵨ22;⏚⏚[)§?89J7Bi+6HNCh(üBi(NO3)3+3NChT+3H20,þÿ
ᐜᵨᓄᵨ⏚Ḅ⏚Ḅὑ■ᡂᨵ!ᓄ"஺$ᫀ&⏚Ḅὑ■ᡂᨵ!ᓄ"'ூ)*6,௃HSHS./0⏒2Ḅ3᪀56⊤8&H—C—C—N—Ho$ᫀ&H—C—C—N—H஺IHHூ@௃⌕BCDEF8GHI◤KᑴMNc(H+)ᜧTUVWHIXḄc(H+),ᓽMḄpH)TUVHIXḄpH஺16.CIO?`abᦔdeᑺ6ᵨTdghij஺C1O2lmឋopqr6sC1O2tᓄ&ulmḄNaCIChxy஺`aᵫNaCIChᑴ{NaCIChᨔḄ}~᝞NaClOa----ᑴClOz|------»|ᑴNaClO2M|----»|ᑴNaCIO?ᨔ|bT60࠷XNaCICh᧕ᑖ&NaCIChNaCL(1)ᑴCIO2.ᔣᵨ.⏚⏚ᓄḄNaCKhNᐭᨵ(ᵨ)ḄSO2Ḅ6ᑴC102஺ᐸᩩ`mᐭḄS02ᡠC1O2Ḅs)¡¢o(2)ᑴNaCIChM஺s`mḄCIChᐭNaOHH2O2ḄᔠMNᐙᑖ¥¦6ᑴNaCIChM஺ᵫ§¥¦6¨©u¥¦ᱥGᱥN«a¬Ḅᓄឋᜧ)஺®ឋᩩ«a¬Ḅᓄឋᜧ)¯°&>_______஺(3)ᑴNaCIChᨔ஺NaCIChḄ´µ¶᝞·ᡠ¸஺¹ºᵫ»ᑖᦪ&10%ḄNaCKhM(¾NaOH)ᑴ{NaC10-3H0ᨔḄ¿ÀÁᫀ஺22

126o5o8赵/4o裳3o程(4)NaCIChᨔBᵨXᔣᐸNÂᐭÃ⏚ᓽ6ᑮCICh஺¥2o1O¦GᱥNÅᨵ`a`aÃᑣὑImolNaCICh,6ᡂCIO2Ḅᱥ»Ḅ&஺(5)C102Ç6s®ឋÈÉNḄCN-ᓄ&N2CO',ÊËtᓄ&ChÌÍmÎÏÐÈÉNCN-¾&1040mgLLᜐᳮ§ÈÉlOn?,ᳮÓr◤⌕ᐭ᪗ÕÖ×CIO2Ḅ&ØᓣÚ(ᑏ
ºÜ~)__________ூ$ᫀ௃(1)S02ÝCKh⌼ᡂ)(2)C10>O22(3)sMÂßàá´ᶍãT60࠷,äåᓾàá´ᶍbT38࠷X3ᨔçèé(4)0.8mol(5)8960Lூ᪆௃ூᑖ᪆௃NaCIChMNÂᐭ.⏚ᯠᐭSO?✌ᐜW¥¦2NaClO3+SO2=NaSO4+ClO2T,sC஺ᐭNaOHH2O2ḄᔠMN¥¦¡ᳮ&22ClO2+H2O2+2NaOH-2NaClO2+O2+2HO,sNaCIChMÌ`íᑡïᑮNaCIChᨔðñᑖ᪆2$஺ூ)*1,௃ᑴC102W¥¦Ḅ¡ᳮ2NaClO3+SCh=Na2SC)4+ClO2Tᐸᩩ`mᐭḄSChᡠC102Ḅs)¡¢S02ÝC102⌼ᡂ)'ூ)*2,௃sCKhᐭNaOHH2O2ḄᔠMN¥¦¡ᳮ&2cle)2+H2O2+2NaOH=2NaClO2+O2+2H2O,ClᐗóᓄᔠôõãᓄᑺC102,஺ᐗóᓄᔠôᓣb02ᓄGᱥᵫᓄᑺḄᓄឋöTᓄGᱥᑣᓄឋC10>O2'2ூ)*3,௃ᵫ·6NaCICh⛳MNá´ãT38࠷X᪆
ᨔNaC1023H20,á´bT38࠷X᪆
ᨔNaC10,ᡠ¨øNaCIChMNùNaCIChḄïsMÂßàá´ᶍãT60࠷,äåᓾàá´2ᶍbT38࠷X3ᨔçèé'

13ூ)*4,௃NaCIChÂᐭÃ⏚ᡂCKh`aÃNaCl,Wûüᓄ¥¦¥¦Á~5&5NaClO+4HCl=5NaCl+4ClO2T+2HO,ᑣὑImolNaCICh,ᡂCIO2ḄᱥḄ0.8mol22ூ5!"௃CN-%C+2&ஹN-3&)C102+,-ឋ/0%ḄCN-ᓄN22CO3,456ᓄCl\89Ḅ:;<=>2C1O2+2CN+4OH-N2+2CO+2஺-+2H2஺)/0%m(CN')=1040g-L-1x103x1Ox1O^L=10400g,IJKL=400m஺M,ὑ400mHCQ,᪗PQRSCOḄTUV=nVm=400molx22.4L/mol=8960Lo17.ᨵ]ᱥGḄ3_ᔠᡂab᝞Sdᡠf(89ঝḄᩩijᑡl):(1)89ঝ+◤Ḅ89ᱥ2ᩩio)(2)ᓄᔠᱥEḄq᪀s>(3)89ডḄ89uvoCOOCH3Ḅ3_wᑖy᪀TzᔠSᑡᩩi)ᑏl|wᑖy᪀TḄq᪀s>:(4)}~ḄCC14⁐)}Na89lH2,}NaHCCh89;II.ᑖ;%3ᐗ23_ᓄ᛻wḄ;஺(5)?+?CH$CH?ONa>OO+CH3OH01,3-ஹCH3COCH3CHCOCHCHCCHCOCH33323CH30H2CH3cH2ONaᧇᑴ%஺஺ᚈḄabd(¢]£ᑺ¥ᨵ]ᑺ¦ᵨ)஺Oூ¨ᫀ௃(1)89ᱥª«⏚)ᩩi®

14CH3CHCOOCH3¯3°±89ூ"᪆௃ூᑖ᪆௃A´ᡂ89)µ¶·¸¶ᡂB,B´±89)¸¶·«;ᡂC,CᡂD»ᐭ½¶DᡂE,EᡂFqᔠEᓄ>ஹFq᪀s>)DᡂE¿ᓄ89)Eq᪀s>CH3-CHC00CH3.F%«;À±,´±89ÁGூ1!"௃B´±89)¸¶·«;ᡂC,◤⌕89ᱥª«⏚)ᩩi®;ூ2!"௃CH3CHCOOCH3ᵫᑖ᪆)ᓄᔠᱥEḄq᪀s>ூ3!"௃89ডF%;À±)´±89ÁG,ᦑuv±89;

15ூ4!"௃COOCH3Ḅ3_wᑖy᪀TzᔠSᑡᩩi:OI.}~«ḄCC14⁐ᑣᨵ⛳2Æ}Na89lH2ஹ}NaHCCh89)ᑣᨵ¸¶½¶;II.ᑖ;%3ᐗ23_ᓄ᛻wḄ;)ᑣDZ¶ÈÉឋÊË;COOCH3Ḅ⛳2Ì3,ÍÎÏᨵ2;ஹ3Ð;)ᑣwᑖy᪀Tq᪀%9|Oᨵ1ÑÆஹ1Ò¶ஹ2¸¶ÍÈÉឋÊË;I)3-ÓÔᡂ89»ᐭᓴÖ;)ᯠØ´CᡂDḄ89ᳮ»ᐭ;ᡂÊ⏚)⏚⏚2ᵬ⏣ᡂᡂ¿)¿ᙠÝ⏚ÞßᵨS´¯5°àáḄ89ᳮᡂâ᪗Áᱥab:3)H+HRrCHQHCH2=CHCH=CH2-kJCHzBrCH2cH2cH2BrfHOOCCH2cH2cH2cH2coOHªç⏚)Al)Mg2)CO2COOCH3CHaCHgNa+CH30H0o18.ᨵ]ᱥHÓÔ᝞Sabᔠᡂ:¯1°89জ%FH

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17Æᡂ)ûüøùý89)ᑣᡂᑖ;>C9H2O4ḄéÁᱥ)|éÁᱥḄq᪀s>CHOூ2!"௃6ᓄঞCᑖ;%Ḅµ¶2CH3NO2´ᡂ89ᡂD,ᦑ¨ᫀᡂ89஺ூ3!"௃6ᓄঠ%ᱥXḄᑖ;>C7H60,⛳2ÌQ=7X2+2-6=5,þÿᨵ4⛳ᑣᨵ21⛳EXᡂF,ᔠFḄ᪀Xூ4௃0HEEḄᑖ!᪀"#$%&জ()a-*+⏚-.FeCb/012⁐4ᨵ-CH(NH2)C00Hஹ78+9ঝᑖ;<46ᓄ>᛻Ḅ@EḄ᪀ABC9E<ᐳᨵ12CE;⛳5,ᑣ$%ᩩGHIj|-CᚈKḄᑖ!᪀"HaC-kJLcᙢ஺1-CH—COOHO2ூ5௃CHOAZ᱄CH,EᧇᑴX“°⚗`/bP᯿ᨵRᱥHḄᔠᡂTUVCH3NO2ஹHO,OHCHOCHOCHOAAH3c᱄CH,1XYᡂ”CH3NO21OᡂᡂOHIτOHOHOHOH91Eᡂ

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