2022-2023学年重庆市缙云教育联盟高三（上）质检化学试卷

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2022-2023
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13<.1,4-ᡂᨵ2<ᡂ~ᱥᦑஹ>2ᢥᱥAḄDEF"1G1ᡂJᡠ~ᱥᨵ5<ᦑDefᦑ⌱GA஺ூ௃⚪ὃᨵᱥḄU᪀(ឋAY\ḄU᪀ஹឋA>ᓄᳮNᐳSᚗḄ1,4-ᡂ⚪ὃ|ᑖ᪆ᳮYஹᮣᵨḄY஺5.(3ᑖ)cᑡ£¤efḄ()A.DeஹI3cஹ14c¦§Ḅ¨/r1B.©⏚«¬ஹ®ᓄ¯¬ஹ⏀±ᙳY³´µA¶ឋC.C02ஹNO2ஹS02Ḅ·¬¸⏚ឋ¹ὅᙳ"⏚ឋºᓄᱥD.´µA¬ஹ»¼¬ஹFe(OH)3½1ᙳY~¾¿Àᦔூᑖ᪆௃A.<ᐗ¨ÃᡂḄᓫA"ᐗ¨Ḅ¨/r1GB.®ᓄ¯¬³´µAÄ᪆C.⏚ឋºᓄᱥᢣY(ÆᡂÄ(·ḄºᓄᱥD.¾¿ÀᦔᢣGÇÈᐝÊË̽1ÍᐭÏᐝḄᚖÑÒᔣÔÕᑮ½1×ØÙḄᩩᐝÚḄ“Ûܾ¿ÀÙݽ1ᱯᨵḄឋA஺ூNO௃NGA.I2cஹ"cஹ14cḄAᦪVàᦪ"ᐗ¨Ḅqá"â¨ᓫAᦑA┯_B.®ᓄ¯¬³´µAÄ᪆+©⏚«(ã⏣ᙳY³´µA¶ឋᦑB┯_C.⏚ឋºᓄᱥᢣY(ÆᡂÄ(·ḄºᓄᱥNO2>ÆJ◀æᡂÄ(·çᡂNO,⏚ឋºᓄᱥᦑC┯_D.´µA¬ஹ»¼¬ஹFe(OH)3½1½1ᨵ¾¿ÀᦔᦑDefᦑ⌱GD஺ூ௃⚪ὃæ⏚ឋºᓄᱥஹâ¨ஹᑖ/᪀1Ḅᭆé(´µAஹ½1ḄឋAêḄᑖ᪆ᑨìí⌕ºᓄᱥḄᑖï᪗ñḄᳮNᵨ6ẠN⚪ᐵ⚪ô)ᜧ.6.(3ᑖ)ᙠ`ᩩbc÷ø2ùᵨcᑡᔠᡂᵬ⏚GCO2(g)+H2(g)=HCOOH(g)AH=-31.4kJmol1,cᑡᨵᐵ£¤efḄ()A.ᓣdü)e⌮þ᳛


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7B.ᓄ⊝ᦪ8()ᨵᐵ7C.ᓄᑺ8#ᦋ;!"6᳛<#⊝%=>?7D.!"ASVO,AH<0«ூ@A௃@BA.ᓣ)2ᓄᑖ34ᑖᦪ5!"6᳛
ᦑADE7B.ᓄ⊝ᦪ8()ᨵᐵ)<;⊝ᦪ<;ᦑB┯G7C.ᓄᑺ8#ᦋ;!"6᳛<#⊝%=>?⊝᳛<;ᦑC┯G7D.!"ASVO,AH<0,᪷AG=AH-TASIJ!"ᙠ*IL$%&',ᦑD┯G7ᦑ⌱BAoூOP௃Q⚪ὃTᓄ⊝UVὃT=WẠJYḄZ[\]^⚪_`aᓫ஺7.3ᑖd┑fRu
Wᓄᑺᓄᔠᡂᵬ⏚Ḅjk᝞mᡠo஺ᑡqr┯GḄsfd2HCOOHI
2HপA.t┑ᱥvnஹinឋvD.!"ঞ{ᨵூᑖ᪆௃A.t┑ᱥvnஹᙠ!"jk{ᐜ=ᡂὑ{ᱥ7B.II{┑ᐗ}(ᐗ}ᡂ┑ᐗ}~+27C.!"ᓄ!"=ᡂᵬ⏚7D.!"ঞ{ᓄ!"=ᡂW஺ூ@A௃@BA.t┑ᱥvIIஹ10ᙠ!"jk{ᐜ=ᡂὑ{ᱥឋv

15ᦑCDE7D.!"ঞ{ᓄ!"=ᡂWᨵᦑDDE7ᦑ⌱BB஺ூOP௃Q⚪ὃT!"ᳮUVὃT=ᑖ᪆⚪Ḅ#^⚪){஺8.3ᑖdᨬ¡¢£%¤¥LiTFSIf¦§¨©ᨵªd&'«ᩖᦋ&#~℉┞¯3ᵯ°±²ᵯ₹Ḅ#஺LiTFSIḄ´᪀᝞mᡠoᐸ{AஹBஹCஹD·¦¸ᕜºᐗ}C(E»·¦¼½஺ᑡ¾¿DEḄsfdA.CsÀ{tÁᨬḄᐗ}B.aᓫ᝱ÃᓄᱥḄyzឋBD>C>EC.ᓄᔠᱥ{8ᨵAஹCஹDᐗ}Ä3Ḅᨬ᜜ÆÇÈ8ᵯ3yz´᪀D.AU+(EḄaᓫ▢¯3ᙠËÌ{#ᜧÁᐳÎூᑖ᪆௃´ᔠmoIJᨵ4ÏCÐᡂ2ÏᐳEÐᡂ6ÏᐳC(E»·
,ὅ"»VIA½ᦑCO,ES,AÐᡂ4ÏᐳDÐᡂ1ÏᐳAஹBஹCஹD·¦¸ᕜºᐗ}ᑣAC,DF,BÐᡂ2Ïᓫ·ÓÔᑮ1Ïᵯ3᦮ÏÄ3×Øᨵ1Ïᓫ»Ùᵯ₹ᦑBN,LÚᑖ᪆@A஺ூ@A௃@B´ᔠᑖ᪆IJAC,BN,C0,DF,ESᐗ}A.À{tÁᨬḄᐗ}sN,0>S,ᑣaᓫ᝱ᓄᱥḄyzឋBHF>H2O>H2S,ᦑBDE7C.ᓄᔠᱥ{CஹNஹ0ஹFᐗ}Ä3Ḅᨬ᜜ÆÇÈ8ᵯ3yz´᪀S<ÇÈᦑC┯G7D.Al3\S2-%=Þß©@!"à<#ᜧÁᐳÎᦑD┯G7ᦑ⌱BBoூOP௃Q⚪ὃTÄ3´᪀(ᐗ}ᕜºá´ᔠÄ3âᦪஹᱥv´᪀ᩭäᐗ}@A

16ᐵUVᑖ᪆("ᵨ#ḄὃTåæçáឋJYḄ"ᵨC᧕┯O⚪é)<ᜧ஺9.3ᑖdᑡᨵᐵᱥvᱯëᑨḄqr{DEḄsfdA.íîᩞᧇḄñòólnm~lOOnmôᦑíîõö÷B.SiO2ஹAI2O3ᙳ#(⏚ù%=!"ᦑὅᙳúឋᓄᔠᱥC.ᵫ!"H3PO2+NaOHfjÁd=NaH2PO2+H2OIJH3P02¦ᐗ⏚D.üý⏚ᐹᨵᓄឋÿ
ᵨ⏚ᓄூᑖ᪆௃A.ᑖᦣB.SiO2⏚ᡂ!"C.H3P02#$ḄNaOH&'(ᡂNaH2P02,)*H3PO2+ᵯ-./0-1D.⏚ᓄᓄ஺ூ34௃35A.ᑖᦣ(678ᑖᦣ(9:(ᦑA┯=B.SiO2⏚ᡂ!"(>ᯠSiO2@A⏚BNaOH&'(CSiO2Dឋᓄᱥ(ᦑB┯=C.H3P02#$ḄNaOH&'ᡂNaH2Po2,)*H3P02+ᵯ-./0-1(ᡠHH3P02/ᐗ⏚(ᦑCJKD.⏚ᐹᨵNᓄឋ(Cᓄᓄ(ᡠHOHᵨ⏚ᓄ(ᦑD┯=ᦑ⌱5C,ூQR௃S⚪ὃVWᐗXᓄᔠᱥZ[(\៉ấ_ᐸᓄᔠᱥឋa3⚪ᐵc(deDឋᓄᱥḄᭆg஺10.3ᑖhijkᓄᡂ1-kimḄ$nopḄqᓄ᝞sᡠt(uᑡAwo᫏

17A.z{|}B.~I!nDᙳ.$C.AH=E(C=C)+E(Cl-H)-E(C-C)-E(C-H)(E⊤tc)D.1-kimᑖ᪀Ḅ᪀{CH3cHe1CH3ூᑖ᪆௃A.ᡂᨵᑖ1ᡂ(|}ᨵᑖ1ᡂB.ᱥḄ$:ᡂᱥḄ$Ḅ{ᔾ(ᱥḄ$ᜧ:ᡂᱥḄ$Ḅ{C.AH=ᱥḄc!-ᡂᱥḄc!D.ᑖ᪀ᢣᑖ1ஹ᪀Ḅᓄᔠᱥ஺ூ34௃35A.z+ᨵ/ᱥᡂ(9:ᡂ(ᦑA┯=B.~IᱥḄ$:ᡂᱥḄ$({ᔾ(~nᱥḄ$ᜧ:ᡂᱥḄ$({(ᦑB┯=C.AH=ᱥḄc!-ᡂᱥḄc!=E(C=C)+E(C-C)+6E(C-H)+E(Cl-H)-2E(C-C)-7E(C-H)-E(C-Cl)=E(C=C)+E(Cl-H)-E(C-C)-E(C-H)-E(C-Cl),ᦑC┯=D.1-kimḄ᪀{CH3cH2cH20,ᐸCH3cHe1CH3ᑖ1ᙳ{C3H7C1,᪀(ὅ{ᑖ᪀(ᦑDJKᦑ⌱5D஺ூQR௃S⚪⌕ὃVᓄ$Ḅqᓄ(ᒹᔾḄᑨஹḄ¡ஹᨵ¢£¤ஹᑖ᪀¥Z[ḄὃV({¦⚣ὃQ(⚪¨©ª/«஺11.(3ᑖ)2021ᡃ¯°Ẇ²ᕒHᓄ´(MOS)µ{ᵯ᩽·ᓄᑺ(Ẇ¹./Zn-2NOᵯº»(zᵯº¼ᐹᜓᔠᡂ¾!¿᜜ÁᵯḄÂ(ᐸõÄᳮ᝞sᡠt஺ÆZÇ᩽ÈOÉ"3-{H+!OH\ÊËÌᐸÍᔣÏÐ(ᑣuᑡ)Ò┯=Ḅ()A.Zn/ZnOᵯ᩽ᵯÓ⌕ÔM0S2ᵯ᩽ᵯÓÕ

18B.ᵯºÃµ¼NaOH&'!Na2so4ªᙳqC.Zn/ZnOᵯ᩽⊤☢¹Ḅ{Zn-2e+20H'=ZnO+H2OD.×ᵯØÏÐImole¼(᦮0ᵯº»a$ÚÛᜧ3.0gூᑖ᪆௃A.Zn/ZnOᵯ᩽{Ü᩽(M0S2ᵯ᩽{J᩽B.Zn/ZnOᵯ᩽Ḅ{Zn-2e+2OH'=ZnO+H2O,M0S2ᵯ᩽Ḅ{N0+5e-+5H+=NH3+H2O,D᩽Ýᙳᨵ"ᡂ(Ç᩽ÈOÉ"3-{H+!OH,ÊËÌᐸÍᔣÏÐ(&aḄᱥaḄ$q(&ᑺ"ÛßC.Zn/ZnOᵯ᩽Ḅ{Zn-2e+2OH=ZnO+H2OD.J᩽ImolNOàᓄ{NH3,àáᵯ1ḄᱥaḄ${5mol,ᦑ×ᵯØÏÐImolh¼(ᳮâãOHNOḄᱥaḄ${0.2mol஺ூ34௃35A.Zn/ZnOᵯ᩽{Ü᩽(M0S2ᵯ᩽{J᩽(J᩽ᵯÓ¦:Ü᩽ᵯÓ(ᦑAJKB.Zn/ZnOᵯ᩽Ḅ{Zn-2e-+2OH-=ZnO+H2O,Ç᩽ÈOH/áᔣÜ᩽(äÜ᩽Ýᨵ"ᡂ(ᦑNaOH&'q(MOSᵯ᩽Ḅ{NO+5e+5H+=NH3+H2O,2Ç᩽ÈH+áᔣJ᩽(äJ᩽Ýᨵ"ᡂ(ᦑNa2s04&'q(ᦑBJKC.Zn/ZnOᵯ᩽Ḅ{Zn-2e(2OH=ZnO+H2O,ᦑCJKD.J᩽ImolNOàᓄ{NH3,àáᵯ1ḄᱥaḄ${5mol,ᦑ×ᵯØÏÐImole/¼(ᳮâãOHNOḄᱥaḄ${0.2moL᦮0ᵯº»a$ÚÛᜧ0.2molX30g/mol-17g/mol
=2.6g,ᦑD┯=ᦑ⌱5D஺ூQR௃S⚪ὃVÄᵯºḄõÄᳮ(⚪¨©ª¥(åæsç!èéêKᑨJÜ᩽3⚪Ḅᐵc(©Qᵯ᩽Ḅëᑏ஺12.3ᑖh᝞síᐗXḄî£s஺uᑡᨵᐵ)ÒJKḄïhA.ᵬOHᵨ⏚

19B.ñᔠᡂN02ḄÐp9:íḄòÍC.iàᓄ{óḄᓄôÄD.õöuOᵨ÷ᑴùᘤûüóḄ&'ூᑖ᪆௃A.¾⏚ᡂ⏚ýB.íḄòÍÉíᓫaàᓄ{íḄᓄᔠᱥḄÐpC.ÿᓄᓄ⏚ḄᓄᔠᨵᦋD.⍗⏚ᓄ஺ூ௃!A.ᵬ#$%&'(⏚)*ᡂ(⏚╄%-&ᵨ(⏚/0#$%ᦑA┯3B.Ḅ4567ᓫ9ᓄḄᓄᔠᱥḄ%;NO,ᔠᡂNO2Ḅ-6Ḅ45.ᦑB┯3C.=>ᓄ%?⏚%>ᓄᓄ⏚Ḅᓄᔠᨵᦋ%-6ᓄ@A)*%ᦑc┯3D.⍗⏚ᓄ%BᵨᑴDᘤFG⏚%ᦑDHIᦑ⌱!D஺ூKL௃M⚪ὃPQᐸᓄᔠᱥḄឋ9%TUὃPVWẠYZḄ[\]^%_⚪`abᓫ஺13.(3ᑖ)ᑡfgHIḄ6()A.᝞kl⏚m9Ḅn6o⏚m9nḄ2p%ᑣl⏚Ḅc(H+)r6o⏚c(H+)Ḅ2pB.sᔣo⏚uᐭw5xl⏚y%o⏚Ḅᵯ{|⊝ᔣ~%ᵯ{|⊝ᦪC.ᙠ%O.lmol/LCH3coONamḄpH=9,ᑣmᵫᵯ{ᩭḄc(H*)=105mol/LD.ஹᱥ9ḄxnḄMOH⏚HAḄmᔠ%mᨵᐵ{nḄᜧᐵ6!c(A)>c(M+)>c(H+)>c(OH)ூᑖ᪆௃A.o⏚⏚%ᑖᵯ{%l⏚⏚%HC1ᐰᵯ{B.ᵯ{|⊝ᦪ'nᨵᐵ!C.CH3coONaᵯ{%%O.lmol/LCH3coONamḄpH=9,ᑣm

20ᵫᵯ{ᩭḄc(H+)=——----c(H)mD.ὅាªᐰ)*ᡂ⏚lMA,A®¯mᕈឋ஺ூ௃!A.o⏚⏚%ᑖᵯ{%l⏚⏚%HC1ᐰᵯ{%ᡠ´l⏚m9Ḅn6o⏚m9nḄ2p%ᑣl⏚Ḅc(H+)ᜧ¶o⏚c(H+)Ḅ2p%ᦑA┯3B.ᵯ{|⊝ᦪ'nᨵᐵ%n-%ᵯ{|⊝ᦪ-%ᦑB┯3C.CH3coONaᵯ{%%O.lmol/LCH3coONamḄpH=9,ᑣmK1-14+n5ᵫᵯ{ᩭḄc(H)=----------=1——mol/L=10-mol/L,ᦑCHIcW)m10-9D.ὅាªᐰ)*ᡂ⏚lMA,A®¯mᕈឋ%c(H+)c(A-)>c(OH)>c(H+),ᦑD┯3ᦑ⌱!CoூKL௃M⚪ὃP{nᜧ`a%TUὃPᑖ᪆ஹᑨÑQYZÒᔠÓᵨ&Ô%ÕIᵯ9ᵯ{ᱯKஹᵯ{Ḅ×ØÙÚஹmÛ{nÜÝÞg6M⚪ᐵß%àáÍឤᳮãḄᮣåÓᵨ%⚪æçn-ᜧ஺14.(3ᑖ)ឋᩩé%ᑭᵨëấᓄíî(ëCuOஹAS2O3Qñx-mឋᩖ9)ᑴᜓCU2(OH)2SO4Ḅõö÷᝞ø஺ᑡfg-HIḄ6()A.“#ú”yAS2O3Ḅ{)*AS2O3+6NH3+3H2O—6NH4++2AsO33B.“#ú”ḄþËᙠḄ□
⌕ᨵCu2+ஹNH4+C.“ᓄ◀ASO33”ᡂImolFeAsO%!ὑ(NH4)2s2஺8'1.5molD.“+,”.Ḅ0123ᨵ(NH4)2SO4ூᑖ᪆௃3ồᓄ:;(3CuOஹAS2O3=>?@AឋᩖD)ᑴᜓCu2(OH)2SO4,ᵨ

21NH3I(NH4)2SO4JᡂḄA1,K3ồᓄ:;L3:ᓄᔠᱥOᓄ'PCu(NH3)4QSO4A1LAS2O3Oᓄ'ASO3',RSᐭ(NH4)2S2O8IFeSC)4,ᓄ◀ASO33',UᑮFeAsO43WXLY0◀ZLUᑮḄA1⌕'(NH4)2s04IPCu(NH3)4QSO4A1L+,ஹY0ஹ\]Uᑮ^_Cu2(OH)2SO4,`aᩭcd஺ூcd௃c:A.᪷gᑖ᪆,AS2O3,KᡂASO33,hḄ
ij'AS2O3+6NH3+3H2O—6NH4++2ASO33\ᦑAmnoB.“,K”hḄ
ij'AS2O3+6NH3+3H2O—6NH4++2AsO33,rUᑮPCu(NH3)4QSO4A1L01Uᑮ2sᙠḄ□
⌕ᨵPCu(NH3)4^+ஹNH4+,ᦑB┯woC.“ᓄ◀ASO33"Asᵫ+3yᓣ{'+5yLFeᵫ+2yᓣ{'+3yLᑣᡂlmolFeAsO4,O}3molᵯ
L(NH4)2s2஺82ḄOᵫ-yL'-2yLᑣ◤4⌕(NH4)2s2஺82'3moiL=i.5mol,ᦑCmno8X(2*D.᪷gᑖ᪆LUᑮḄA1⌕'(NH4)2s04IPCu(NH3)4QSO4A1L+,ஹY0ஹ\]Uᑮ^_CU2(OH)2so4`=(NH4)2s04,ᦑDmnoᦑ⌱B»ூ௃⚪ὃᱥDḄᑴᜓL'{⚣ὃLᱥDḄឋDஹhḄijIḄ'cdḄᐵLᑖ᪆¡ḄὃL⚪¢£¤2¥஺¦ஹ§⌱¨⚪(ᐳ3ª⚪Lᐳ58ᑖLᐸ215-17⚪'¬⚪L18-19⚪'⌱⚪)15.(12ᑖ)NaQO2°±⌕Ḅᩔ³!´ᑺL¶·ᵨᩭ¸¹ºᱥ¥Lᐸ±^»¼᝞¾Nad஺1^_¿ÀᵯcÁij'2cle)2+2NaCl_ri21_2NaC102+C12஺ÃdÄᑡÆ⚪:(1)NaC1022CIḄᓄᔠy'+3஺(2)»ÇÈ·ᵨÉÊ;(FeS2)'ËᧇᑴᜓÍ⏚LÏÐÄ☢ÒÓÔ:

22Õ*×4FeS2+1102ᔣ2Fe2O3+8SO2஺Ø3ÙÚᱥDᑖÛܤᩭÝLNaHSCU°beeØßàáÙ஺a.⏚b.⏚Ôâc.ᵯcDd.§ᵯcDe.
ᓄᔠᱥf.ᐳyᓄᔠᱥØ4Ùᑏæ“ij”çè2ᡂC1O2ḄᓄéÒÓÔ2NaClO3+SO2+H2s04=2NaHS04+2C102஺Ø5Ù“ᵯc”ᡠᵨëâìᵫíâìîᑴᡂLîᑴL'◀ZMg2+ICa2+,⌕SᐭḄñᑺᑖò'NaOHA1ஹNa2c03A1஺Ø6Ù“óôᔾᦈ”°ᔾᦈ“ᵯc”YÓ᣸æḄ>?C102஺aᔾᦈij2LᓄᑺØC1O2ÙøËᑺØH2O2ÙḄᱥDḄ?ùú'21»ூᑖ᪆௃ᵫᑴᜓûÓüÀLNaCQIS02ᙠH2SO4⏚ᓄᩩþÄᡂC1O2,ᐸ2NaC103°ᓄᑺLÃᦈ^ᱥ'NaHSO4,ÿ
ᡂ⏚
C1O2,᪷ᵯឤḄᓄ2NaClO3+SO2+H2so4=2NaHSO4+2ClO2,⌱-NaOH◀/0123ḄMg2+,⌱-6⏚◀/0123ḄCa2+,ᯠ8ᵯ9:;3▢᩽CIO2?ᵯ
ᡂC1O2-,□᩽CCᜫᵯ
ᡂC12,EFGᓄḄGᓄHIᔾᦈC102,ᱥC102N,ᨬ8NaQO2HIQᨔஹTU?ᑮWXY1Z᪷[\ᓄᔠ^Ḅ_ᦪa0,?C1Ḅᓄᔠ^XY2ZbcdaeᐭḄghᙠjk᮱3mn
ᡂGᓄcaoGᓄ᪷ᓄᔠ^ᓣq^ឤarឤstXY3Zuᱥvᑖxyzᩭ|NaHSCU⏚3Ḅ~ᐰ3a⏚1ᙠH2ᡈᰚ᝱ᵯḄᓄᔠᱥᵯ9vEᨵḄᓄᔠᱥᓄᔠᱥXY4ZNaC103aS02ᙠH2SO4⏚ᓄᩩ
ᡂC102aNaHSO*᪷ᵯឤstXY5ZᑭᵨFNaOHHI◀/Mg2+,ᑭᵨFNa2cO3HI◀/Ca?XY6Zhᜐᳮ
2Na0H+H202+2C102=2NaC102+02t+2H2O,CIO2Gᓄᑺ¢rᱥNaC102,ᵫᵯឤGᓄᑺa¢rᑺḄᱥvḄ¤¥஺

23ூ9¨௃9ª(1)ᙠNaC1023Na+1^0-2^᪷[\ᓄᔠ^Ḅ_ᦪa0,?C1Ḅᓄᔠ^0-(-2)X2-(+1)=+3^ᦑ¨ᫀª+3X(2)bcdaeᐭḄghᙠjk᮱3mn
ᡂGᓄcaoGᓄ᪷ᓄᔠ^ᓣqᔡ±^ឤarឤstª4FeS2+1102ᔣ♦2Fe2O3+8SO2,ᦑ¨ᫀª4X11X2X8X(3)uᱥvᑖxyzᩭ|NaHSCU⏚1ஹᵯ9vஹᓄᔠᱥᦑ¨ᫀªbeeX(4)NaCIChaSO2ᙠH2sCM⏚ᓄᩩ
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Z[\]^Ḅᱥ`Ḅa62moi
20minᑁ
ᵨH2⊤deLMḄVᙳLMg᳛601mol

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Z[\]^Ḅᱥ`Ḅa62mol,ᑡᓄUV⊝æçÛ
2c02(g)+6H2(g)=CH30cH3(g)+3H2O(g),èy(mol)2600jᓄ(mol)422~3~32V⊝(mol)222,~3~3êëᔠìÛíîï(2)ᱥ`¯ᓄᑖ᪆ðñ
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27H᠒ᤅK!LMNᵨAPQRNSTUᘤC7WᡭYZPB:[ᴻP]^MN_T`aḄbcdᘤ:efᵨefgᔿh!:Cijf/ᐰᔿlᐵTB,Eno11.94gFeC124H2OḄᨵDEᑺpᐭUᘤC,……ᡭYB,r/1stᤅK30min,ᑴᜓ-.wx஺……ᔣ!ᐭz{<Ḅ|⏚:〉<~஺……!ᑁḄᦈᑮ{ᘤTᵨh3ᑮ6஺জUᘤCḄrᧅ7ᡈᑖᧅ]஺ঝjf/ᐰᔿlḄḄ$■FeII
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ᵫ⚪ÌFe+2ÍÎ᧕jffᓄᡠ×ìí◤⌕Æi᠒᠒ᙢÐᐭN2,ᐸᵨ$ÂÑfòḄᔿᐭᦈḄ᳛ÒḄ"#$&ᙳᒴ)*+,ᦑêᫀ¹ÂÑfòḄᔿᐭᦈḄ᳛Ò&ᙳᒴ)*+,Ò72
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28ᦑêᫀ¹rᧅ(ᡈᑖᧅ)Òঝjf/ᐰᔿlḄḄ$■Fe(II)jffᓄᦑêᫀ¹■Fe(II)jffᓄÒঞ-.?-.ᐭ~Ḅᵨ$t,ᨵᑭ*wᨔ᪆lᦑêᫀ¹t,ᨵᑭ*wᨔ᪆lÒট|⏚z{<ÓEᕈ⏚ឋᑣÖ×⌱ᵨḄ¦ᑺ$§⁐©ªE(ᡈᵬ¬EஹpH¦¯ஹ°±Ḅ²⁐©ª¦¯)ᦑêᫀ¹§⁐©ªE(ᡈᵬ¬EஹpH¦¯ஹ°±Ḅ²⁐©ª¦¯)Òঠ᪷Û⚪ÜÝÌÞᓄßàஹáᓄâ-.ᡂஹÞᓄâ:-.¶·¸¹FeC12+2C5H6+2KOH=Fe(C5H5)2+2KC1+2H2O(ᡈFeC12•4H2O+2C5H6+2KOH=Fe(C5H5)2+2KC1+6H2O),ᦑêᫀ¹FeCb+2C5H6+2KOH=Fe(C5H5)2+2KC1+2H2O(ᡈFeCh•4H2O+2C5H6+2KOH=Fe(C5H5)2+2KC1+6H2O);(3)᪷ÛTã-.Ì11.94gFeCl24H2O/ᐰ-.ᡂḄä<¹11.94gX2ᓽ199=11.16g,ᑣḄ᳛¹ᒹý_X100%=85.0%,11.16gᦑêᫀ¹85.0஺ூ#þ௃ÿ⚪ὃᱥḄᑴᜓஹᱥᑴᜓᫀḄ⚣ὃᑴᜓஹᐗᓄᔠᱥᳮ!"#Ḅᐵ%&'ᑖ᪆*+Ḅὃ,ᔠឋ./⚪0123!஺ூ⌱78ᱥ9᪀ឋ௃18.(15ᑖ)=>ᐸᓄᔠᱥᙠABCD3EḼ'⌕ḄHᵨ஺[KI!T|T|T|(1)J᝱=LMᵯLḄO⍝⊤RS3s3P(2)=ᨵVWXYZ[஺

29জ]=(P4)aᑖLᨔ[᧕deCS2,1dejkl]=mCS2nao᩽ឋᑖL(q“᩽ឋ”ᡈ“o᩽ឋ”)஺ঝv=ᨔ[awWxyz{|}~Ḅᩞᧇᐸᨔ[ayzḄ9᪀᝞1ᡠR஺ᑡᨵᐵv=ᨔ[ḄkḄaAC(q)A.v=ᨔ[3ḄHᵨ+aᑖLHᵨ+B.v=ᨔ[3=LᩖᓄSsp2ᩖᓄC.v=ᨔ[aᔠᨔ[D.v=ᨔ[Ḅw3=LnᙠXw☢¡(3)PC15awW]⁐ᨔ[ᰚ¦§ZᡂwW*©ᵯḄª[«¬ᐸ3ᨵwW®☢[Z□°LmwW±☢[Z▢°L(³ᨔ[Ḅᨔ´᝞2ᡠR)ᑏ¶PC15ᰚ¦§Ḅᵯ°S2PC15(ᰚ¦)=PC14++PC16w஺(4)Fe3+j¼Zᡂ½⁐Ḅ¾°L¿Fe(OH)|2+,ÃÄÅ⁐Æ᡾ÈᙠFe3+dª3ÉᐭH3P04ZᡂÌ⁐Ḅ¿Fe(P04)2Í3\ᵫÐÑ«Fe3+ZᡂḄ¾°L|ÒÓḄ¾[aP0?,³¾[ḄÕ᪀a®☢[Z஺(5)Ö×Ø=ᓄᱥRh2P(ᓄÛSÜ237)ÞᵨHᵯ"jḄᦔàᓄᑺᐸâᨔ´᝞3ᡠR஺ãäᨔ´åᦪanm,ᨔ[3Pê°ᨬìḄRhḄᦪ08,ᨔ[Ḅî2_-----"237w_gcm-3(ᑡ¶ôS)஺NX(XAaூᑖ᪆௃(1)PLMᵯL᣸÷S3s22P3,9ᔠøᑭᳮஹúᱯüᑣþ¶MᵯL᣸÷ÿ(2)জᔠᳮᑨঝA.ᨔḄ᪀ᵨ"#B.ᨔ%P'(ᡂ3+P-P-ᨵ10ᐳᵨᵯ'0ᩖᓄ5⍝ᦪ894C.ᨔḄ᪀<ὅᨔ>D.P'ABsp3ᩖᓄP'ᕜFḄ3+P'(ᡂGH┵((3)PC15KLM⁐ᨔᰚPQ(ᡂKLRSᵯḄT(ᡂḄUV☢(□Y'9PC14+,U\☢(▢Y'9PC16-(4)T%Fe3+ab(ᡂc⁐ḄdY'eFe(OH)h2+,ijᐭH3P04(ᡂm⁐ḄeFe(P04)2h3KnoPO43KFe?+(ᡂḄdY'qrs(5)ᨔt%⁐ᳫᦪ898ஹM⁐ᳫᦪ898X+6XJL=4,⁐ᳫM⁐ᳫᦪ8xy82

3098z4=2z1,ᔠᓄ|}Rh2P,⁐ᳫ⊤Rh,M⁐ᳫ⊤P,☢☢P9ᑖ᪆0PYᨬḄRhᨵᨔtᑁᡂ4+Rhஹᨔtᑁ4+Rhᨔtᨵ4+“Rh2P”ᨔti᪷ᨔ=¡¢£¤஺ᨔt¦ூ¨©௃¨z«1¬P'ᵯ'᣸¯}93s22P3,ᔠ°ᑭᳮஹ²ᱯ´ᑣᵯ'miTlT|T|᣸¯¶93s3p,·HITºᦑ©ᫀ9z3s3p.«2¬জMᑖ'ᨔ᧕CS2,¿aa9᩽ឋᑖ'᪷ᳮMÂCS2ÃÄ᩽ឋᑖ'ᦑ©ᫀ9zÄ᩽ឋঝA.ᨔḄ᪀ᵨ"#ᨔ%xḄᵨ"ᑖ'ᵨ"ᦑAUÅB.ᨔ%P'(ᡂ3+P-P-ᨵ10ᐳᵨᵯ'0¶%ÆÇ☢᪀ᑣᩖᓄ5⍝ᦪ894,P'ABsp3ᩖᓄᦑB┯ÉC.ᨔḄ᪀ᑁP'x(ᡂᐳ-9ᑖ'ᵨ"ᨔÊᔠ>ᨔᦑCUÅD.P'ABsp3ᩖᓄP'ᕜFḄ3+P'(ᡂGH┵(ËK%P'ÆRÃᙠ#KÇ☢ᦑD┯Éᦑ©ᫀ9zAC«3¬PC15KLM⁐ᨔᰚPQ(ᡂKLRSᵯḄT(ᡂḄUV☢(□Y'9PC14+,U\☢(▢Y'9PC16',PC15ᰚPQḄᵯYÎÏ}92PC15«ᰚP¬=PC14++PCl69ᦑ©ᫀ9z2PC15«ᰚP¬=PC14++PC16-«4¬T%Fe3+ab(ᡂc⁐ḄdY'eFe«OH¬Ñ+,ijᐭH3P04(ᡂm⁐ḄeFe«P04¬2h3',noPO43KFe3+(ᡂḄdY'qrsPO43KḄ%'P'Òᵯ'0ᦪ95+3-2X4=0,ᵯ'0ᦪ94+0=4,ᦑPO43KḄÓ᪀>9UV☢(2ᦑ©ᫀ9zPO43'UV☢(

31(5)ᨔt%⁐ᳫᦪ898ஹM⁐ᳫᦪ898Xº+6Xº=4,⁐ᳫM⁐ᳫᦪ8xy8298z4=2z1,ᔠᓄ|}Rh2P,⁐ᳫ⊤Rh,M⁐ᳫ⊤P,☢☢P9ᑖ᪆0PYᨬḄRhᨵᨔtᑁᡂ4+Rhஹᨔtᑁ4+Rh,ᑣᨔ%PYᨬḄRhḄᦪ898ᨔtᨵ4+“Rh2P”ᨔt944X237-N---ÖX237gಗ=4X237g,ᨔtÚᦪ9ᑣᨔ9------G——anm,Nmol(aX107cm)3A4X237-3ygecmNX(X10-7)Aa4X237ᦑ©ᫀ9z8NX(x10-7)3Aaூáâ௃ã⚪ὃæᱥ᪀ឋèé᪶᜜ᵯ'᣸¯ஹᑖ'᩽ឋឋஹdᔠᱥஹÓ᪀>ஹᩖᓄÎ}ஹᨔt᪀ì◤⌕|ᐹᜓñòḄóẠᮣö÷ᵨR"øùᙳûü£¤ᨔtᨵᐵ஺ூ⌱ÿᨵᓄ௃19.ᨵᱥHᔠᡂ╋Ḅᔠᡂ᝞OICH-C-CI3A(C7H80)ᓄᑺ“B(C9HIO02)10P,*(CnHiO+,⏚-DCC1)H+ஹACHCHO;<.G(C13H14O4),ᓄᑺ.HN^IE(CIIHIINO2)______i______.F(Ci3Hi2NO2Na)NডH(aq)ஹ:H3O*12+HX(REFGᡈH?@XEᓴJ?@A)II.R-X+NaCN-R-CN+NaX

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AḄQRSᵬGUVB-CḄWXYZE[ᡂWX஺]^EHᔲ`a3
bᔠᑡᩩdḄEḄAᑖf᪀ᨵ4ahὃ⇋kf᪀l஺জ`ᨵ-NH2n-COOH,◀Up᜜rᐸtpuv᪀ঝ᪶yᐳ{|}ᨵ4~ᔾᦈ☢E6221COOH4
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