重庆市缙云教育联盟2022届高三化学第一次诊断性检测（1月） 【含答案】

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13^9-3N2+6H2஺=3Mg(0H)2+2NH^ᦑ3ᦑ⌱DQA.5oᓄấ;q(B.r)soᓄ:;<*ᡂrᓄ:toஹ(C.:ឋ^)G;<ᐜ)(D.8ᓄ┛ஹzᓄ╅(Dᑖ|*ᡂ}Ḅ~tsᓄᱥ஺K⚪ὃNᱥ^ឋ^Ḅu2⚪1\ᐵᓄPᱥ^ḄKឋ^D⚪Ḅᐵhmnu2ᵨtᱥ^ᱯឋḄᐵ஺12/D:4PHW12Ḅộ(஺“)2;<c(H+)=10~12mol/L,Kw10-14c(OH■)=---------=---------mol/L=10-2moi/Lc(H+)IO-12,¡ᨵ஺H-ᦪWlLx10~2mol/LxN/mol=0.01NᦑA;A,1)1.8gB.l.8gj((4஺)ᡠ¡^CᦪW20g/m஺X¦§¨©—0.9”,ᦑ┯8.7g------------x2xN/mol=0.2NQAAC.«¬Ḅ&G⏚)879®஺2¯°ᵯCḄᦪW87g/moᓃᦑC┯ߟx3xN/mol=3N.D.32gᵬ⏣ḄᑖC¡ᨵC-HhḄᦪW32g/mo1A\ᦑ┯ᦑ⌱4A.ᵫ·"=W¸¹ᱥ^Ḅ¬B.j((/°)ᡠ¡10»^CC.lmoZ5oᓄ┶)&G⏚¯°27noiᵯCD.ᵬ⏣ḄᑖC¡ᨵ3ᩩh஺K⚪ὃN¿À=ÁÂÃᦪḄᨵᐵ¸¹tᑨ⚪1¿À=ÁÂÃᦪXὃḄ“>Z”,ÆÇὃNÈP*}ᱥ^Ḅ¬ஹÉCᦪஹ^¬ஹÊ)¿À=ÁÂÃᦪᐵḄᳮDË/ÌÍÎÏÐ1ḄᓄPÑÒᑁÔ\ÕÌᱥ^Ḅ¬W§ḄᔜᓄP¬)¿À=ÁÂÃᦪḄᐵD⚪Ḅᐵh஺

1413.DD4ØÙÚÛ;q!¬G⏚<ᐭKSCN,ÜÝ;<ÞWß⁐àáâ;Dã;<äᨵFe3+,é/*Fe+2Fe3+=342+,ᡠÌìíîÙÚÛᔲ¡Fe3+,ᦑA┯B.⏚ឋᩩòóô⏚᪷BCØBaS/oᓄ*ᡂBaS஺᜜ùúí;<ᔲÞ^ᦑB┯CᔣMg(0")2〉C/C00NH4⊝ᓄ╅Ḅ⊝!ᔣ#$ᑣ“9(°")23c0°N%⏚.ឋ0ᐵᦑc┯45DᙠCuS/ᐭK/<=>+4@=2CU஻+/2,CWGH⁐Jᱥ%LMᕈOP⁐QRஹTUஹVWᙳᔠᳮᦑD![5ᦑ⌱]>A.Feb⏚>ᡂdᓄefᐭKSCNghijP⁐klmnopᨵr+5B.⏚ឋt⏚᪷vwxᓄey⏚᪷vw]CCH3COONH4jឋf᪷vw᪷vwx{ᓄ╅5D.=>2C/++4ᔆ=2CaN+2,CidGH⁐Jᱥ4LMᕈOP⁐஺⚪ὃᓄᫀḄj⚣ὃᱥḄឋஹTUஹᢈljḄᐵᑖ᪆lḄὃḄឋᑖ᪆⚪Jᜧ஺14.0A.ᐗ¡ᓄᔠᓣ£ḄᱥGᓄ¤ᱥCᐗ¡ᓄᔠ¥¦£Ḅ¤ᱥ஺஺G§¨¤ᱥᦑA┯45B.ᐗ¡ᓄᔠ¥¦=>§¨“ᐗ¡ᓄᔠᓣ=>ᓄᦑB┯45C.ᓄᑺGªᓄ«ᓄᑺ§¨ᑺḄᱥḄ¬j>1,ᦑC┯45D.᪷¯ᓄᔠᓣ¥x°>ᡂ±²#8m஺/ᵯwᦑD![5ᦑ⌱]஺஺

15¶τcu----4co+2H?0+SiO?4஺஺2+5º42,Cᐗ¡ᓄᔠ¥¦»§¨Hᐗ¡ᓄᔠᓣ»ᓄ²#ᵯwᦪj8½¯¾¿À⚪஺⚪ὃᓄ§¨⚪Jᜧὃᓄ§¨ḄᭆÂஹᵯw²#ḄÃÄÅ°ÆG⚪ḄᐵÇ⚪ÈẠ°ÆḄὃÊËÌ>ḄᮣÎᵨl஺15.8஺Ð2AgN03ᨵÑÒ>ᡂNa2c03+/°+C°2=2NaHC031Óᵯ2CuS0.+2HO-^2Cu4-+2HS0.??DrlᔣCÔÕb⏚0TU,Ö⊈ᵯغTH⁐ÑÒᑣÙᨵS°ÚAg++cr=AgCll](1)ᵫÜÝᑖ᪆x°A^NaCOBBBa”C^uS0஺jAgN᜜,23t41ᦑBQC4.AgN03.(2)ᵫLàá¶âNa"C03Ḅãäᔣ⛳æ2c°3Óᐭç஺°2±>ᡂḄNa"஺᪆ºᓽᨵÑÒ>ᡂéêj22c஺3+“20+c02=2NaHCOl3fᦑᨵÑÒ>ᡂ5Na2c03+42஺+E஺2=2NaHCOl3t(3)ëCUSO4ìíᙠᵯîᑭᵨðkñᵯ᩽¿Àᵯ>ᡂC“ஹ°2æ“25஺4,ójÓᵯ2CUS0A+2H0----2Cu+0?T+2HS0.2-^??úSc°n4xᵨÕb⏚æBDar5l2ᐹüQRj]ᔣCÔÕb⏚0TUÖᵯغTý⁐ÑÒᑣÙᨵS°24\Óᵯ2CUS0A+2HF)----2.C1L+02T+2HS0Aᦑ27245ᔣCÔÕb⏚0TUÖBa஺%غTH⁐ÑÒᑣÙᨵS°2ÿ(4)BBa஺%,D9'03,ὅᡂBa(N&)2AgCl,!"#4g++஺ᔆ=AgCN,ᦑAg++Cᔆ=4gCN஺AஹBஹCஹ0()*+,ឋ./᪷1ᐳ3+4/56ᑖ89஺^^ஹNa2cO3ஹCuS0^4BaC4>Ḅ@*

16জB)*.ᔜDEF/ᑖ8,GHᨵ5mLMNOḄ4PQR>/SᨵC.,TᕈV⁐/XYC.CuSO4tঝᑖ8ᔣ4PQR>\ᐭ2mL^.⏚/`a°.,T>cd⁐ef/XY஺.>gᨵ4gNC>3,4.,T>ᨵijklc/XYA.>gᨵ'a2c03•ᑣ8.BaC%,1pᑖ᪆rs஺t⚪ὃwḄxyz{|/}⚣ὃ/ᱥḄឋஹ`Ḅஹᐳ3rsḄᐵ/ᑖ᪆z{|Ḅὃw/Ḅᱯxy!/⚪ᜧ஺16.ᕜVH”Cl+Zn¡0"£2=++2HOSi>Cl>NN/>HCl>SiHH2r¤ᵫ¦§ᑖ᪆+4/ABNஹBBSiஹCGஹ஺Zn,¡DCᐗªᙠᕜ⊤>Ḅ®ᕜ¯4/ᦑᕜ¯4¡2£)*ᐗª>/aḄ°±²ឋᨬ´/ᜫ¶ᵯ/ᑣ@ᵯᨬᜧḄ(¸/ᦑ¡3MḄᨬ}º»ᓄᱥ½ḄOᓄᱥ¾⏚/஺Ḅᨬ}»ᓄᱥ½ḄOᓄᱥ¿»ᓄÀ/ὅḄ!"#2"++Zn¡°"£2=Z/++2”2஺/ᦑ2H++Zn¡OW£=Zn2++2/஺.2¡4£ÃÄÅÆᔣÇÈÉÊËᜧ/ÃᕜÄᐗªÅÆᔣÇÈÉÊÌÍ/ᑣ9BஹC*ᐗªḄÈḄÉÊḄᵫᜧᑮÍḄÏÐS>Cl>N,ᦑSi>Cl>N.¡5£ÓkᑖÔg¿Õ}/Ög¿Ḅᑖ>×½ᑖFØᜧஹÕØ}/ᑣ48ஹCᑖ8ÙᡂḄᨬÚᓫ¿ᓄᱥ>Õᵫ}ᑮÜḄÏÐN/>HCl>SiH41^NH>HCl>SiH^34ᐗªᕜ⊤>Ý4ᕜḄᐗª4BஹCஹDḄÈÐᦪßàËᜧ/4Ḅá᝱È᪶᜜ᵯᓰ13æç/Öᨬ}ç¦ᨵ3æᵯ/ᵯ᣸éIs22s22P3,ABNBḄᓫ(ᨬíîḄÉïðᩞᧇ/Bᮞᨬ}ºg»⏚(ᨬ´Ḅôõ⏚}ö⏚/+4CG¤஺ḄÈÐᦪᨬᜧ/Ö஺Ḅá᝱Èᨬ᜜÷ᨵ2æᵯ/ᐸù÷ᵯᙳ᣸û/+40ḄÚᓄᵯ᣸éü\13d1°4s2,0ḄÈÐᦪ30,DBZn,þpᩭ
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Ḅᐵ)*+ᑖ᪆.ᵨ01Ḅὃ23!"ឋḄ.ᵨ⚪4567ᜧ஺NaClO+NaCl+HS0-^NaS0.+C/T+H0?4???17.2422cᙠ:4ஹB;<=>?@AᨵCD⏚ḄFGHᑖIJIKLᕈNO⁐CaS0Q2CaClO
+C0+H0=2HC10+CaCOlᔾᦈ2223TGUG■WXYZG[\1
ᵫ⚪3^_.`ᳮ>bᩩdJeT⏚fஹTᓄfD⏚gK_.hᡂTG_jNaClO+NaCl+H.SO.-^Na.SO.+CLT+H0?.2422,᪷mᑴᜓ“2`ᳮ^ᑴᜓTGḄ_.ᱥpLKL_.ᩩd>bᡠr.⌱t:஺uvh:jNaClO+NaCl+HSO-^NaSO+C/T+H0242422ᦑc\2QC2x^0yᨵz{Ḅ|}G_.52+"2°="*+"50,hᡂḄHC/஺~:8xḄᨵ⁐ᩩ⁐^ᙠ4ஹB;<>?@A:CD⏚ḄFGH◀TGxḄ|}Gᦑᙠ:4B;<=>?@AᨵCD⏚ḄFGH[\3
C%K/_.hᡂᓫ2+2ᔆ=4+21-,CC஻⃓hᡂḄᓫᕈNO⁐gᨵᓫḄ7g|ᑖIᦑᑖIJIKLᕈNO⁐\4
ᮞḄ⌕ᡂᑖCa\°"Q2,r20Ca0“Q2_.hᡂCaGzஹCa\c/0Q2,஺஺஺ಘᐹᨵᓄឋ^ᵨᩔ¡¢£¤ᓄ¥0eT⏚┛_.hᡂ¥⏚┛§eT⏚"C/0¨ᐝᑖ,ª«¬®ᜫᦔ_.'a©஺%+C02+H20=2HCl°+CaCgi,ᦑCaC/0Q2.CaClO.2+C0+H0=2HC10+CaCOl_223\5
TGᨵ¢GL³XYZG£0Na஺”gK_.Cl+2NaOH=NaClO+NaCl+H0ᑣFxA:ḄNaOHgK^ᔾᦈUGḄTG■WXYZ22fGᦑᔾᦈTGUG■WXYZG஺jJINaClO+NaCl+H-----NCL^SOA+Cl.+H2O:4ᵨᑴᜓC'2,_.,pL§KL_.

18◤⌕>b^⌱tCvh:ᑴ¸Ḅ“2yᨵ|}G■W|}GḄ᡾^ᙠ4ஹB;<¾>?A:CD⏚Ḅ:6CxÀeÁḄḄO⁐ᩩ§ÂÃḄO⁐ᩩ^ÄÅᑮBxᩩ7⁐Cxᩩ⁐ᓄឋ[Cl2>h,0Èᙠ°xᓄK/¸ᑮÌTᓄ¥7g|ஹÍ6ᜧ|ᑣgKᑖIஹJIÎNO⁐,AᙠExᮞ_.hᡂ¬®ÑxḄNa஺”gKᵨᔾᦈUG2,■WXYZGmÔᑖ᪆u
஺⚪ὃTGḄÕÖ×ᑴØஹTGḄឋ⚣ὃTGḄឋஹᑴᜓ⚪ᐵ)23ḄTGÙᨵ¬ឋ*+ÚhḄᑖ᪆01ஹÕÖ01Ḅὃ⚪456xÛ஺MnO218.NaOHpL2H2022%஺+஺2THNOdijeN43c3Cu+8W+2Nᔩ=3C“2++2N°T+4”2°ᓫç<ᑁ:BéhḄN%zê:4éhḄGḄ{ëìçìíG_.éᱥ-ᓄï_.hᡂOð⁐Ḅ¤ᓄï[\1Qᵫᑖ᪆^:BN“3vh:ᑭᵨNaOHpLgÁbòóCô|ᑖéhôG,ᦑ:BxõHᑁA:Ḅö÷NaOHpL,ᦑNa஺pL[\2Qᵫᑖ᪆^:AGvh:ᵨ“ø°2ùᓄ“2°2ᑖéhGᦑ:4xõHᑁvMnO22HM-------2H0+02T?h_.Ḅ[MnO22HO-^—2HO+02T222ᦑ\3Qᵫᑖ᪆^FxûḄᡂᑖ'"4~03,ᦑNH4NO3\4Qᵫᑖ᪆^:Ḅÿ
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19ᦑ3Cu+8H++2N03=3cli2+2N0T+4HO.+26ᵨQᝅ&'STUVWᑮ&'Y)ᨵ[\⁐]^01_ᓫaUbᑁ&'B

205,“2°Ḅᦪ8,ᦑ/ᓄ123Ḅᓄ456782KM:஺4+10<+8”25஺4)*+=2MnSO+5a2T+6K2sO4+B஺4ᦑ2KMnC+4+10KCI+8H2s07*+=2MnS0+5c72T+6KSO+B஺.424ঝᵫজ23KḄLM⏚ឋLMPᐭNaBiQ,LMVWXY⁐[\Mdᓱ_ᓄᡂa0&23KWc⁐Ḅd3+,ᐗgḄᓄᔠij+2iᓣlᑮ+7iWᓄᦪ5,BiᐗgḄᓄᔠij+5inoᑮ+3iWᓄᦪ2,᪷ᐗgᓣnipᦪឤMM+qNarO3Ḅᦪs285,tMn2+Ḅᦪ2,ᑣḄᦪ5,᪷ஹBi᪶NaឤḄᦪ2,8ᡝ+Ḅᦪ5,Na+Ḅᦪ5,x᪷ᵯ₹ឤ23ᱥᨵH+,ᦪ14,ᨬK᪷ឤ~ᡂᱥ1ᨵ“2°,ᦪ7,ᦑ/23Ḅ56782Afn2++5NaBiO+14"+=2MnO~+5Bᓽ+5Na++7/0,3ᦑ2M"++5NaBiO+14"+=2MnO~+5Bi3++5Na++7HO_32)2+᪷⚪23LM⏚ឋLM2°_e2+1ᡂ3+,ᓄᱥ3+,CrᐗgḄᓄᔠij+6inoᑮ+3iWᓄᦪ3,FeᐗgḄᓄᔠij+2iᓣlᑮ+3iWᓄᦪ1,᪷ᐗgᓣnipᦪឤ,2ᳫqFe?*Ḅᦪs186,t2°2Ḅᦪ1,ᑣFe?*Ḅᦪ6,C/+Ḅᦪ2,Fe3+Ḅᦪ6,x᪷ᵯ₹ឤ23ᱥᨵ“ᓝᦪ14,ᨬK᪷ឤ~ᡂᱥ1ᨵ“2°,ᦪ7,ᦑ/23Ḅ567.Cr2°27+6Fe?++14H+=2Cr3++6Fe3++7HO2ᦑ஺᪗+6Fe2++14H+=2Cr3++6Fe3++7HO.2)3+᪷⚪LMᐭNaOHLM~ᡂ“°21)⁐+┶ᐗgḄᓄᔠij+7inoᑮ+6iWᓄᦪ1,ᑣᐗgḄᓄᔠij-2iᓣlᑮ஺i~ᡂ஺2,Wᓄᦪ4,᪷ᐗgᓣnipᦪឤ♦q°2Ḅᦪs481,t°2Ḅᦪ1,ᑣMn04■Ḅᦪ4,“°1Ḅᦪ4,x᪷ᵯ₹ឤ23ᱥᨵ஺”,ᦪ4,ᨬK᪷ឤ~ᡂᱥ1ᨵ“2஺ᦪ2,ᦑ/23Ḅ56784Mn஺4+4OH-=4MnO2^+02T+2HO2

21ᦑ+4஺”-=4MnO2~+02T+2HO2t2(4)ᐗgḄᓄᔠij¦5§ᓣlᑮ+6iᑣ¨©2sxᜫ¬(6x+2)©ᵯᐗgḄᓄᔠij+1inoᑮ-1iᑣ¨©NaC/0ᑮ2©ᵯt'a2sxḄᦪ1,᪷ᜫᵯឤNaCZ°Ḅᦪ(3x+l),᪷ஹஹ±ஹឤ7஺25஺4Ḅᦪx,NaGḄᦪ(3x+l),Na஺”Ḅᦪ(2x-2),“2஺Ḅᦪ(x-1),ᑣ/23Ḅᓄ45678NaS+(3%+l)NaCL0+(2%-2)Na0H=xNaS0+(3%+l)NaCl+(%-l)%஺2x24ᦑ1³3%+1.2x-2.x.3x4-1.%-lo(l)জlµ⏚LMᙳᨵ·ᓄឋḄXY⁐LM52¸⁐¹º*»⏚ᐭl¼⏚LM~¸⁐¹º½LMḄXY⁐¾¬[\ᓄᡂ¿2,ᑣᨵKCஹ"*H2s஺4ஹ”2°ஹKMn/ஹ”À஺4ஹ/5஺4"ÁᱥÂḄᓄ123ºKMn04ÃᓄᑺKGÃ1ᑺᓄᱥ“2,1ᱥᵨ5஺4,᪷ᐗgឤ*"25஺423ᱥ“2஺Æ25஺4~ᡂᱥx᪷ᐗgᓣnipᦪឤឤÇᑏᐸᓄ4567³ঝᵫজ23KḄLM⏚ឋLMPᐭNaBi03,LMVWXY⁐[\“Ê+_ᓄᡂBiO323KWc⁐Ḅd3+,x᪷ᐗgᓣnipᦪឤஹᵯ₹ឤឤÇᑏᐸ567Ë'0ᮞ஺3ÍLÎÏÐ82(2)᪷⚪23LM⏚ឋLM_Fe2+1ᡂC/+,ᓄᱥFe3+,x᪷ᐗgᓣnipᦪឤஹᵯ₹ឤឤÇᑏᐸ567³(3)᪷⚪ὡ஺4LMᐭNaOHLM~ᡂÒ"஺?[(⁐)═ᐗgḄᓄᔠinoᑣᐗgḄᓄᔠiᓣl~ᡂ°2,x᪷ᐗgᓣnipᦪឤஹᵯ₹ឤឤÇᑏᐸ567³2(4)ᐗgḄᓄᔠij¦Ôiᓣlᑮ+6iᑣ¨©'a2sxᜫ¬(6x+2)©ᵯᐗgḄᓄᔠij+1inoᑮ-1iᑣ¨©NaC/Oᑮ2©ᵯ᪷ᜫᵯឤឤÕÖ/ᓄ4567஺×⚪ὃÙᓄ123567ḄÇᑏÕÖ⚪ÚÛÜÍᜧᐵß\àᐗgḄᓄᔠiWᓄáâãᵨᜫᵯpᦪឤ(ᐗgᓣnipᦪឤ)ஹᵯ₹ឤឤÕÖ567Ḅ5äå៉çèḄᓄᑺ1ᑺËé⚪஺

22C(X)CH,r%ஹ(XH,1OCH,/20.⏚ßêëஹH+HCOOH^\\CHO+H2°ìí23sp2ஹsp3CH,()p2QHCH8OHH(Q-()—CII—<'H—C'H(CHJONH,ஹH—COOCH1NH.,OHNH.OHOHCH,——CH,(>-\=J\CH,NO³NH2COOCH,Kî8(1)8NO8,BḄïðñaòóôëஹ⏚ßஹêë,ᦑ⏚ßஹêë³CO(X'HC(X)CH,1OCH,/\(2)Cᵬ⏚ö~ìí23ᑮD,567NH.+HCOOH^11(HO+3°,

23C()()CHC()()CH$Ol'HSANOCHZ\ᦑNH8+HCOOH-^11CHO+“2஺³(3)᪷0EḄø᪀ᑖ᪆ü¦C“2C°C”3ìíDḄ¦©•"#$%&D-EḄ*+,-./023ᦑìí23³(4)ᑖ᪆Fø᪀Nᩖᓄ57sp2ஹsp3,27ᦑspஹsp(5)HḄ᪀FḄᡂ1G34ᓄ6ᑮ8ᑣG:ᨵ⏥=CH,CH.OHNDᵫ&ᑏ@GḄ᪀.CH.OCH.ArCH,OHNDy=/•ᦑCHQ()1-()—C—CH—1(6)BCDEᱥGA.a-H⏚JK:ᨵ.CḄ᪀◀UV᪀LM᜜OᨵAPQ#$AP4#$;WACDEᱥᑖ$Ḅ᪶Zᐳ\"]^ᨵ2_`()14(()—C—CH—<'HᑣaᔠᩩdḄcḄeᑖf᪀gḄ᪀.NH2H(>—CH—C()()CH—C—CH—CH,H([>—cH—C()()CH,ᦑஹHAஹNH.ஹ

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