2022-2023学年湖南省常宁市高考化学模拟试题（三模）有答案

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ᵨ8.ᙠ1LḄᘤᐙᐭ2molᵨ7mol+3U2NH3,%ᢝᐸ(ᩩ*+ᨵ-./0ᑁ23N%Ḅ56786Ḅᐵ:᝞<ᡠ>஺@ᑡBC┯EḄFG3⚓/J30⚓

3A.LFMNB.86OT|KPQRᐭ1molNz1molN%,S⊝ᔣVWᔣXYC.86OZKPWḄS⊝[ᓄ᳛O50%D.aஹc_`aḄbcdPᐸᵯ᩽ᑖOZnO@~ᒹḄZnO஺LOvw/P@ᑡBC┯EḄFOgᣚOA.ḄᵯZnO@Ḅ-OHB.□᩽Ḅᵯ᩽d+llHO-28e=6CO2+28H'2OC.Lvwᙠ◀tuḄsP|}ḄpH~Ꮇj|}+ᨵ-¡¢ᔁG4⚓ᐳ13⚓

4D.vw/Pᳮ¥_᩽tu◀ḄᱥḄ§.¨10.©7ª1d3Ḅ«¬ᐭឤᘤᔠᡂᵬ⏣ᙠ²ᓄᑺᵨ@@´dJCO()+3H(g)^CH,OH(g)+HO(g)AW,<02g22CO(g)+H,(g)^HO(g)+CO(g)A/n22²ᓄ./023+ᨵs86@OSḄ[ᓄ᳛᝞<-1ᡠ>(<¶·⊤>.ᩩ*@C°2ḄS⊝[ᓄ᳛¹86Ḅ-ᓄ)CHQHḄ»᳛᝞<-2ᡠ>஺米Mz25^20g15Ho105fHD0016020025028016020025028086FC86/m<-1<-2@ᑡᨵᐵC½ḄFAAH<02B.250(¾ᑮS⊝PbcOÀÁPbcḄ7/8,PÂÃḄ[ᓄ᳛O30%C.250PĹ86ᓣC°2ḄS⊝[ᓄ᳛ÆÇFᵫÉL86ËᑁÌID.250஺(2͹86ᓣCHJOHḄ»᳛ÆÇÎFᵫÉ86ᓣS⊝⌮ᔣXY11.Ð8@@ᑡÑÒÓÔNaHCChஹNa2cChÕÖḄឋ஺ÑÒ1dᵨpH¢×2§O.lmolL'NaHCOjÕÖḄpH,23pHØO8ÑÒ2d©O.lmolLNaHCChÕÖ7O.lmolLCaCbÕÖ¨Ùᔠ»Ú⁐ÜÝÑÒ3dᔣO.lmolUNa2cChÕÖ¬ᐭCO2ÕÖpHÞ12@ßᑮØO9G5⚓/J30⚓

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6D.〉lmᜧop]qrCH30H(g)Ḅs⊝uᓄ᳛wᔁxyஹ{⌱⚪13.~(⌕ᡂᑖFe20rAiq,Si0FeS?⏚)ᧇᑴᜓᔠ⏚2(Fe2(0H)'(S0jẆḄᑖ7᝞8ᑡ¢£┯¥Ḅ¦§K0H©ªH2sO’©ª®¯FeO23T♦°|~~*\|—T⏚᧡µ¶|~·kHᗐ~|~>|»¼ஹ½¾µFe(OH)(SO)J„2x4ÃĪTᔾᦈIIÆ4¶……¶ἔHIÉÃĪḄ⌕ᡂᑖNa2c஺3A.ÃĪḄÍᵨ¦ᔾᦈ“ᯏ°”▤Ò=Ó1ḄS°zB.ᔠ⏚ÕᵨÖ×ᓄØᩭ¯8ÚᐸÛᡂ=ḄFe"ᐹᨵ®ᓄឋᨵᐵC.ᙠ“ᔠ”▤Ò8àáâFe஺8ᵨ8ãäFe2(஺H)ஹ(SO)J=*å_4D.æ“ƪ”ᑮ“è”ḄT7=éᨵ“◀ấ”rì14.ᙠឤîᩩð8ᔣòᨵóḄ2Lឤõö÷õᘤ=âᐭ°2molNO202moiN°O.lmolC",01üýÉQ2N0,(g)+NaCl(s)NaNO,(s)+NOCl(g)AW,<0⊝ᦪK,ঝ2NO(g)+CL(g)U2NOCl(g)A^<0⊝ᦪ/:lOminᑮ⊝!"#ᘤᑁ&'Ḅ)*+,20%,lOminᑁᵨNOCl(g)⊤0Ḅᙳ2᳛v(NOCI)=7.5x10'mol-L1-min'?ᑡABCᨵEFḄGoA.4NO2(g)+2NaCl(s)=2NaNC)3(s)+2NO(g)+C12(g)Ḅ⊝ᦪLKB.⊝N“J)=2.5x10-ߟRS'T7⚓/V30⚓

7C.ᐸXᩩZ[ᢝCᨵ]^ᙠឤ)ᩩZ?ab^ᑣ⊝ᦪdeᜧD.⊝N°2Ḅiᓄ᳛L60%15.25஺m3^ᔣẓp஺ஹrstuᐭwx⏚^zᔠrsḄpH~]ᓄḄᐵ'᝞ᡠ0,cmXOcmHXO-&⍎஺“⊤0cmHXOjᡈcmXOJ஺?ᑡA┯ḄGA.H2XO3Ḅ2ḄᦪL1.0x10OcmHxcmXOQ>>B,ᙠNaHXOஹrstCOHCH2XOJC.rs¡tឋcmHX஺12cmHzXO>2cmS஺¥Oc2mHxcmXO¥D.¦Cᨵ]^§Ḽx⏚Ḅ©ᐭ^cmH/0j[ᢝeᜧTIIᔁm«⌱⌱g®¯°ETIIᔁḄᦻ²▊´µᔁ¶"ᑖO----------------¸ஹ¹º»⚪16.½¾¿ÀÁᨵḄÂ⌕ᡂᑖGFeOCr?஺,ÉᨵFCOAUOSiO2ÊᩖÌ^ÍÎÏÀÐÑÒᑴᜓáÕᓄÖ×ᧇ^Ï×ᧇឋÌÙÚ^ᨵḼÛᭈÝ⁐ß஺ᐸ¹à»᝞?஺OâãᔁT8⚓^ᐳ13⚓

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12ঝᑡᡂ(1)AᑖḄ₹஺(2)CᱥḄ஺(3)ᵫE!ᡂFḄᓄ#$%&o(4)ᵫB!ᡂC'%জஹD!ᡂE'%ঝḄ*+,-ᑖ.஺(5)ᵨ“*”᪗4DḄ5ឋ78஺(6)K9FḄ:;ᱥᑖ<F=14,K>!?@*+ABC>!DE*+FGHIJᨵLMNOᑣKḄQ᪀ᨵS஺(7)ᑏ4ᵨHUVW2■■Yᯋ8ᧇᑴᜓᓄᔠᱥᜧBrḄᔠᡂ`a(ᐸdefᑺh⌱)13⚓/l30⚓

13

14"ᫀ:1.Dூq@௃A.ᓄtᔆḄvwxyIz{CO?Ḅᔾ▬{BCCO2Ḅ᣸$ᨵᑭ“7W“Aᨵᔠ⚪B.'ᜧwḄ{ᔾᦈᐸC02,wC02ḄJ<$ᨵᑭ“7W”Bᨵᔠ⚪C.ᣓḄC028ᧇᑴ¡ᡂ¢£ᡈ⛴ᧇ¦§¨©ᑴª«ᱥḄ8ᧇᡈ¬ᑮᑴªḄ®£Ḅ◤°:±BCC02Ḅ᣸$ᨵᑭ“7W“cᨵᔠ⚪D.4³´ᙶ¶·¸¹ºzC02Ḅ᣸<»¼wCO?J<ºz$ᨵᨵᑭ“7W“Dᔠ⚪ᦑᔠᳮ⌱⚗9D஺2.Cூq@௃A.(NH4)2Fe(SC)4)2BCᑏᡂ(NH6SOiFeSCU(NH/FelSO)ÊËÌ!?@!ᡂæ⏚ëWæ⏣Ô$%&CH3COOCH2CH3+OH-.CH3COO+CH3CH2OH,CïðD.ᔣò⏚óÊËôzõ?õ?Ìò⏚ó>!öᑖ@*+!ᡂéêᓄó÷øWò⏚╆ú?ᔠõûᵯ@ᙠÔ*+ᨵýþÔ$%&CU2++2NH«HO=2M+Cu(OHR,D┯஺32ᫀ⌱C஺3.Cᫀ1⚓ᐳ16⚓

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17ூBC௃A.“ῃ~ᛞ”CaS+2SO=CaSO+SCaS?/ᑺSC>26ᓄᑺ?/ᑺ242,᪷ᵯHឤ
*6ᓄᑺ?/ᑺᱥOḄP1$2,A┯!$B.S2ஹS4ஹS6S8ᵫSᐗ᪀ᡂḄᨵឋOḄᓫO¡¢£gUB:D"C.¤CaS04᯼§¨ᜐᳮ
«ᱥᐙᑖ¬ZᜧᱥḄ¬☢¯«ᐙᑖC:D"D.±ᛞ~⏚┛᯼§᯼§³6ᓄ´6ᓄµ~⏚┛³᯼§?/~ᓄ┛¶·¸ᡂ±¹ºMCaS,
ᐭῃ~ᛞᜐᳮSO2,¹ºM½¾¿ᑭᵨ,D:D"ᦑᔠᳮ⌱⚗A஺8.BூBC௃A.bÃÄᓣÆÇÈÉ>ḄÊÈËa▊ÍᓣÆÇÈᓄÎÏ⊝⌮ᔣÓÔ⌮ᔾÖᑣḄ:+ÖA:D"B.Ti-ᙠÚÛ-c(N2)=2moi/L,c(H)=7mol/L,çᑮÏ⊝-zNH3ê22mol/L,᪷ë+3B2NHᱥOìᓄᐵî
*Ï⊝-(N)=2mol/L-1mol/L=l3C2mol/L,C(H)=7mol/L-3mol/L=4mol/L,ᑣÇÈ=ḄᓄÎÏ⊝ðᦪK=2--------------z---------------------=U.UuZOC(N)c(“)1X4஺ᙠÇÈT|-±ᐭ1molN21molNH34=óô—=21T=0.0703>0.0625c(2)-c(K)2x4,ᑣᓄÎÏ⊝⌮ᔣÓÔB┯!"C.ÇÈTi-çᑮÏ⊝-c(NH3ê2moi/L,ᑣ᪷ᱥOìᓄᐵî
*ὑ÷N2ḄᱥOḄPÊÈ1mol/L,ᵫøÚÛ-NḄÊÈ2mol/L,ᦑNḄÏ⊝ìᓄ᳛221np"LX100%=50%2m3L,C:D"D.ᓣÆÇÈ>UûtZᜧᵫøÇÈ$aVc,ᑣaஹcýÃþḄûtᜧÿᐵ
PaீPcDᫀ4⚓ᐳ16⚓

18ᦑᔠᳮ⌱⚗B஺9.Cூᑖ᪆௃ᵫ&'()*+ᙠZnO@1234ᜫᵯ78ᡂ:;ᓄ=>?□᩽Ḅᵯ᩽CD,;Fᙠ1234Gᵯ78ᡂH;ᓄI>?0,+2e+2H—H,02▢᩽Ḅᵯ᩽CD஺ூQR௃A.ᵫᑖ᪆()123▢᩽ஹGᵯ7210@123□᩽ஹᜫᵯ7>?1234ḄᵯUV2110@1234ḄWAB.ᵫ&'()*+ᙠZnO@1234ᜫᵯ78ᡂ:;ᓄ=>?□᩽Ḅᵯ᩽CD/=XQH+HHO-28e=6COT+28H+22V_/,B/=X+HHO-28e=6COT+28H+OH22C.ᵫᑖ᪆()ᵯR`□᩽CDaV_7,▢᩽O+2e+2H=HOC^~OH222CDacCDV-/+1lHO+14O2=6CO2t+14HO2ᵫ22cCD()fghᙠi◀*+ḄklmnḄpHpqrᨵtC┯vO+2e+2H+=HO222D.▢᩽CDa8ᡂḄH;ᓄIwx*+CD8ᡂ:;ᓄ=yz,OHCD{|a:+14HO=6COT+17HO,~ᵯRḄcCDa2222OH+11HO+14O=6COT+14HO,ᵫCD{|a()ghlᳮ422222᩽*+◀iḄᱥḄDᫀ⌱C஺10.BூQR௃ᫀ5⚓ᐳ16⚓

19A.25(TCᓣC°2Ḅᓄ᳛ᜧᵬ⏣Ḅ᳛W▊ᓣCOḄ᳛ᜧCDHᔣᑣ¡2>°,ᦑA┯vB.£C°2x¤2Ḅ¥¦ᱥḄᑖ§imolஹ3mol,250஺(3CD¬ᑮ®⊝l°±¥¦l°±Ḅ7/8,¬ᑮ®⊝F²cᱥḄ3.5mol,CO?(g)+3H2(g)UCH,OH(g)+H0(g)CDF²ᱥḄ·¸2CO(g)+3H(g)UCH,OH(g)+HO(g)An222131120.250.750.250.250.5C°2Ḅᓄ᳛40%,º»CDIIḄC°2ḄᱥḄ0.4mol-0.25moi=0.15mol,ᑣº»C°-75+°-15xl00%=DIIḄIFḄᱥḄ0.15mol,?lIFḄᓄ᳛330%,ᦑB;C.CDI¿À250ÁÂᓣC°2Ḅ®⊝ᓄ᳛·¸ᵫfÄᑁÆ⌕È8CDI,ᦑC┯vD.25(rcᓣc02Ḅᓄ᳛ᜧᵬ⏣Ḅ᳛WᵫfÄᑁÆ⌕È8CDH,ᦑD┯v⌱Bo11.CூQR௃A.ÊË1ᵨPHÍÎÏ°ÐmoLL'NaHCOjmnḄpH,ÏGpHÕ8,c(H+)>c(OH”ᑣ=⏚IØmnḄzR|ᜧᵯÙ|஺ᵫÊË1(GÚc(Na)>C(HCO)>C(H2cOÛc(CO)&=ᵪ0Þ3K_H-HCO-HCQ3-H+COK.,aHCO”HCO,C0)=HC03

20B.ÊË2â°ÐmolLNaHCC)3mnxO.lmollÐCaJmn²äåᔠ8æ⁐èé=⏚┛ᑣᵫèémR®⊝ëᳮ)ÊË2ìmnåᔠlᨵc(Ca)c(CO)>KKCaCO3),B┯vC.ᱥḄíḄ=⏚Øîឋᜧ=⏚IØ஺ÊË3°ÐmoLL'Na2cO3mnìðᐭòóḄC°2,mnPHô12õᑮ10,ᑣÊË3ìÈ8CDḄÙ7{|aCOr+HOCO=2HCOc;2+2öD.ᵫ&)Na2c஺3y÷⏚CD¿ÀCDNaHCO,y÷⏚CDᔾÀCD©CDÂ(CO:)>cCD(CO),D┯vᫀ⌱C஺12.CூQR௃Aú).জC0(g)+H20(g)^=iC0ag)+H?(g)A%=-41.20kJmoLঝCHOH(g)^=iCO(g)+2H,(g)AH=+90.64kJ-moL32᪷üýþóÿᵫজ+ঝCHOH(g)+HO(g)UCO(g)+3H(g)A/7=-41.20kJxmoF'+(090.64kJxmo$=+49.44kJxmo$%03222⌱⚗A┯);B.ᵫ,-./0᝱12ᨵO-H4Ḅ67/0᝱2ஹ3ஹ42ᨵC-H467⌱⚗B┯);C.ᵫ,-.ᔊ:3Ḅ;ᓄ=ᨬ?@ᔊ:ACHQ*+H*=CHO*+2H*,ᓽCHZO*=CHO*+H*,⌱⚗cGHID.K᦮ᑴNOḄGAOPPQRᜧḄRᜧTUV⊝⌮ᔣZ[CHQH(g)ḄV⊝\ᓄ᳛^_⌱⚗D┯)I`ᫀ⌱C஺13.BC`ᫀc7⚓ᐳ16⚓

21ூᑖ᪆௃jklmn(o⌕ᡂᑖAFez஺?ஹAI2O3ஹSiO,xyFeS2zk⏚|)ᯏ~FeS?஺22ᡂFe2t)3zS02ᵨᔾᦈᡂḄS02,ᯏ~A1O>FeO,SiO^k⏚|)23232ᐭ“”A1O,SiO2KOHk⏚|/ᑡᜐᳮ23¡¢Ẇ¤o⌕¥FezCh⏚§ᐭ¨©©ᓄ-=ªᙠḄ¬®¯°2o⌕ᨵFe2(SC>4)3§ᐭ©ᓄ±²ᔠ´µஹ¶·¡²ᔠk⏚[Fe2(OH)x(SC>4)y]nI¼°`஺ூ½௃A.ᵫ¾¿ᑖ᪆-.ᯏ~FeS2஺2ᡂFe2()3zISO2,ᓽA4FeS+110=2FeO+8SO,ᵨᔾᦈᡂḄSO2ᓽNa2cO3+SO2=Na2SC)3+CO2ᦑ22232AGHIB.²ᔠk⏚-ᵨÄᓄÅᩭᐸÈᡂ2ḄFe3+ᐹᨵÊËPḄឋÍᨵᐵᐸÈᡂ2ḄFe3+ᐹᨵ©ᓄឋᨵᐵᦑB┯)IC.ᙠ“²ᔠ”▤ÐÑÒ§Fez஺?ᵨyឋ§UxÓᜧᦑC┯)ID.ᵫ¾¿ᑖ᪆-.Ô“”ᑮ“¢Ö”Ḅ/:2ᵫ×ᡂØ©ᓄấN©ᓄÚ2Ûấ⏚|◤ݱ“◀ấ”ᦑDGHI`ᫀABC஺14.CDூ½௃A.4NO(g)+2NaCl(s)=2NaNO,(s)+2NO(g)+C12(g)-ᵫজ,2ঝᑮ᪷¼V⊝âᦪäå2Kæçè-°V⊝âᦪAK?,A⚗GHIB.lOminéᑮV⊝êëᘤᑁPḄTUîx20%,ᑣV⊝ñᔠOPòᱥÍḄyA(0.2+0.2+0.1)molx(l-20%ô0.4mol,lOminᑁᵨNOCl(g)⊤öḄVᙳø᳛v(NOCI)=7.5x10~3mol-L-1-min-1ᑣV⊝n(NOCl)=7.5xlO^mol.1ILmin"xl0minx2L=0.15mol,þéᑮV⊝জ2ὑḄNO2xmoLঝὑḄCbymoL᪷জঝজᡂḄNOCl(g)0.5xmol,ঝὑḄNO(g)2ymol,ὑ&ᫀ(8⚓ᐳ16⚓

22ḄCb/g0ymol,ᡂḄNOCl/g02ymol஺᪷2345ᑡ0.5x+2y=0.15mol(0.2-x+0.2-2y+0.1-y)+0.5x+2y=0.4mol;x=0.1mol,y=0.05mol—ஹ0.1mol-0.05molc(CIJ=---------=--2-.-5-x-l02mol-LlᦑB⊝D-2LB⚗GH;C.B⊝JᦪLMNOPQᐸSᩩUVᢝXᨵZᙠឤ]ᩩU^_`B⊝JᦪK2XᨵZC⚗┯c;D.B⊝eN°2gᓄo/mol,ᦑgᓄ᳛50%,D⚗┯c;ᦑ&ᫀ⌱CD஺15.BDூᑖ᪆௃c/XO0noḄpHrsHXOtH2XO3ḄvOrᜧmxyz⊤lgC/HX°J,nxyz⊤1gc/HXO,0c/%XOj.ூ;௃c/XOt0c/XOt0c/H-0A.ᙠMc/HXO,0=io-i,H2XO3ḄK02=C/HX0J=10-1X10-93=10-103,ᑣᦪ1-0x10'",AGHtc/XOt0c/H+0C/H2XOJC/OH-0B.NaHXChnoḄ=c/HXOt0,“c/HXO0,e/H,XO0-c/OH0c/XOt0c/H+0NaHXChnoḄpH>7,ᑣ஺஺t0>C/HXO0,c/H»/XO0c/OH0.C/HXO,0,B┯ct2C.noឋe᪷ᵯ₹ឤc/HXO>2c/XO»2c/SO0c/Na0᪷ᱥᧇឤ2/HXOt>2c/XOt-0+2c/HXO=c/Na+0ᑣc/HXO02c'/¤XOj=2c/SO0©GHtC23/&ᫀ(9⚓ᐳ16⚓

23c2(H*)c(XO^)e2(H+)c(XOt)D.c(H?XOj=KarK«2,NOXᨵZeK“iஹ¨2XᨵZᡠ“H/OJª«VᢝXᨵZD┯ctᦑ⌱BDo16.(1)¬eNaOHSi°2®N4FeO-A1O+0+12NaOH4NaFeO+8NaAIO+6HO232222(2)V¯ᰚᙽḄnᱥ²ᐰn;´_Fe02µ;ᡂFe(OH)3¶·ᑴᜓº»বA"SiO/-2H*+2CR-=Crq+Hq(4)¬KC1noஹ¬v¼ஹ½ᓾ¿ᨔ10H++3S,O;+2Cr,O^=6SOj-+4Cr'-+5H,O(5)94.9%ூᑖ᪆௃úÄÅᨵḄÆ⌕ᡂᑖÈFe°Cr2C)3ÉᨵFCO.AIQASiO?ÊᩖÌÍÎD¬ᐭÐÑᓄÒÓÔᐭÑÕᰚÖ×ØÙÚºÛÜÑᓄºÛÜCN+ÑᓄCrO,ÑᓄÝÞÑᓄấàÐÑᓄÒᑮNaFeChஹNaCrO>NaA10,NazSiChÊᱥ̽ᓾᑮᰚᙽ¬µn242;FeO/µ;ᡂÐÑᓄº¶·ᔣão1ÔᐭÞÑᓄäåᳮpH7@8,çA10/2-2-2-Si03gᓄA1(OH)3H2SiC)3¶·ᔣão2¬ᐭè⏚êCrQ4gᓄCrzCT,¬ᐭëᓄìnoí¬v¼ஹ½ᓾ¿ᨔஹîãஹïðஹñòᑮKzCnCbóôí¬õÉöᑮCnCh஺(1)÷øᵨúûᙠSiC)2,SiC>2ᙠ®N^üàÐÑᓄÒýþîঝXᨵÿᵨ
ᵨ;ᓄᓄNaFeC)2,ᓄᓄᡂNaA10,᪷ᜫᵯ!ឤ#$!ឤ%&Ḅᓄ()*+2,-4FeO-A1O+஺2+12NaOH=^^4NaFeO+8NaA10+6HO23222(2)/ᫀ110⚓ᐳ16⚓

245ᐭ789:Ḅ;<%=ᱥ?ᐰ=A5BCDFeO2?ᐰ9AᑮᓄJKLM1ᓄᓄOBᑖAᡂᓄQLM1%ᵨRᑴᜓU஺বWᳮpHᵫ\ឋᑮ^_ឋ%3JKbLkᔣLm25ᐭn⏚WᳮpH,qCrO+ᓄCr2஺bḄ)*+2H*+2CrOj^=±Cr,Ob+H,0(4)ᵫRz-{|NaCrO=A{ᜧRKCrO,Q%?ᡂNaCrOᔣKCrOḄᓄ,227227227227ᐹ+5KCI=mஹ5BஹᓾᨔஹLஹஹᓽ%ᑮK2Cr2O7bᯖ⏚᪷ᐹᨵ$ឋCoObᨵᓄឋὅᓄ$ᡂ⏚᪷#᪷ᜫᵯ!ឤஹᵯ₹!ឤ#$!ឤ%&Ḅ)*:1OH++3s2஺b+2Crqb=6S0++4Cr”+5HQ஺ম10431.88txlOO%«ᱥᐗḄ®846.6tx152=31.883CnChḄ«᳛1°a*33.6%=94.9%,17.AH,+AH<2qads)+2Wg)fg)=28g)+2^g)ᡈ0(ads)g)=200(g)CO,+H,0+2e-=HCOO-+OH<75%36ூᑖ᪆௃ூ¼A௃পজ2H*g)+CO(g)UCHQH(g)AH,,ঝÂÃ)+8*g)BHQ(g)+CO(g)qÅ#1ÆÅ)*z5ᑮ+3H2(g)+CC)2(g)UCH30HÇ)+Â0È)AH=AH|+AH2,ᵫ⚪Ê500࠷ÌK=K^K=2.5xl.0=2.5,700࠷ÌK=K,xK=0.34x1.7=0.578,ᑣHI3232Î-{ᓣ,Ð⊝ÒᦪÔÕ▊×ØÙBÚÛHV0bᦑAH+AHஹ

25C(ads)+2H(g)+CO(g)=2CO(g)+2H(g)ᡈC(ads)+CO(g)=2CO(g),ᦑ2222C(ads)+2H(g)+CO(g)=2CO(g)+2H(g)ᡈC(ads)+CO(g)=2CO(g).2222(3)ᵯAçèéCO2ᙢᓄHCOO-,ëḄᓄᔠí+4îàᑮ+2èéPt▢᩽ᵯᵯ᩽)*+CO+HO+2e-=HCOO+0H-.ñ□᩽ᡂó448mL22448xlO3L,_________x4=Ìôᵯᦪ+22.4L-0.08moLõᡂ:᪗«ᱥôᵯᦪ—xlOO%=0.03mol/LxlLx2=0.06mol,ᡠᵯAᦔ᳛0F0875%,ᦑCO,+H2,0+2e'=HCOO+OH…//ZJ7O/
4-{ß,æ᳛ßùᐜûᑮÐ⊝ᵫü&Mýᡠᙠÿᐜᑮ⊝800஺஺ᑣNᡠᙠ700ᓄᓄ᳛▊%!⊝"⌮$%K=K⌮,ᓣ⊝⌮ᔣ)*K+,,KIEMḄᡠ.*⌮ᜧ,1M?஺/:0.8a0.8a0.2a0.2a⊝ᓄ8>?஺/:0.6a0.6a0.6a0.6a0.6஻x0.6஺⊝8>@o/0.4a0.4a0.6a0.6a⊝<ᦪK=04ax0.4a=9KABADᓲ(OC)c(l~^q9=0.8ax0.8a4K⌮,ᦑV⌮k⌮C(S)C(H)=40.2ax0.2a=36,ᦑH>B(3)sp2ஹsp34S/?a3xl0^°xAT,-------------------4132M(NH,)BH7a(4)6284UᫀJ12⚓ᐳ16⚓

26(1)PtḄᵯ^᣸`5[Xe]4f“5d96slᑣPtᙠᐗoᕜM⊤qḄᙢstJKᕜMVHINᜐydTIফ5+3-4x2▢^P0Ḅᵯ^ᦪ=4+2=4,ᵯ^ᦑQ᪀AO☢QIᐗoᔾᵯ^Ḅᐸᵯឋᜧᑣᵯឋᵫᜧᑮ,tN>H>BIᦑAO☢QIN>H>BIব᪷᪀ᡂ4ᐳᓫ¢ḄB£^ᵯ^ᦪt4ஹ᪀ᡂ3ᐳᓫ¢ḄB£^H0ᵯ^ᦪt3,B£^ᩖᓄ¥1¦ὅsp3ஹ©ὅsp2I᝞H,«᪀q¬ᨵ4®¯᛻Ḅ£^ᦑsp3ஹsp214I(4)11জᨔ³qM£^ᦪ=8x8+6x2=4ஹ¶ᑖ^ᦪtM£^ᦪḄ6¸ᡠ.¬ᨵ24¶ᑖ^ஹB£^ᦪt8ஹH£^ᦪtB£^ᦪḄ4¸ᨵ32¹£^ᨔ³qMஹNH>BஹHᦪº»=412418132=1161218,ᐸᓄ¼5MCNHjbB2H8ᦑ3M(NH)BH3628IJ_£
ঝM£^ÄB£^ᨬÆÇᨔ³QÈÉḄa=Wx/xapm=4pm,ᦑa734apmIM,-x4p_N-----------------------------PVNAAঞᨔ³QÐ=(axlOTOcm)3,V,ᑣM(ᓄᔠᱥḄ᥅×Ø8Ù4=Ú23><]0-◘/paS<10^xA^_OÞßà732B24g/moLäåMḄ£^Ø8=4ᦑ4UᫀJ13⚓ᐳ16⚓

2719.(1)106(2)ç¢ஹèéব+H2O(4)ᓄஹêëூᑖ᪆௃ïBḄᑖ^5ðñজòAt,ᐸÄCH3cHOóô%ᑮBBÄCu(OH)2ᙠ?!ᩩ÷ø©⏚ᓄúéûᡂèé%ᑮCCOOH,cᙠüḄOýᓄþÿ
ᡂᑮDBrᙠKOHḄ⏣ᑮ⏚ᓄᫀ14⚓ᐳ16⚓

28COOHE○%&CHOH'()ᓄ*+ᑮF25kᵫ-.ঝ0HḄ1᪀345.G6A7,ᑖ:;<Ḅ:₹>7ᐸᑖ:@6106஺বCOOHBᑖ᪆ᵫE(ᡂF7)ᓄ*+ᓄDEF46:+C2H50HCOOCJHJHI⏚-A~~+HOO2(4)Bᑖ᪆ᵫB(ᡂCJFজ7L%MNᓄ6O%7Nᓄ*+PD(ᡂEJFঝ7Br&QRḄSTHBr7*+஺মBrCOOHD7,ᐸUVWXᓫḄ7Zឋᨵ“*”᪗aḄ:ᫀ15⚓ᐳ16⚓

29(6)K7FḄbcᱥᑣfᨵg*hijᑖ@>Fk14,ᓽmnX"CH/,F7ᑣKḄᑖ46CioHgChHKi'(op*+ᑨrᐸfᨵ)%stT'(uv*+ᑨrᐸfᨵL%wKᑖx⌕zXO5rᐸfᨵHCOO-%j{|}RfᨵzX~ᑣn~fᨵX{fᨵ,ᦑKᑖ|}RḄz~tiᑖ7HCOO-0-CCCH3ஹHCOO-^QHC=CCH-2ஹHCOOCH2-0HC=C-ஹHCOOCC-0-CH3,ᑭτᔠwᨵQஹஹ᪀ᑣKḄ1᪀ᨵ4x3=12஺K-.ঝ5rᐸtᵫ}&2-ᯋ*+ᵨBr2
ᡂᑮᦑᔠᡂ:ᫀ16⚓ᐳ16⚓