2022-2023学年福建省厦门市联考高考化学仿真测试模拟试卷（二模）有答案

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2022
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14.¿Àᜧ\]ÁFᓄᱥ+NOஹNO2-¯ÀḄ1Æ}᝞ÈᡠÉ஺LxNO.ߟ►ᓄ᮱₯ᐝNOX᝱/AN+V!᝱INU¤B¿À₯ᐝÑÒÓÔÕNOḄÖÒὅᡂ$Ê஺@ᑡ|%ḄKA.XÓÛr஺2B.ÝÞᜧ\]ÁFᓄᱥ¹⌕ᩭàᵯáᵨ"C.NO2©ᓄrNCMäå᝱-rFᓄIJ"鼠D.₯ᐝÑÒèᜧᜧ\]NO¯Àèé""即5.@ᑡënì]+ᡈ¤-ᐭîJïᑺ¨ᑨòËᑖ᪆ᙳ$%ḄK一⌱⚗ënìó□+ᡈ¤-ᐭïᑺᑨòËᑖ᪆ANHöஹBa¥ClNOöúÀÛᜧÀᐳûCJNaOHᨵᜧᐳᑡBNa\Mg2+CPHCOMg2++HCO+OH-=MgCOJ+H,O3"嶷卜生ᨵᜧᐳ)A©+"CO-.,4<"CNa\K\A10Cf郦NaHCOsᐰ012ᡂc0256+AI8OH%:;"此至反1;ᨵᜧᐳᑡBᓄDE"DNa\K\CIOSOf?so?"C1O+HO+S0=C1+S0F+2H+解22必JA.AB.BC.CD.D+*6.ᵬKLᙠN/PBᓄᱥḄSᓄTUBᓄVWᓄXᵬ⏣+ᵬZUBᓄV8CH3OOH[,\]^ᜩᯠ5ḄaᦔᑭᵨᐸEᳮ᝞hᡠjᑡkl┯nḄoC)4tpᔁr2⚓ᐳ13⚓ஹ

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ᦑD┯ᦑ⌱Co8.Bூᑖ᪆௃“⁐ᓄᑺ"ᓽHZ02,ᡂḄᐗ"#$ᑣH2°,ᓄᔠᱥNᐹᨵ*+ឋḄ-.(012)ᑣNS°2,᪷56ᓄᐵ8Mᓫ:;஺2ᑖ=ᡂ>ᫀ@3⚓ᐳ13⚓

17°2D0,ᓽM°2,ᵬᙠ⏚H
ᡂIIJᐗᓄᔠᱥKLᨵSᐗ"ᓽIDS,Mᐗ"NOPᦪRSTᜧKVWᕜYᐗ"XH,ZO,WS,XஹZNOPᦪ[ZஹWNOPᦪ[Ḅ1/2,ᑣZNa஺ூ]=௃A.D°,IH?S,`abឋ0>S,ᑣcdeឋH2°>H2S,$fgᑖOhiᙠjkᑣlmH2O>HSA⚗┯o2tB.XஹYஹZஹWMᐗ"pqrᡂst⏚jut⏚juKp
ᡂS02,BvwoC.ZxXஹYஹWrᡂᓄᔠᱥᑖyNaHஹNaO/NaO^Na?S,NaHHHᨬ᜜|ᨵ2222}ᵯOᨵ8ᵯO᪀C⚗┯oD.$ᕜYᐗ"ᑮNO⌲$ᐗ"ᑮ2NO⌲TᜧNOᜧP*Na)>«S)>r(0),⚗┯oDᦑ⌱B஺9.Bூᑖ᪆௃Znᵯ᩽᩽
ᓄZn-2e=Zn2+,LᨵMnChḄᵯ᩽v᩽
NMnO+4H++2e=Mn2++2HO,MnChᒑḄoᐭKI¡ᵯ¢22Ḅ£¤ᦔ᳛§Ḅ¨©ªMnO2+3I-+4H+=Mn2++I3+2H2஺P+2e=3r஺ூ]=௃A.LᨵMnChḄᵯ᩽v᩽«ᵯ᩽Ḅᵯ¬¡Znᵯ᩽ᦑA┯oB.ᐭKI§Ḅ¨©ªMnO2+3I-+4H+=Mn2++[3+2H2O,I3+2e=3h®¯°I;ᙠv᩽²³´ᵯOឮ¶“·ᜫ”ḄpºᦑBvwoC.ᐭKI§Ḅ¨©ªMnO2+3I-+4H+=Mn2++d+2H2஺d+2e=3I-,Ớ¼Oᨵ½¾ὑÀ
ᡂஹÁÂᦑᨵ◤⌕²³ᔣ.8HᐭKIÆ.ᦑC┯oD.Çᵯf᩽ȾὑImolZn,6É2moiᵯOᑣÊᨵ2moiH+ËÌ:OÍᣚÏᐭ>ᫀ@4⚓ᐳ13⚓

18v᩽ᦑ¾ὑ0.5molZnfᨵImolH+ËÌ:OÍᣚÏᦑD┯oᦑ⌱B«10.Dூᑖ᪆௃1OmLO.Imol-L"HXâãH⌲äᐭxmol-1/ḄçgpHéV(N&•î0)ḄTᜧïTᜧᦑÌamḄñòó⊤õᵯpö÷ᓄñòøᩩó⊤pH÷ᓄñòoᵫû®üõᵯpöéçg.ýᐜTᜧᑣäçgÌ©Hÿᵯ
ᓄᵯ
ᓽHX⏚bᵯᨬᑣbNHOាᐰx=01oூ%
௃A.bᵯᨬᑣbNHHzOាᐰ+NH4X,a/012bḄ45ᑣaHX645a789ḄHXஹNH4X;ᔠ+=HXஹᢓᑴ0Ḅᵯ@NHdXB0
CD0Ḅᵯ@ᦑ0Ḅᵯ@F9Gb>a,AIJKB.ᵫᑖ᪆PQx=0.1,ᵫRPQbpH=7,ᑣNH4X+=UVឋXIJKb(NH3-H2°)=(HX),ᵫRPQO.lmol/LḄHX+=pH=2.8,ghc(HX)Ka(10j8)2~0.1mol/L,c(H+)=c(X')=1O-2Xmol/L,ᦑ(N&•஺)=((qᡝ0.1=104,BIJGc(W)xc(X)C.HX+N&-HQUNHK+X-HQḄw⊝yᦪK=c(fc(M)•}c(N~pxc(CH)xc(X)c(N-Qxc(CH)xc(X)_«~•KQx(~~LJA-----7777------c(N-L•HQxc(H>0xc(~•—Qxc(14^xc(CH)'32"\yc(H)=10-46x*6=104810*4ᦪio,,CIJKD.a789ḄHXஹNH4X;ᔠ+=ᵯ₹ឤGc(H+)+c(NHKc(X-)+c(OH)ᱥᧇឤGc(X-)+c(HX)=2c(NHK)+2C(W3,FQ,ὶ᪷@ᙠc(HX)+2c(H+)=c(X-)+2c(NH-HO)+2c(OH)┯ᕒ.32ᫀ⌱D஺ᫀ5⚓ᐳ13⚓

1911.(1)+3(2)ᔲᵫ¥As¦ম+3S"(aq)4=i2AsSJ(¨)©ᐭ«ḄNa?S,+=V‘S)¬ᜧw⊝Iᔣ¯°±ᨵᑭ¥´ồবNa3Ass3+2஺2=NaAsO+3S>I<34(4)2H3ASO+2SO=ASO+2S0-+4H+H0¶Ớ⏚ஹ¸¹+=42232(5)pHº¥7)9,»pHᓣ½H^AsOL¾HAS஺Gᔾ▬ᑺ⊤☢ᡠÅÆᵯ₹¬Ç☟ᵯɬ©ᔾ▬ÊËয1X10-5ூᑖ᪆௃ÌồÍ0©ᐭÎᓄÏÐÑᡂAs2s3´¸As2s3´¸Ó«ḄÎᓄÏЩᐭ¶ÔᓄÕAs2s3+6NaOH=NaAsO+NaAsS+3H,0,ÖqᑮÎᓄÏÐØÙÓÌ3333NajAsCVNa3Ass3ḄØ=LØ=ÔᓄῃÎÑᡂÎᓫÓNajAsOÝ⏚ᓄÞÑᡂH3ASO4,nnß⏚(HQsO”)ᙠ⏚ឋᩩáÊᨵÔᓄឋâsc\ãäÑᡂAsa?஺(I)AsMVÎᐗæᓄᔠç-2,ᑣồᐗæḄᓄᔠç+3çKফèQJII.As2s3(s)+3S"(aq)U2AsSL(aq)L©ᐭ«ḄÎᓄÕ+=V¬ᜧw⊝Iᔣ¯°±ᨵᑭ¥´ồᦑ“´ồ”«FVFeS±ᨵPëᵨ«ḄNa2síᣚGবᵫRPQᔣØ=IIVïᐭÔðDñ“ÔᓄῃΔAsSLÓÔðÑᡂAsOJÓÎᓫòF"a3Ass3+2஺2=NaAsO+3S_34(4)ᵨS°2Dñ“ã䔫F@òFG2H3AsO4+2SO2=As2O3+2SOj+4H'+0,ồ⏚ᐹᨵÔᓄឋPëÓỚ@Ñᡂô¸¹¾õ⁐ḄỚᓫᦑP⌱÷Ḅøùúᑺᨵ¶ᫀ6⚓ᐳ13⚓

20Ớ⏚ஹ¸¹+=;(5)ᵫRPQpH=7)9,»pHᓣ½HzAsOL¾HAsOJ,ᔾ▬ᑺ⊤☢ᡠÅÆᵯ₹¬ÇAs°LüÅÆᵯ₹☟ᵯɬ©ýþÿồḄᔾ▬(6)KSP[Ca3(AsO4)]=8x10-19,eg)2xl(f3mo]/L,ᑣ2(2x10-3)xc2(AsOJ)=8x10Jc(AsOJ)Ḅ௃10-5i/Lxmoo12.(1)2MnO*+16H++10Cl-=2Mn2++5ClT+8HO⚠22(2)!"ᑁḄ$%᣸'(■*+,-.⌼ᡂ1᡾(3)34ᦈ6S2cb(4)E-F789(;!)1=!"(ᡈ?@ABCᐭE!"(ᡈFEᣚ!ᨵHIᮞḄ1=KL(5)S2cl2100࠷MNOBᑖ(QᡂḄSRS2cb2s2cl2+2H2O=3SJ+S02T+4HC1(6)ᦈ6ᑮᨩU⁐WBaClSO12ூᑖ᪆௃Z⚪\]⍝_`ᱥᑴᜓdḄ-.⚪(ef!"Aᑴᜓg%(ᐜef⛳jkl?◀ngᓄp,rᵨt⏚1=(ᙠ!"DwQxyᑴᜓz{(ᙠ!"Eᦈ6(ᵫRxyf}~ᵨg%(+$%ᨵ(◤⌕%ᜐᳮ(M⚪஺(1)!"A\⏚jl⏚xyᑴᜓg%(}2MnOL+16H++10CI-=2Mn2++5Cl?+8HOLᵫDᘤmḄ\⚠22(2)!"ᨵ%ᙠ(ᙠ;OᩩMjtxy(ᦑᐜᡭK1eᐭN2ḄḄ\!"ᑁḄ$%᣸'(■*+,-.⌼ᡂ1᡾(3)S2cbḄ138஺(2,᧕34ᦈ6(ᦑ!"EḄᵨ\34ᦈ6S2c£¡ᫀ£7⚓(ᐳ13⚓

21(4)z{᧕j?xy(!"FḄ?᧕Cᐭ!"E(ᦑ¦!"ᙠ§¨8◍\E-F789(;!)1=!"(ᡈ?@ABCᐭE!"(ᡈFEᣚ!ᨵHIᮞḄ1=KL(5)ᵫ⚪ª«(S2c¬NO᧕ᑖ(®ᑖzQḄS᧕ᙠS2cb(ᦑS2c121()0஺<2MNOBᑖ(QᡂḄSRS2c¬᪷±⚪Ḅª«S2c¬j?xyḄ}2SC1+2HO=3S+SOT+4HC12222(6)ᵫ⚪ª«59஺(3Ḅ59஺(2,²ᦈ6ᑮḄ\59஺஺ᦑ²┵´ᑁḄµ¶\ᦈ6ᑮᨩU⁐Wef⚪Ḅª«·!"ECᐭ!"FḄ%W¸¹ᨵºᓄtjg%(ºὅ¼pᓄ½ᔾᦈBzQt⏚᪷¾¿(MᵨgᓄÀᩭÂ.(ᦑBaCkSO(513.(l)CH(g)+12O(g)=2CO(g)+HO(l)AH=-1299.5kJ/mol22222ফB(3)<(4)Catlßᓄᑺ⌱âឋä(QᡂåzᱥÊæ(ᡈßᓄᑺᜫè(xyé᳛ä)L(5)xy1j2Ḅëxì\%Wᑖ¿ᦪÊæḄxy(%WᵬîḄᱥÛḄᑖᦪÊᜧ(ÍÎÐᨵÒ(Ö⊝WyḄᑖÎÊᜧ(Ö⊝ᔣ⌮xyᔣñò33(1)᪷±⊤Äᦪ±(C2H2ḄÆO-1299.5kJ/moLᦑOᓄÇ}CH(g)225+2O(g)=2CO(g)+HO(l)AH=-1299.5kJ/mol222(2)A.xy1jxy2ᙳxyÉ%Wᑖ¿ᦪÊᜧḄxy(ឤᩩ%WÍÎÏÐᨵѲ7Òᓄ(MᑨÔxyÕÖ⊝(AÐᨵØᔠ⚪ÚB.ឤᩩ(%WÍÛÐᨵÒ(%WÜ]ÝÐᨵÒ(Ðᨵ¸ᑨÔÕÖ⊝(BØᔠ⚪Ú¡ᫀ£8⚓(ᐳ13⚓

22C,xy1jxy2ᙳxyÉ%Wᑖ¿ᦪÊᜧḄxy(%WÍᱥÛḄÐᨵÒ²(%WÖᙳ᥅÷ÛÐᨵÒ(MᑨÔÕÖ⊝(CÐᨵØᔠ⚪ÚD.xy1jxy2ᙳxyÉ%Wᑖ¿ᦪÊᜧḄxy(úWûᑖᦪÐᨵÒ²MᑨÔÕÖ⊝(DÐᨵØᔠ⚪Úᦑ⌱Bo(3)2CH(g)FtC2H29)+34®Ḅ4AH=[2x(-890.3)-(-1299.5)-(-285.8x3)]kJ/mol=+376.3kJ/mol,#$%ᔾ'#$஺᪷*+⊝-./+⊝01ஹ⌮#$4᳛67/ᦑVjE=V⌮/k1c2(CH,=k⌮C(C2H2)d(H2),K=&@⌮/AᑮT2஺(30/Kᵫ1.5Eᡂ3,1#$%ᔾ'#$/ᓣHIJ/+⊝KᦪMᜧ/ᦑTGP(4)QRSTUVW/6X0YᑁᙠCatl]ᵨ_`aḄb᳛H/ᦑᙠᐸdᩩf6X0/gᓄᦔ᳛jHḄkCatlPᙠCat2]ᵨ_/IJHl500P0/WḄb᳛noḄTpqrksgᓄᑺ⌱vឋno/xᡂybᱥM{(ᡈgᓄᑺᜫ~/#$4᳛no)7P(5)ᨵE/ᵬḄᱥḄᑖᦪMᜧ/+⊝SᑖMᜧ/#$12Ḅ1#kaᑖᦪM{Ḅ#$/aSᵬḄᱥḄᑖᦪMᜧ/ᨵE/+⊝ḄᑖMᜧ/+⊝ᔣ⌮#$ᔣPᔠa%Imol,ᑣCH,ḄᱥḄ%0.4mol,ᵨḄᱥḄ%0.6mol,#$1SxᡂC2H2ḄᱥḄ%xmol,#$2SxᡂC2H4ḄᱥḄ%ymol,TᑡWs2cH4(g)AC2H2(g)+3H2ᓄ(mol)2xx3x2CH4(g)A—C2H4(g)+2H2x----0.75ᓄ(mol)2yy2y,x+y=0.4x0.6=0.24,x+y,¡¢x=0.09mohy=0.03mol,ᦑ+⊝0ᔜᱥḄᑖ¥%sCHCHC2H4H,N4222+⊝(mol)0.4-0.09x2-0.03x20.090.030.09x3+0.03x20.6,aḄḄᱥ§ᫀ©9⚓/ᐳ13⚓

230.09x3+0.03x2xl21kPa=33kPaḄ%1.21moLᦑ`aḄᑖ%:1.2114.পIs22s22P63s23P63d24s2ᡈ[Ar]3d24s2iJNF«JriJEJ7TAூ9EJ7IsFsF(2)“TiCLiஹTiBnஹTil%ᑖᨔ/¶᪀6¸/6¹ᑖ4sTiC14

24ì/Ti4+Ḅí_ஹîïஹðñᔜᨵòóô/ᨔáSTi4+Ḅõèᦪk6஺ᦑsP6P(4)ᨵÇÈCHNH3Sᨵõè×/ö÷øù⍝ḄûükH+ᡈ`ÆPR(a)SḄCa?+þR(b)
3ḄC%NHᡈᨵ஺(b)
ᨔᦪ()anm,ᑣ%ᨵPb?+1IxM1----+1./%ᨵCH3NH38x8=1./%ᨵ36x5=3./ᑣᨔ6789%:=dg-cm-3(ᑡ@ABC)஺ᦑH+ᡈECH3NH3ᡈᨵ;-^-x1021aXNA஺15.(1)1,2-KLMN(2)OᡂQRSx/0HবC1VWoO0?,laC1-Y"-H஺)°H(4)Cl+5NaOHA>OH+3NaCl+NaBr+HO2(5)_`aW(ᡈbᱯḄaWdeQR)ClCOOHHHnOnOrQ\/C1A(6)Oᡈூᑖ᪆௃=\/=\ᑭᵨ⚪stu/A(Cl)vClCldeQReᡂBC1Cl,BvCOஹ~0QRX^OHSVOHeᡂC,ᵫDḄy᪀{Cci,CḄᑖC/⌮@CCl»(1)ᫀ11⚓/ᐳ13⚓

25ClKLMN/ᓄL"LMN“2-KLMN:ফA(O1)v/'1QR/eᡂB(C1C1),QROᡂQR஺OᡂQR;বᑣ%ḄVW஺VW;ম☢ᓄ-0H,QRḄḄ:_`aW(ᡈbᱯḄaWdeQR)஺_`aW(ᡈbᱯḄaWdeQR);(6)ᫀ12⚓/ᐳ13⚓

26Cl-OHcr9ᨵᱥCd,ᑖ᪀6¡¢£ᩩ¥Sa.ᨵ¦ᐗ¨©b.ᨵ3.-C1,ª.C«¬1.L®c.vNaHCC>3¯°QRd.᪶²ᐳ³E´ᨵ4µ¶/ª¶·☢¸¹~422:1஺ᑣ¦ᐗ©
ᨵ3.-Cl,1.-COOH,ªᑖy᪀º/ᐸy᪀{¼ᑏᑖ᪀6¾/◤ᐜOÁÂÃ¥/ᯠ᪷Æ▲Èᩩ¥ÉʵË஺ᫀ13⚓/ᐳ13⚓