2017届高考大题专练--有机专练1

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ὃᨵ22ᜩ37.15ᑖ
ᛛᑺᵨὊᵯஹ᯼ஹ■ᔁᩞஹᵯ;ὊὊḄᱯᑴ!஺ᛛᑺG#$%&'()HḄ*+ᔠᡂ./᝞123ᑖ4ᩩ6ᶍ8
9CH3cHC3H6ch»C3Ha—জAটB
ᩩ-------------►HCHI2—O?-ACOOH60ঞᑺ[COOH—1FCHsCHzONaDMFটDJ-©*E©;<:oOoonHIIIICH3CH:ONaᓄᑺe-cHCRl-C-ORஹ+R3—CH.C—OR4----------------------------------------1IDMFᑺRಔ21
BḄIJ2KLMI
N_________________________22P4জḄ4ᩩ6Nᐝ᯿TᨬᐜWᑮḄYZᨵ\ᱥ^᪀`ab஺23ᑏd1ᑡ4Ḅ4fg94ঝb,4টb஺4ᑏdBjD4kᡂGḄ4lma=5ᵬpḄqYZᱥrᱥḄsᑖt᪀)ᨵ+஺26ᑭᵨwxᔠᡂ./ḄyzTwᵬp{|⏣N~ᧇᔠᡂ1☢ᨵ\ᱥ2\ᑺ⌱
஺O4-CHCOOCHCH223ᑏdᔠᡂ./:

137.215ᑖ
21
1,2-q⏣21ᑖ
22
CH2cleH=CH222ᑖ
23
ᡂ421ᑖ
Tᓄ421ᑖ

ᩩ24
nHOOC2CH
COOH+nHOCH2CH
CHOH----->2432oOnHHoeC+22n-l
HO22ᑖ
2(5)10(2ᑖ)(6)(6ᑖT1ᑖ)CTO-C00H⍎஺8஺3CH,CHQH5ுCHjCHOᔙுCH,COOH0HACH,COOCHCH22⏚0'HᰦᔩUKUU30b2

2*¡ὃ£ᨵ21ᜩ38.$ᢙ^¦§&ᱥḄᨵᦔᡂᑖḄᔠᡂ./᝞1ᡠª(3ᑖᑺ{4ᩩ6;ᶍ8):(ᢙ^¦§&ᱥḄᨵᦔᡂᑖ)0«¬1ᑡ⚪9(DCḄ^᪀`ab஺(2)জḄ4ᩩ6b.ঝḄ4fgb஺(3)1ᑡ¯ᢙ^¦§&ᱥḄᨵᦔᡂᑖ°±ᐹᨵḄឋ´µ¶·¸Ḅb(¹º»)஺A.¼ឋ½p¾Ḅ¿TÀÁ½p¾ḄᜧB.±ÃkÄ84C.±Ãk4D.Åᨵ⏚ឋÇᨵÈឋ(4)EjÉÊNaOH¼Ë4ḄᓄÌlmaN»(5)Îᔠ1ᑡᩩ6ḄEḄsᑖt᪀)ᨵ+஺ᑏdᐸ'᪶ÑᐳÓÔÕ'ᨵÖ×ØḄ^᪀`a9஺a.jEᐹᨵÙsḄÚ±ÛÜÚ±ÛÝᙠs*ßàxb.árᱥâ*±jYᓄã¼ËÃkä⁐4(6)æᨵçèḄpéxêëᐭ*íîZèïTðîZçèñஹ¯òxḄÔ~óTôæᨵõèḄpéxêëᐭ*íîZèïTðîZöè(òxḄÔ~ó஺÷øùúdwAN~ᧇᔠᡂCOOHNH2Ḅ./(û᯿⚪'ᢙ^¦§&ᱥḄᨵᦔᡂᑖḄᔠᡂ./üý¬⚪)஺

3þ¬ᫀ
◀᪗᜜2ᑖ
1^PoH3
2ᡈFeJ
lᑖᓄ
1ᑖ(3)AD(4)0=ಟ&+3Na°HCOONa+CH,COONa+2H,0aONa(5)15CHCOO—COOH30Pr
2H4ᓄ0H3I^^COOH6r:''xVCOOH(3ᑖ)/-NO?;⏚

4=>?ὃABᨵ20ᜩ38.G⌱I52ᨵ&ᓄJKẠ(15ᑖ)MN⏣(G)QᵨSTᑴ✏Wᐸᔠᡂ[\᝞^:0HCOH3HBr/H,0CCOOHCOOH(A)(B)NaOH------------>DC,H,OH.AH+/H,0C,HOH5EF?^HSO.A;4CH,ICHJIgBr(ab)OHCH,(G)OH—জR'MgBr(ab)G一*:RCOOC2H5ঝH*/H,0R，hij^ᑡl⚪2(1)GᡠopqrstḄvwᑖxyஹo(2){|}ᔠ^ᑡp~ᩩḄBḄ{ᑖ᪀ᨵq஺i.oᨵᐗᨵp~Kᕈii.ᙠ>ᩩ^sஹ஺(3)␺xEF,¡⌱ᵨ^ᑡAᑺ£Ḅ¤␺xAᑺ(¥¦§)஺a.¨b.ª«¬c.⏚ឋKMnCU«¬d.NaHCCh«¬(4)C—DḄᓄJ´µ¶_________________________________________

55ᱥ¹A
ᑖº¶C7H஺3»ᓄ¼ᓄ½ᑮH
ᑖº¶C7Hl2O3Hᙠ>ᩩ^Q¿HᡂÀÁᱥ1,1ḄÂ᪀öoGjᫀ
1ÅK
2ᑖÆÇ
2ᑖ
22
3ᑖ
3d
3ᑖCH,C.H.OH(4)+2.ÈCOONaNaBr+2H,O(3ᑖ)(5)(2ᑖ)

6=>?ὃABᨵ19ᜩ36ஹ
15ᑖAḄËbQ¿ᵨᩭ⊝b>~ÎÏḄÐNᓄÑÒÓ஺ᵨAÔᧇQ¿ᔠᡂ>q⏚Ö✏ᧇ>q×ØÖ✏ᧇ஺ᐹᔠᡂ[\᝞^ÚᡠÛ
Üᑖᩩᶍ2ij^ᑡl⚪2
DAḄvwy,Ú£×ØḄᑖº¶yo
2BḄÂ᪀öC£oᨵḄrstvwy஺
3Dᓫß✏àᓄᔠᱥsáâãä஺ঠḄᓄJ´µ¶஺
4ডḄÖçy஺
5ᑏéêa^ᑡᩩḄëìØḄᡠᨵ{ᑖ᪀ḄÂ᪀ö2o0IIa.oᨵë-C--Â᪀b.᪶îᐳð¼ñᨵ4òóó☢õö÷322222100o/Cxoযù᯿éC-CH2Ḅᔠᡂ[\ûü>ᩩᵫ2-ÿ
ᑴᜓHzC-CH-CHḄᔠᡂ⌕Ḅᩩ஺

736.ᓄ⌱5ᨵ!ᓄ"Ạ$15ᑖ1'(1ᑖCMOzlᑖ2CH30H2ᑖ1"1ᑖCHcHOH1lHc23-O562(3)2ᑖ49ᓄ1ᑖ2ᑖ(6)ᑖ

8
ὃᨵ18ᜩ21.(15ᑖ)1:;ᔠ<ᵨ>ᨵ!ᔠᡂ?@AḄBCDEFᐸHᳮJNaOH,RCHO+R'CH2cH0ORCH=CCCHOH0(R>RF⊤QR"ᡈT)FUᑖVᓄᔠᱥPVB+2Ḅᔠᡂ[\ᐸ]^⌕ᵨ஺ফH%`FabI.:deᐗ⏣(᝞'e⏣)ijᡂkl;:■HHLCH+KCHC*m0HeKCg-4H0lO-C-CHjCH,OH0-/oᙢIIOII.PCAcḄr᪀J(1)PVAcᵫ]ᓫvwxyzᑮF|ᓫvḄr᪀}~\—_____________________O(2)AḄ᪶ᐳTᨵ_____ᔾᦈ஺(3)abEBnḄCCL,⁐FᑣEḄJ________஺(O)—010(4)Ad,ᔠᡂBḄᓄ@~\____________o(5)CJ~r᪀FᵫBHzᑮFᑣCḄ~r᪀\____________________O

9(6)NᵫAwজঞᔠᡂ஺A.জḄᑺ¢ᩩ\஺B.ঝḄ¤¥\C.ঞḄᓄ@~\஺21.(15ᑖ)(1)CH3co0CH=CH2o(2)2o(3)2-§(:o11CH.OU\/-...+ahCiio-^GH>=aicno+JIOi)®╆2(4)ஹg/OJZo(5)Vo(6)A.³CuNaOH,´µ¶oB.´µᡂ(H)oC.2CH(CH)3OH+O2^2CH(CH)CHO+2HO323222

10·¸ὃᨵ17ᜩ12.(•ᾗ½¾¿)G\]À¥✏ᧇḄÃ⌕ᡂᑖÄFᐸr᪀AÅᨵÆÇÈᐗk.GḄᔠᡂ᝞É(Êᑖmᱥ¢ÊᑖᩩᶍÌ):abজRCH—CH2+CH2—CHRFÎÏCH2—CH2+RCH-CHR1ঝBA᪶ᐳTÐÑQᑖVAᨵ6]ÒÓk᛻ḄTHVoঞD¢F\ÓÕᱥ.Ö×ØÉᑡÚ⚪(1)(CH)2c=CH2ḄÕÜÝÞJ.3(2)AுB?@AàáḄ¤¥âãJஹ.(3)DᑖVAÅᨵḄÅ9äå\,GḄr᪀}~J.(4)jᡂEḄᓄ@~J.(5)ÓæçèÉᑡᩩজdFeC”éjÑ⁐oঝêkëᨵìÇíî"ஹÅC=0ḄFḄÓᑖï᪀vᨵ](Òᒹñòvï᪀)oᐸA᪶ᐳTJ4ஹóôḄᱥõḄr᪀}~J.CHjCHOOOH(6)¸öᵫê'(ᔠᡂFḄÞFᑏøᵫ(ᑴía-1"⏚()Ḅᔠᡂ

11(1)(CH)°C=CH,ḄÕÜÝÞJ2-ᵬ"-1-(.3(2)AüB?@AàáḄ¤¥âãJíîஹxᡂ.(3)DᑖVAÅᨵḄÅ9äå\⏣1"¢þ"FGḄr᪀}~J_(5)ÓæçèÉᑡᩩজdFeCh⁐ঝᨵஹC=0ḄFḄᑖ᪀ᨵ21$(&ᒹ()᪀)ᐸ,᪶.ᐳ0123456ஹ789Ḅᱥ;Ḅ<᪀=>3.CHjCHOOOH(6)ABᵫDEᔠᡂFḄHIJᑏLᵫMEᑴa-QM⏚(OH)ḄᔠᡂUV:CHCH=CH-H^^»CHyH—CH3fH—COOH323•aCH3fH~~€00HBr(LHBrOH

12deAὃghᨵ16ᜩ36.ூᓄlee⌱n5:ᨵpᓄlẠ௃(15ᑖ)CH-CH—C(X)HᓄᔠᱥAte$u⌕ḄwᧇJᐸ<᪀=>3,zᵫᓄᔠᱥᵬᡂ஺ᐸ}ᓄᐵ᝞:GCHOH:জᵬḄᑖ>3C1H|C1O872OH
ᩩঝRHH0+R2-0H-------------*RCH-O-Rᑡ⚪(1)AḄᓄl3_______Aᑖ,ᨬᨵ_____wᜐe☢஺(2)C-FḄ3F,73஺(3)ᓄᔠᱥᵬᡂAஹBḄᓄlH¡>3஺(4)Aᨵ$ᑖ᪀Jᐸ,¢ᔠᑡᩩ¤জ7¥¦§ᡂঝᑖ,J¨ᙠNaOH,89ঞ᪶.ᐳ01¬ᨵ556J¨☢®31:2:2:1:2Ḅ¯______(ᑏ<᪀=>)᪀,ᨵe$°>3±᪀J²wᡈᙠ´µ☢e¶·3±><᪀Jᙠ¶·3><᪀JᑣAḄ±><᪀=>3஺

13¹5ºC0°H¯u⌕Ḅᨵpᔠᡂ¼½,¾¿eJÀÁᵨÃÄஹ✏ᧇஹᛛᧇÇÈᐝ᪛ᾦÌᓄ¼ÍÎJÏ᯿ÑVUJÒÓeᩩÔA3wᧇᔠᡂCOOCH2cH3ḄVU¹ᐸÕgᑺ×⌱º36.¹1ºME⏚¹ᡈ3-ME⏚º¹1ᑖº9¹2ᑖº¹2º¹1ᑖºQஹÙ¹2ᑖº@-CH=CH-COOCHCHjg{-@♦HzO:Ú•°.@-CH=CH-COOH-r@-fCHjCHjOHব“¹2ᑖºH\/HCH=CH-

14deAὃghᨵ15ᜩ38.ூᓄl⌱n5ᨵpᓄlẠ௃(15ᑖ)ÔßAᡈᔠᡂàᑖᓄᔠᱥPMLAḄVU᝞:*+,ᑺäR-CHOHR-COOH2(1)AḄᓄl>3C%,ᐸ᪶.ᐳ012æLç56¨6☢¿®32:1,AḄ3AḄèéᑖ᪀ᨵ$(&ᒹ(A)஺(2)ᵫF}ᓄ3H2MAḄ¯(3)ImolᨵpᱥF¥îïNaHCOsᡂ᪗òéóḄC044.8L,Fᨵ±᪀J2ᐸ><᪀=>¯(4)CḄ<᪀=>¯஺(5)E¥NaOHᙠ§õᩩ¤ḄᓄlH¡>¯»(6)ö÷PMLAᨵ$<᪀JᑏLᵫHMAᑴPMLAḄᓄlH¡>஺(×ᑏ2e$)

15ூᫀ௃¹15ᑖº¹1º1,3eùúE¹2ᑖº2¹2ᑖº¹2º§ᡂ¹2ᑖºHOOCஹ_/CHCH=CHCH?2¹3º"C=cஹcgH¹2ᑖº¹4ºOH°H¹2ᑖºHOOC-CH-CHCOOH+3NaOH►NaOOC-CH-CHCOONa+N»CI+2HO222(5)&OH(2ᑖ)nHOOC-CH'-q+OHᩩHOj-C-CH3CH-O-|-H+(n-IJH/JnHOOC-CH-CH-OH^^^1_^__1.2HOCHOH+(n1)H/)COOHI8HliᡈCOOH(3ᑖᐸᔠᳮᫀᑖ

16