inorganic chemistry in aqueous solution (tutorial chemistry texts 21) (jack barrett) rsc 2003外语英文电子书

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1、Coverimages,(MurrayRobertso1i:visualelements1998-99.takenfromthe109VisualElementsPeriodicTable,availableatwww.chernsoc.orgjviselementsPrefaceWaterisanimportantmolecule.Seventy-onepercentoftheEarth’ssurfaceiscoveredbyliquidwater.itisthemostabundantniole

2、cule,anditisagoodsolventforpolarandionicsubstances.SamuelTaylorColeridge’sAncientMarinerknewthis:Thelackofpurewaterfordrinkingpurposesandthelackofwatersufficientlypureforirrigatingthelandaremajorchallengesforthehumanrace.Thisbookoffersnosolutionstosuch

3、severeproblems.Itconsistsofareviewoftheinorganicchemistryoftheelementsinalltheiroxidationstatesinanaqueousenvironment.Chapters1and2dealwiththepropertiesofliquidwaterandthehydrationofions.Acidsandbases,hydrolysisandsolubilityarethemaintopicsofChapter3.C

4、hapters4and5dealwithaspectsofionicformandstabilityinaqueousconditions.Chapters6(s-andp-block),7(d-block)and8(f-block)representasurveyoftheaqueouschemistryoftheelementsofthePeriodicTable.Thechaptersfrom4to8couldforinaseparatecourseinthestudyoftheperiodi

5、cityofthechemistryoftheelementsinaqueoussolution,chapters4and5givingthenecessarythermodynamicbackground.Ainoreextensivecourse,orpossiblyasecondcourse,wouldincludetheverydetailedtreatmentofenthalpiesandentropiesofhydrationofions,acidsandbases,hydrolysis

6、andsolubility.Therearemanytablesofdatainthetextandtheauthorhasspentmuchtimeinattemptingtoensuremaximumconsistencywiththevariousavailablesources.IthankMartynBerryforreadingthemanuscriptandforhismanysuggestionsthatledtoimprovementsinthetext.JackBarrettKi

7、nystoii-zipon-TlianiesiiiLDITOR-IY-CHIEFEXECLlTlVttDlIORSFDUCATIONALCONSULTANIProfi..s.vorEWAhelPrc~fissorAGDailiesMrMBerryProfissorDPhillipsProfessorJDWoollinsThisseriesofbooksconsistsofshort,single-topicormodulartexts,concentratingonthefundamentalare

8、asofchemistrytaughtinundergraduatesciencecourses.Eachbookprovidesaconciseaccountofthebasicprinciplesunderlyingagivensubject,embodyinganindependent-learningphilosophyandincludingworkedexamples.Theonetopic,onebookapproachensuresthattheser