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1、CoordinationChemistryReviews231(2002)109/149www.elsevier.com/locate/ccrRemarkablereactionsofcationiccarbynecomplexesofmanganese,rhenium,anddiironwithcarbonylmetalanionsJiabiChen*,RuitaoWangStateKeyLaboratoryofOrganometallicChemistry,ShanghaiInstituteofOrganicChemistry,Chi
2、neseAcademyofSciences,354FenglinLu,Shanghai200032,People’sRepublicofChinaReceived23October2001;receivedinrevisedform1February2002ContentsAbstract.........................................................................1091.Introduction......................................
3、.............................1092.Synthesesofcationiccarbynecomplexesofmanganese,rhenium,anddiiron...............................110552.1Synthesesof[h-C5H5(CO)2Mn/CPh]BBr4(1)and[h-C5H5(CO)2Re/CPh]/BBr4(2).....................110552.2Synthesesof[Fe2(m-CO)(m-CAr)(CO)2(h-C
4、5H5)2]BBr4and[Fe2(m-CO)(m-CAr)(CO)2{(h-C5H5)2SiMe2}]BBr4........110553.Reactionsof[h-C5H5(CO)2Mn/CPh]BBr4(1)and[h-C5H5(CO)2Re/CPh]/BBr4(2)withmetalcarbonylmonoanions......111554.Reactionsof[h-C5H5(CO)2Mn/CPh]BBr4(1)and[h-C5H5(CO)2Re/CPh]/BBr4(2)withmetalcarbonyldiani
5、ons........122555.Reactionsof[h-C5H5(CO)2Mn/CPh]BBr4(1)and[h-C5H5(CO)2Re/CPh]/BBr4(2)withthereactivesalts[Et3NH][Fe2(m-CO)(m-ER)(CO)6](E /S,Se).............................................................125556.Reactionsof[h-C5H5(CO)2Mn/CPh]BBr4(1)and[h-C5H5(CO)2Re/CP
6、h]/BBr4(2)withcarbonylmetalanionscontainingNCO,SCN,andCNgroup..............................................................131557.Reactionsof[Fe2(m-CO)(m-CAr)(CO)2(h-C5H5)2]BBr4and[Fe2(m-CO)(m-CAr)(CO)2{(h-C5H4)2SiMe2}]BBr4withnucleophilescontainingS,O,andNatoms..........
7、...............................................137558.Reactionsof[Fe2(m-CO)(m-CAr)(CO)2(h-C5H5)2]BBr4and[Fe2(m-CO)(m-CAr)(CO)2{(h-C5H4)2SiMe2}]BBr4withthe[(m-S)(m- SPh)Fe2(CO)6]anion.............................................................14059.Reactionsof[Fe2(m-CO)(m-
8、CAr)(CO)2(h-C5H5)2]BBr4withthereactivesalts[Et3NH][Fe2(m-CO)(m-SR)(CO)6]............14251
