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时间:2018-02-10
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1、Chapter6Extrusioncoatingandproductapplicationscoating-betterheat-sealability:extrudingthesurfacelayeratalowertemperaturereducestheoxidationofthepolymer.Selectionoftheheat-sealableskinpolymercanprovidegoodheatsealingpropertiesbyusing,forexample,anionomer-layerscontainingadditive
2、sandpigments:onlythesurfacelayerneedstocontainanyadditivestoreducecostandprotectthediemetal.Twodissimilarcolorsarealsopossible.-lessmanufacturingprocesses:machinetimesavings-polymersthataredifficulttoprocesscanberunsupportedbyotherpolymers-increaseincapacity-combinepolymershavi
3、ngspecialbarrierpropertiesasthinlayersasarenecessary-nonslipsurfacesorultralowheatsealtemperaturesbytheselectionoftheskin-polymer.6.3.4LaminatingsystemFigure24showsthelaminatingsystemconsistingofpressure,stripping,andchillrolls.Figure24.Structureofatypicalchill-rollinextrusionc
4、oating.Thepurposeofthelaminatingoperationistocreateadhesionbetweentheresinandthemovingwebandtosolidifytheresin33.Thelaminatingsystemnormallyhasapositionsuchthatonecanvarytheverticalandhorizontaldistancesfromthedieliptothelaminatingnip.Figure25showsthisairgap.Thetypicalairgapadj
5、ustmentprovidesanoptimumtimeforoxidationofthepolymermeltsurfacetooccur.Atypicalresidencetimeis100ms.Ahighresidencetimeleadstoexcessiveoxidation.Thisimprovesadhesionbutalsocausescoolingofthemelt.Suchcoolingcanweakenadhesion.Highresidencetimesathighlinespeedsrequireairgapsofappro
6、ximately30cmleadingtoalargeneck-in.Thiscauseswastefromthickandwideedgebeads.Figure25.Laminator33.Thesolidificationofthemoltenresininthecontinuousextrusioncoatingprocessrequiresefficientcoolingperformancefromthechillroll.Double-walled,spiralchillrollscanprovideadequatecooling.Th
7、etemperaturerangeofthecoolingwaterisoften15−25癈.Thesurfacefinishofthechillrolliscritical.Itdeterminesthereleasecharacteristics,theopticalproperties,andthecoefficientoffriction(COF)ofthecoating.Aglossyorpolishedfinishproduceshighopticalpropertiesofexcellentgloss,goodtransparency
8、,andlowhaze.PolishedfinishesalsoprovidehighCOFandpoors
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