最新有机合成教学讲义ppt.ppt

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1、有机合成参考书1、《有机合成设计》斯图尔特.沃伦著(英)丁新腾,林子森译2、《有机合成》斯图尔特.沃伦著(英)丁新腾译3、《基础有机化学》邢其毅主编4、《新编有机合成化学》黄宪、王彦广、陈振初编著----PreparationofAlkane----1.HydrogenationofAlkenes2.ReductionofAlkylHalides3.CouplingofAlkylHalideswithOrganometalicCompounds----PreparationofAlkene----1.Dehydrohalog

2、enationofAlkylHalide2.DehydrationofAlcohols3.DehalogenationofVicinalDihalides4.ReductionofAlkynes----PreparationofAlkene--------PreparationofAlcohol----1.Oxymercuration-Demercuration2.Hydroboration-Oxidation3.GrignardSynthesis4.HydrolysisofAlkylHalides5.Hydroxylati

3、onofAlkenes----PreparationofAlcohol--------PreparationofHalide----1.FromAlcohols2.HalogenationofCertainhydrocarbons3.AdditionofHydrogenHalidetoAlkenes4.AdditionofHalogentoAlkenesandAlkynes5.HalideExchange----PreparationofHalide--------PreparationofEther----1.Willia

4、msonSynthesis2.Alkoxymercuration-Demercuration----PreparationofEther--------PreparationofAlkylbenzene----1.Friedel-CraftsAlkylation2.ConversionofSideChain----PreparationofAlkylbenzene--------PreparationofPhenol----1.HydrolysisofDiazoniumSalts2.AlkliFusionofSulfonat

5、es----PreparationofPhenol--------PreparationofAmine----1.ReductionofNitroCompounds2.ReactionofHalideswithammoniaorAmines3.ReductiveAmination4.ReductionofNitriles5.HofmannDegradationofAmides----PreparationofAmine--------ReactionofDiazonium----1.ReplacementofNitrogen

6、2.Coupling----ReactionofDiazonium--------PreparationofAldehyde&Ketone----1.OxidationofPrimaryAlcohols2.OxidationofMethylbenzene3.ReductionofAcidchlorideAldehydeKetone1.OxidationofSecondaryAlcohols2.Friedel-CraftsAcylation----PreparationofAldehyde&Ketone--------Reac

7、tionsofAldehyde&Ketone----1.Oxidation2.Reduction3.AdditionofCyanide4.AdditionDerivativesofammonia5.AdditionofAlcohols6.CannizzaroReaction7.AdditionofGrignardReagent----ReactionsofAldehyde&Ketone--------ReactionofCarbanion----1.Halogenationofketones2.NucleophilicAdd

8、itontoCarbonylCompounds3.NucleophilicAcylSubstitution----ReactionofCarbanion--------SubstitutiononAromaticRing----1.Nitration2.Sulfonation3.Halog