离子液体全英文简介ppt课件.ppt

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1、CatalysiswithIonicLiquids:ProgressandProspectsYouquanDENGCentreforGreenChemistryandCatalysisLanzhouInstituteofChemicalPhysicsChineseAcademyofSciencesLanzhou,730000,China1.INTRODUCTION:WhatareionicliquidsRoomtemperatureILscontainorganiccationsandinorganicanionsN-alkylimidazolium

2、N-alkylpyridiniumquaternaryammoniumquaternaryalkylphosphoniumFunctionalgroupse.g.X=NH2,SO3H,CO2H,etc.incorporateduponthesidechainofImidazolium[CF3COO]-[CF3SO2]-[BF4]-[PF6]-[(CF3SO2)2N]-AirandwaterstableDecreasingcoordinatingabilibityIncreasinghydrophobicitySecondgenerationILsTypic

3、alcations[AlCl4]-[AuCl4]-[PdCl4]2-TypicalanionsReactivetowaterFirstgenerationILsFunctionalILsThirdgenerationILsNew!Chloroaluminate1.INTRODUCTION:PropertiesofionicliquidsLowermeltingpoint:＜-90oCNegligiblevaporpressure:GreensolventsLargeliquidrange＞200oCSelectivedissolvability:‘liqu

4、id’zeoliteDesignable:Acidity,Density,HydrophilityDiversity:overatrillionpossibleGoodelectrechemicalsatbility:E.W.ca5VHighthermalstability>400oCILscontaning1-alkyl-3methylimidazoliumcationsStrongcoulombicforce:MuchdifferentfrommolecularsolventsILspossesssomespecialphysicalandchemic

5、alpropertiesreasonablygoodelectricalconductivity(25mS/cm)1.INTRODUCTION:GeneralsituationofILsresearchca.200papershaveappearedonthe226thACSNationalMeetingHundredspatentsonILshavealsobeenissuedCatalysisOrganicsynthesisSeparation&analysisFunctionalmaterialslifesciencesThefigureillust

6、ratesthegrowthinpublicationsonILsAtleastanother500paperswillappearedbytheendof2003TherehasbeenmuchworkperformedonILsasreactionmediaorfunctionalmaterialsLubricants,sensing&opticalmaterialsStationaryphaseforGC,treatingnuclearwasteElectrochemistryNanotechnologyCleanenergyHeack,Beckma

7、nnetcNano-metalparticles,filmElectrolytes,ElectrodepositionElectrolytesforsolarcell,batteryArtificialmuscle,drugreservoirs1.INTRODUCTION:GeneralresearchsituationofcatalysiswithILsILsascatalystsorreactionmediahavebeenreportedtohaveexcellentperformancesformanycatalyticreactionsCatal

8、yticreactionsusingILsasreactionme