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1、ModellingofanInductivelyCoupledPlasmaTorch:firststepAndréP.1,ClainS.4,DudeckM.3,IzrarB.2,RochetteD1,TouzaniR3,VacherD.11.LAEPT,ClermontUniversity,France2.ICARE,OrléansUniversity,France3.InstitutJeanLeRondd’Alembert,UniversityofParis6,France4.LM,ClermontUniversity,,FranceCompositio
2、ninmolarfractionMars97%CO2;3%N2Titan97%N2;2%CH4;1%ArICPTorch:atmosphericpressureLowflowofgazAssumptionsThermalequlibriumChemicalequilibriumOpticalThinplasmaSimpleCase!CompositionSpectrallines,SpectroscopymeasurementsTransportCoefficientsModellingThermodynamicPropertiesRadiativelos
3、stermInteractionPotentialsCompositionSpectrallines,SpectroscopymeasurementsTransportCoefficientsModellingThermodynamicPropertiesRadiativelosstermInteractionPotentialsChemicalandThermalequilibrium:GibbsFreeEnergyminimisationDaltonLawElectricalNeutralityChemicalspecies:MarsMonatomic
4、species(11):C,C-,C+,C++,N,N+,N++,O,O-,O+,O++Diatomicspecies(18):C2,C2-,C2+,CN,CN-,CN+,CO,CO-,CO+,N2,N2-,N2+,NO,NO-,NO+,O2,O2-,O2+Poly_atomicspecies(23):C2N,C2N2,C2O,C3,C3O2,C4,C4N2,C5,CNN,CNO,CO2,CO2-,N2O,N2O3,N2O4,N2O5,N2O+,N3,NCN,NO2,NO2-,NO3,O3e-,solidphase:graphiteTitan:Monato
5、micspecies(13):Ar,Ar+,Ar++,C,C-,C+,C++,H,H+,H-,N,N+,N++,DiatomicSpecies(18):C2,C2-,C2+,CN,CN-,CN+,CO,CO-,CO+,N2,N2-,N2+,NO,NO-,NO+,O2,O2-,O2+Poly_atomicspecies(26):C2H,C2H2,C2H4,C2N,C2N2,C3,C4,C4N2,C5,CH2,CH3,CH4,CHN,CNN,H2N,H2N2,H3N,H4N2,N3,NCN,H3+,NH4+,C2H3,C2H5,C2H6,HCCNe-,soli
6、dphase:graphiteTocalculateingasphase,weconsiderthetemperaturerange[3000;15000]MarsTitanMarsTitanCompositionSpectrallines,SpectroscopymeasurementsTransportCoefficientsModellingThermodynamicPropertiesRadiativelosstermInteractionPotentials*Intensitiescalculation(Boltzmanndistribution
7、)MarsLineCI2582.910-10mCompositionSpectrallines,SpectroscopymeasurementsTransportCoefficientsModellingThermodynamicPropertiesRadiativelosstermInteractionPotentialsThermodynamicpropertiesMassicdensity:ρInternalenergy:eCompositionSpectrallines,SpectroscopymeasurementsTransportCoeffi
8、cientsModellingThermodynamicPrope