浙江大学兰氏化学手册 Section 1 Organic Compounds.pdf

浙江大学兰氏化学手册 Section 1 Organic Compounds.pdf

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1、DEAN#37261(McGHP)RIGHTINTERACTIVEtopofpageSECTION1ORGANICCOMPOUNDS1.1NOMENCLATUREOFORGANICCOMPOUNDS1.11.1.1NonfunctionalCompounds1.1Table1.1NamesofStraight-ChainAlkanes1.2Table1.2FusedPolycyclicHydrocarbons1.8Table1.3SpecialistNomenclatureforHeterocyclicSystems1.11Table1.

2、4SuffixesforSpecialistNomenclatureofHeterocyclicSystems1.12Table1.5TrivialNamesofHeterocyclicSystemsSuitableforUseinFusionNames1.13Table1.6TrivialNamesforHeterocyclicSystemsThatAreNotRecommendedforUseinFusionNames1.161.1.2FunctionalCompounds1.17Table1.7CharacteristicGroups

3、forSubstitutiveNomenclature1.18Table1.8CharacteristicGroupsCitedOnlyasPrefixesinSubstitutiveNomenclature1.19Table1.9FunctionalClassNamesUsedinRadicofunctionalNomenclature1.221.1.3SpecificFunctionalGroups1.23Table1.10RetainedTrivialNamesofAlcoholsandPhenolswithStructures1.24

4、Table1.11NamesofSomeCarboxylicAcids1.30Table1.12ParentStructuresofPhosphorus-ContainingCompounds1.361.1.4Stereochemistry1.391.1.5ChemicalAbstractsIndexingSystem1.49Table1.13NamesandFormulasofOrganicRadicals1.511.2PHYSICALPROPERTIESOFPURESUBSTANCES1.58Table1.14EmpiricalFor

5、mulaIndexofOrganicCompounds1.58Table1.15PhysicalConstantsofOrganicCompounds1.741.1NOMENCLATUREOFORGANICCOMPOUNDSThefollowingsynopsisofrulesfornamingorganiccompoundsandtheexamplesgiveninexpla-nationarenotintendedtocoverallthepossiblecases.Foramorecomprehensiveanddetailedde

6、scription,seeJ.RigaudyandS.P.Klesney,NomenclatureofOrganicChemistry,SectionsA,B,C,D,E,F,andH,PergamonPress,Oxford,1979.ThispublicationcontainstherecommendationsoftheCommissiononNomenclatureofOrganicChemistryandwaspreparedundertheauspicesoftheInternationalUnionofPureandApp

7、liedChemistry(IUPAC).1.1.1NonfunctionalCompounds1.1.1.1Alkanes.Thesaturatedopen-chain(acyclic)hydrocarbons(CHn2n2)havenamesendingin-ane.Thefirstfourmembershavethetrivialnamesmethane(CH4),ethane(CH3CH3orC2H6),shortpropane(C3H8),andbutane(C4H10).Fortheremainderofthealkanes,

8、thefirstportionofthenamestandard1.1baseofDFDEAN#37261(McGHP)LEFTINTERACTIVEtopofrh1.2SECTION1base

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