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《Showcasing research from Professor Wei Wang’s laboratory,School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China.展示王玮教授实验室地研究成果, 南京化学化工学院 中国南京大学.pdf》由会员上传分享,免费在线阅读,更多相关内容在教育资源-天天文库。
1、ShowcasingresearchfromProfessorWeiWang’slaboratory,Asfeaturedin:SchoolofChemistryandChemicalEngineering,NanjingUniversity,Nanjing,China.MonitoringthedynamicphotocatalyticactivityofsingleCdSnanoparticlesbylightingupH2nanobubbleswithfluorescentdyesStudyingthesemiconducto
2、rphotocatalysisatsinglenanoparticlelevelisdesiredforunderstandingthemicroscopicreactionkineticsandmechanismwithimplicationsfordesigningbettercatalysts.Inthepresenceofhydrophobicfluorescentdyes,individualH2nanobubblesgeneratedduringthephotocatalysisofsingleCdSnanopartic
3、leswerevisualizedunderconventionalfluorescentmicroscopybecauseitrecruitedandaccumulatedfluorescentdyesattheliquid-gasinterface.Inthismanner,thephotocatalyticSeeWeiWangetal.,activityofsingleCdSnanoparticlecanbemonitoredandChem.Sci.,2018,9,1448.quantified,whichwasfoundtody
4、namicallyfluctuateamonghighactivity,lowactivityandinactivestates.rsc.li/chemical-scienceRegisteredcharitynumber:207890ChemicalScienceViewArticleOnlineEDGEARTICLEViewJournal
5、ViewIssueMonitoringthedynamicphotocatalyticactivityofsingleCdSnanoparticlesbylightingupH2Citethi
6、s:Chem.Sci.,2018,9,1448nanobubbleswithfluorescentdyes†HuaSu,YiminFang,FangyuanChenandWeiWang*Thecapabilityofsemiconductornanomaterialstoconvertsolarenergytochemicalenergyhasledtomanypromisingapplications,forinstance,photocatalyzedH2generation.Studyingthisimportantphoto
7、catalyticreactionatthesinglenanocatalystlevelprovidesagreatopportunitytounderstandthemicroscopicreactionkineticsandmechanismbyovercomingthechemicalandstructuralheterogeneityamongindividuals.Herewereportafluorescence(FL)labelingstrategytovisualizeindividualH2nanobubbles
8、thataregeneratedatsingleCdSnanoparticlesduringphotocatalysis.Inoperandoimagingofnanobubblegrowthkineticsallowsfordeterminationofthephotocatalyticactivityofsinglenanocatalysts,whichwasfoundtorandomlyalternateamonghighactivity,lowactivityandinactiveCreativeCommonsAttrib
9、ution-NonCommercial3.0UnportedLicence.states.InadditiontoH2nanobubbles,thepresentlabelingstrategyisalsosuitableforothertypes