苯甲酰甲酸酯类及可聚合光引发剂的合成与性能研究.pdf

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Synthesisandpropertiesofphenylglyoxylicacidesterandpolymerizab

2、lephotoinitiatorADissertationSubmittedfortheDegreeofMasterOnChemistryEngineeringbyChunhuiZhangUndertheSupervisionofAssociateProf.RongZhongSchoolofEnvironmentalandChemicalEngineeringNanchangHangkongUniversity,Nanchang,ChinaNov,2015fgD=EFGH6IJKLMNOPQRSTUVWFXYZ[]^E^_`Fab*cdefgh

3、iGH6jkdUlmn#———GoVp]KGH6IJUVWT8dOqPTrsUVWFtu(Vvrwxyz{UGoVpE

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5、84.4%i~·û¸¹º»¼jF;½¾U¿îxz{FÀ¥¬CÁÂÃ#ÄK251.1nmô298.8nmfiÅÆGH6ÇÈdFZ5%UD-BFoVB-206åɾôTMPTAÊjåáËÌz{FÍ6¶û84%i2.âïñóñòô2959ûü†F°¢£6§YáãPrÖ•¶UGoVpBF-2959i°¢ß®©™ÎrkÏÐÑçXTéPµ∂iáãBF-2959U¬√U∫ªºƒ"ñï⊬∆pF§Y«»6hF§Y…¬105Fñ®¯ò°û±6pFïñóñò;2959U²³´†µû1:1.1F~¶û91.4%i~·û¸¹º»¼jF;½¾U¿îxz{FÀ¥¬CÁÂÃ#Ä

6、K246.1nmô320.9nmfiÅÆGH6ÇÈdFZ4%UBF-2959oVB-206åɾôTMPTAÊjåáËÌz{FÍ6¶û93%i3.âñÚÓÔòô2959ûü†F°¢£6§YáãPrÖgåáUGoVp2959-MMAi°¢ß®©™ÎıÖçXTéPµ∂iáãD-BFU¬√U∫ªºƒ"ñï⊬∆pF§Y«»4hF§Y…¬100Fñ®¯ò°û±6pFñÚÓÔò;2959U²³´†µû1:1.2F~¶û87.8%i~·û×ع¼jF;½¾U¿îxz{FÀ¥¬CÁÂÃ#ÄK255.7nmô315.2nmfiÅÆGH6ÇÈdFZ3%U2959-M

7、MAoVB-206åɾôTMPTAÊjåáËÌz{FÍ6¶û96%ihij#GH6FGoVpF£6§YFgåáIABSTRACTInrecentyears,UV-curingtechnologyinChinahasdevelopedquicklyandhasbeenwidelyappliedindailylife.Asanimportantpartoflight-curingsystem,photoinitiatorhasbeenrapidlygrownupwiththedevelopmentofUV-curingtechnology,it’s

8、necessarytodevelopsomeotherbetterperformancephotoinitiatorstomeettheneedofproduction.Inthispaper,twokindsofphotoinitiatorwerejoinedtogetherbychemicalbondandpolymericphotoinitiatorsweresynthesized,someresearchresultsofphotoinitiatorsperformanceareasfollows:1.Withphenylglyoxyli

9、cacidandtriethyleneglycolasrawmaterials,anovelphotoinitiator(D-BF)wa