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时间:2020-03-01
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1、Theterm"enzyme"wascoinedbyWilhelmKuhne.创造crystallized结晶centrifugalsupernatant离心上清液wereusedtoimitateenzymesmesoporous介孑L材料,多孔DMF-2甲基甲酰胺Polymerwithenzyme-likeactivity聚合物noble-metalnanoclusters贵金属纳米团簇Inthepresenceofdopamine在多巴胺的存在下Molecularlyimprintedpolymerswereinventedby分子£卩迹聚合物Nano
2、ceriaassuperoxidedismutasemimic.纟内米二氧化饰作为超氧化物歧化酶模拟。peroxidasemimic.过氧化物模拟酶catalase,过氧化氢酶Nmnoceriaascatalaseandoxidasemimic纟内米二氧化肺过氧化氢酶和氧化酶模拟metalsulfide硫化物cobaItporphyrinicmanganese^facile温和的chemicalsandreagents化学药品和试剂syring注射器thioacetamide硫代乙酰胺stretchingvibration伸缩振动峰carbonylgroup
3、碳基aromaticacid芳香酸calibrationcurve校准线havebeenextensivelyexploredtomimicthestrueturesandfunctionsofnaturalenzymesthroughvariousapproaches・andseveralmonographsandnumerousexcellentreviewshavebeenpublishedhavebeenfoundtoexhibitunexpectedenzyme-likeAlthoughtheprogressandachievementsofcla
4、ssicartificialenzymeshavebeenthoroughlyreviewedintheliterature,nocomprehensivereviewhasbeendevotedtonanozymeswediscussthecurrentchallengesfacingnanozymetechnologiesandfuturedirectionstorealizetheirgreatpotential・新方法Hybridmaterials(杂化材料)formedbyincorporatinginorganiematerialsintoapo
5、lymericmatrixhaveevenmorepromisingadvantages,suchasnovelfunctionalities,enhancedbiocompatibilityandimprovedmechanicalandchemicalproperties・Comparedwithnaturalenzymesandorganiccatalysts,theefficiencyofmostnanozymesarestilllower・Therefore,thedevelopmentofhighperformancenanozymeswillb
6、eahottopicforfutureresearch・Followingtheseearlyworks,wefoundthatthepH-tunableoxidationabilityofnanoceriatoferrocenecarboxylicacid(Fc-COOH).51CeO2nanoparticles,whichexistinamixedvalencestate(Ce3+,Ce4+),possessmanyuniquepropertiesthathaveproventobeofhighutilityinbiomedicalandcatalyti
7、capplications.8,52-57Recen什ySignificantactivityenhancementindicatedthatGOplayedanimportantroleinmodulatingthecatalyticactivityoftheAuNCs.综述InthisAccount,wefocusonourrecentprogressinexploringandconstructingsuchnanoparticulateartificialenzymes,Weexpectthatnanozymeswithuniquepropertie
8、sandfunctionswillattractin
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