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1、LiteratureHighlightsAutomationHighlightsfromKerstinThurow,Ph.D.theLiteratureHilmarWeinmann,Ph.D.LABORATORYAUTOMATIONANDcombinationsoftheseelementstogeneratediversityHIGH-THROUGHPUTCHEMISTRYarereported(Comb.Chem.HighThroughputScreen.2008,11,587e601).RapidMultistepSynthesi
2、sof1,2,4-OxadiazolesinaSingleContinuousSelectiveMonolithiationofDibromobiarylsMicroreactorSequenceUsingMicroflowSystemsAgeneralmethodforthesynthesisofbis-Selectivemonolithiationofdibromobiarylswithsubstituted1,2,4-oxadiazolesfromreadilyavailableoneequivalentofn-butyllith
3、iumfollowedbythere-arylnitrilesandactivatedcarbonylsinasinglecon-actionwithelectrophilesisachievedbyJ.-I.Yoshidatinuousmicroreactorsequenceisdescribedbyetal.usingamicroflowsystembyvirtueoffastmi-N.D.P.Cosfordetal.Thesynthesisincorporatescromixingandprecisetemperaturecontr
4、ol.Sequen-threesequentialmicroreactorstoproduce1,2,4-oxa-tialintroductionoftwodifferentelectrophilesbaseddiazolesinapproximately30mininquantitiesonthismethodalsoisachievedusingamicroflow(40e80mg)sufficientforfullcharacterizationandsystemcomposedoffourmicromixersandfourmi-r
5、apidlibrarysupply(J.Org.Chem.2009,73,crotubereactors(Org.Lett.2008,10,3937e3940).7219e23).CombinatorialMaterialsResearchAppliedtoExpandingtheChemicalSpaceinPractice:theDevelopmentofNewSurfaceCoatingsX:Diversity-OrientedSynthesisAHigh-ThroughputElectrochemicalImpedanceSpe
6、ctroscopyMethodforDiversity-orientedsynthesis(DOS)aimstoScreeningOrganicCoatingsforCorrosionbroadenthefrontierofaccessiblecollectionsofInhibitioncomplexanddiversesmallmolecules.M.Peuch-maurandY.-S.WongdissecttheDOSconceptJ.Heetal.reportahigh-throughputelectrochem-through
7、threeelementsofdiversity:buildingblock,icalimpedancespectroscopy(HT-EIS)methodforstereochemistry,andskeleton.Recentexamplesinrapidandquantitativeevaluationofcorrosionpro-theliteraturethatemphasizetheefficienttectivecoatings.A12-element,spatiallyaddressableelectrochemicalpl
8、atformhasbeendesigned,fabri-Correspondence:HilmarWeinmann,Ph.D.,BayerScheringPharmacated,andvalidated.T
