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1、©2000TobyBroomNopartofthisdocumentmaybereproducedormodifiedwithouttheexpresspermissionofTobyBroom.tbroom@totalise.co.ukAbbreviationFullNameSomeUsesStructuresAcAcetylVerycommonprotectingOgroupforalcoholsandRphenolsAdAdamantylProtectinggroupforacids,RthiolsandalcoholsADAsymmetricd
2、ihydroxylationOOsO4+NMO+OHOOHHNClHONAEAsymmetricepoxidationSharplessConditionsEtO2CCO2EttBuOOH+Ti(OiPr)OHO4+HOHOHHOHAIBN?,?'-AzoisobutyronitrileMakesradicalsNCNNCNAldrithiol®2,2'-DipyridyldisulphideThiolatingReagentNSSNAllAllylProtectinggroupforphenols,acidsandalcoholsRespeciall
3、ycarbohydratesAllocAllyloxycarbonylProtectinggroupforRalcohols,aminesOO9-BBN9-BorabicyclononaneHinderedreductantBBNHBBMSBorane-methylsulphidecomplexReducingagentBH3SMe2BINAP2,2'-Bis(diphenylphosphino)-1,1'-LigandforRucatalyticbinapthylhydrogenationandBuchwaldreactionPPh2PPh2BINA
4、POPhosphinousacid,diphenyl-[1,1'-LigandforRucatalyticbinapthalene]-2-2'-diylesterhydrogenationOPPh2OPPh2Boctert-ButoxycarbonylProtectinggroupforaminesOespeciallypeptidesROBOMBenzyloxymethylProtectinggroupforRalcohols,phenols,acidsOandaminesBOPBenzotriazol-1-Peptidecouplingreagen
5、tNyloxytris(dimethylamino)phosphonNPNiumhexafluorophospateNNPF6N©2000TobyBroomNopartofthisdocumentmaybereproducedormodifiedwithouttheexpresspermissionofTobyBroom.tbroom@totalise.co.ukBOP-ClBis(2-oxo-3-PeptidecouplingreagentOoxazolidinyl)phosphinicchlorideNPNOOClOOBnBenzylProtect
6、inggroupforRalcohols,phenols,acids,amides,aminesandcarbonylsBrBrosylate,ActivatinggroupforOBromobenzenesulphonylalcoholsBrSROBTAFBenzyltrimethylammoniumFluoratingreagentfluorideNFBumt-butoxymethylProtectinggroupforROamines,alcoholsBzBenzoylProtectinggroupforthiols,ORalcohols,phe
7、nolsmuchmorestablethanacetateBHTtert-ButylhydroxytolueneStablizerforethersOHCANCericammoniumnitrateOxidisingagent(NH4)2[Ce(NO2)6]CBSCorey-Bashki-ShibatChiralreducingagentforPhPhcarbonylsNO+BH3BHCbzorZBenzyloxycarbonylVerycommonprotectingRgroupforaminesespeciallyOOinaminoacidsCOD
8、CyclooctadieneLigandfortransitionmetalcatalysts
