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1、©2000TobyBroomNopartofthisdocumentmaybereproducedormodifiedwithouttheexpresspermissionofTobyBroom.tbroom@totalise.co.ukAbbreviationFullNameSomeUsesStructuresAcAcetylVerycommonprotectingOgroupforalcoholsandRphenolsAdAdamantylProtectinggroupforacids,Rthiolsanda
2、lcoholsADAsymmetricdihydroxylationOOsO4+NMO+OHOOHHNClHONAEAsymmetricepoxidationSharplessConditionsEtO2CCO2EttBuOOH+Ti(OiPr)OHO4+HOHOHHOHAIBN?,?'-AzoisobutyronitrileMakesradicalsNCNNCNAldrithiol®2,2'-DipyridyldisulphideThiolatingReagentNSSNAllAllylProtectinggr
3、oupforphenols,acidsandalcoholsRespeciallycarbohydratesAllocAllyloxycarbonylProtectinggroupforRalcohols,aminesOO9-BBN9-BorabicyclononaneHinderedreductantBBNHBBMSBorane-methylsulphidecomplexReducingagentBH3SMe2BINAP2,2'-Bis(diphenylphosphino)-1,1'-LigandforRuca
4、talyticbinapthylhydrogenationandBuchwaldreactionPPh2PPh2BINAPOPhosphinousacid,diphenyl-[1,1'-LigandforRucatalyticbinapthalene]-2-2'-diylesterhydrogenationOPPh2OPPh2Boctert-ButoxycarbonylProtectinggroupforaminesOespeciallypeptidesROBOMBenzyloxymethylProtecting
5、groupforRalcohols,phenols,acidsOandaminesBOPBenzotriazol-1-PeptidecouplingreagentNyloxytris(dimethylamino)phosphonNPNiumhexafluorophospateNNPF6N©2000TobyBroomNopartofthisdocumentmaybereproducedormodifiedwithouttheexpresspermissionofTobyBroom.tbroom@totalise.c
6、o.ukBOP-ClBis(2-oxo-3-PeptidecouplingreagentOoxazolidinyl)phosphinicchlorideNPNOOClOOBnBenzylProtectinggroupforRalcohols,phenols,acids,amides,aminesandcarbonylsBrBrosylate,ActivatinggroupforOBromobenzenesulphonylalcoholsBrSROBTAFBenzyltrimethylammoniumFluorat
7、ingreagentfluorideNFBumt-butoxymethylProtectinggroupforROamines,alcoholsBzBenzoylProtectinggroupforthiols,ORalcohols,phenolsmuchmorestablethanacetateBHTtert-ButylhydroxytolueneStablizerforethersOHCANCericammoniumnitrateOxidisingagent(NH4)2[Ce(NO2)6]CBSCorey-B
8、ashki-ShibatChiralreducingagentforPhPhcarbonylsNO+BH3BHCbzorZBenzyloxycarbonylVerycommonprotectingRgroupforaminesespeciallyOOinaminoacidsCODCyclooctadieneLigandfortransitionmetalcatalysts
