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1、物理化学傅献彩Bibliography:(1)'"physicalchemistry"(fourthedition),fuxiucai,etc・，advaneededucationpress,1990;2)"physicalchemistry，，(thirdedition),wangzhenglie,etc・，advaneededucationpress1988One,theexaminationrequirement:Allanswersarewrittenontheanswersheet,otherwisetheyarenotvalid・Thecon
2、tentsoftheexam:1)thegasp-v-tproperty:A:understandthedifferencebetweentheidealgasmodel,theactualgasandtheidealgasp-v-t・B:masterthestateequationofidealgas,vanderWaalsequation,thepartialpressure,andtheappearanceofthepoints,conceptsandapplications,gasliquefaction,andcriticalnature,cr
3、iticalparameters,contrast,correspondingstateprinciple,thecompressionfactorandsoon.2)thefirstlawofthermodynamics:A:understandingtheconceptsofsystemandenvironment,stateandstateproperties,processesandpaths,reversibleprocesses,workandheat.B:masterthefirstlawofthermodynamics,enthalpy,
4、Cp,Cv,andenthalpy,andtheimportantrelationoftemperaturerelation.SkilledintheprocessofsimplepVT,phasetransition,chemicalreactionprocessQ,W,andcalculation.C:thedesignprocesscomputesthechangeofheat,work,temperature,internalenergyandenthalpyofthecomplexsituation.D:therelationshipbetwe
5、entheenthalpyofchemicalreaction,enthalpyofphasechangeandtemperature,theapplicationofidealgasandthecharacteristicofthrottleprocess.Weknowtheconceptofenthalpy,enthalpy,iongenerationenthalpy.1)thesecondlawofthermodynamics:A:masterthecarnotcycle,theengineefficiencyconcept・It'sgoingto
6、bethecarnotcycleonthep-v,t~s,h-sandsoon.B:understandtheexpression,theessence,thecarnottheorem,andtheinferencesofthesecondlaw.Theconceptofentropy,substance,Statisticalsignificance,Clausiusinequality,entropyincreaseprinciple,entropycriterion,criterion.C:understandthethirdlaw,thecon
7、ceptofentropy,theconceptofstandardentropyanditsnumericalvalue・D:masteringtheprocessofsimplepVT,phasetransition,chemicalreaction,Computation.Tomasterthebasicrelationsofthermodynamics,maxwellrelationsanditsapplication,canGoodenoughtodorelevantproofs・SkilledclapeyronandClausiusclape
8、yronequationFormandapplication.1)multico
