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1、Thethermalconductivityandmechanicalpropertiesofhighlyporouszirconiafelt/ZrO2compositesbyzirconiumoxideprecursorimpregnationJianpingAia,b,GuohongZhoua,*,ZhengjuanWanga,b,HailongZhanga,XianpengQina,b,PengLiua,ShiweiWanga,*aTheStateKeyLaboratoryofHighPerformanceCeramicsandS
2、uperfineMicrostructures,ShanghaiInstituteofCeramics,ChineseAcademyofSciences,1295DingxiRoad,Shanghai200050,PRChinabUniversityofChineseAcademyofSciences,Beijing100049,PRChinaAbstractThevacuumpressureimpregnationmethodwasadoptedtomakebothlowthermalconductivityandhigh-tempe
3、ratureresistanceporouszirconiafelt/ZrO2composites.Incorporatingzirconiafeltintoporouszirconiamatrixtoimprovethemechanicalstrength.Meanwhile,lanthanumnitrateasanadditivetoyttrium-stabilizedzirconiatoreducethethermalconductivityofthematrix.Theeffectofsinteringtemperatureon
4、compressivestrengthandthermalconductivitywereinvestigatedonthebasisofporosity,microstructureandcomposition.Thetetragonalphaseandthecubicphaseco-existedat1450℃,whilethecubicphasepredominatedupon1450℃aszirconiaionswerereplacedbylanthanumandyttriumions.Andtheopenporosityand
5、sizeofsmallporesdecreasedasthesinteringtemperatureincreasedfrom1450to1600℃duetothezirconiagrainsgrewup,adecreaseofopenporosityfrom48.1%to42.5%.Comparedwithothertemperaturesinteredsamples,the1600℃-sinteredsamplesalwaysownedhigherthermalconductivityvalueof0.70~0.78W/(m•K)a
6、tlowertemperature,inversely,possessedlowerthermalconductivityafter800℃.1.IntroductionZirconia-basedceramicshavehighmeltingpoint,excellentmechanicalstrength,lowthermalconductivitycomparedwithotherceramics[1-3].Itisthereforeofinteresttoconsiderthemasthermalprotections.Zirc
7、onia-basedceramicsshowpromiseasthermalbarriercoatings(TBCs)[4-6].TBCsofferadvantageinthermalinsulating,however,theycannotmeetthestrengthrequirementofthermalprotectionswhichrequirenotonlylowthermalconductivitybutalsohighstrength.Therefore,itissignificanttoresearchzirconia
8、-basedceramicsasbulkmaterialswhichmeetboththermalandmechanicalrequirements.Ithasbeenconfirmedthattherma