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1、854J.Electrochem.Soc.:ELECTROCHEMICALSCIENCEJuly1970resultinginanincreaseinilimvalues.Theworkof4.F.H.Verhock,J.Am.Chem.Soc.,52,2693(1930).Epelboin(14,18)inwhichrefrigerationoftheelec-5.T.PavlopoulosandH.Strehlow,Z.phys.Chem.,trodeincreasedtheanodicpotentials
2、suggeststhatan2,89(1954).increaseinilimmightinitselfberesponsibleforfilm6.StandardMethodsofTestingPetroleumProducts,InstituteofPetroleum(1951).breakdownasaresultofincreasedJoule(i2R)heat-7.HandbookofChemistryandPhysics,41stEd.,ing.Theeffectofdecreasingsulfam
3、ateconcentrationCleveland,ChemicalRubberPublishingCo.(Fig.4)inincreasingilimanddecreasingtheanode(1959).voltagescanbesimilarlyexplained.8.A.J.JohnsonandL.L.Shreir,CorrosionSci.,5,269(1965).Acknowledgments9.T.P.Hoar,"ModernAspectsofElectrochemistry,"Theauthor
4、swishtothankProfessorT.K.Rossforp.262,J.O'MBockris,Editor,Vol.2,Butter-theprovisionofresearchfacilitiesandtheScienceRe-worth,London.searchCouncilfortheirsupportandinterestinthis10.M.Halfawy,Experimentia,7,175(1951).work.11.J.Edwards,ThisJournal,100,189C(1953
5、).12.C.Wagner,ibid.,101,225(1954).ManuscriptreceivedJan.20,1970.13.H.F.Walton,ibid.,97,219(1950).AnydiscussionofthispaperwillappearinaDis-14.I.Epelboin,GalvanotechnikuOberfl~chenschutz,cussionSectiontobepublishedintheJune19718,247(1967).JOURNAL.15.E.Darmoisa
6、ndM.I.Epelboin,BullSoc.Franc.DesREFERENCESElectricians,4(Ser7),344(1954).1.I.A.Menzies,D.N.Bulin,andG.W.Marshall,16.P.Delahay,"DoubleLayerandElectrodeKinetics,"Trans.Inst.MetalFinish.,45,122(1967).IntersciencePublishers,Inc,.NewYorkt1966).2.I.A.MenziesandA.F
7、.Averill,EIectrochim.Acta,17.T.P.Hoar,D.C.Mears,andG.P.Rothwell,Cor-13,807(1968).rosionSci.,5,279(1965).3.I.A.Menzies,G.W.Marshall,andG.B.Griffin,18.M.GarreauandI.Epelboin,J.Chim.Phys.,(11-CorrosionSci.,9,287(1969).12),1515(1966).ElectricalPropertiesofMangan
8、eseDioxideandManganeseSesquioxideP.H.Klose*,1UnionCarbideCorporation,ElectronicsDivision,Greenville,SouthCarolinaABSTRACTMeasurementsofelectricalpropertiesofMnO2andMn203werecarriedoutonmaterialo
