Functionalized Carbon Nanotubes Properties and Applications

Functionalized Carbon Nanotubes Properties and Applications

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时间:2019-07-02

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1、Acc.Chem.Res.2002,35,1096-1104FunctionalizedCarbonnanotube-boundcarboxylicacids.Inthefirstcategory,Margrave,Smalley,andco-workersreportedthefluorina-Nanotubes:PropertiesandtionofSWNTs.2,3Invariousalcoholsolvents,thesefunc-tionalizedSWNTsweresolvatedasindividualt

2、ubes,Applicationsmakingitpossibletocarryoutfurthersolutionchemistry.Pekkerandco-workersreportedthehydrogenationofYA-PINGSUN,*KEFUFU,YILIN,ANDcarbonnanotubesviatheBirchreductioninammonia.15WEIJIEHUANGOtherexamplesincludethederivatizationofsmall-diameter(ca.0.7nm)

3、SWNTsreportedbyTourandco-DepartmentofChemistryandCenterforAdvanced13,14workers,theinteractionswithanilinesreportedbyEngineeringFibersandFilms,HowardL.HunterWilsonandco-workers,12thereactionswithnitrenes,ChemistryLaboratory,ClemsonUniversity,Clemson,SouthCarolina

4、29634-0973carbenes,andradicalsreportedbyHirschandco-work-ers,19andthe1,3-dipolaradditionreportedbyPratoandReceivedFebruary1,2002others.20Inthesecondcategoryoffunctionalizationreactions,ABSTRACTthenanotube-boundcarboxylicacidscomefromintrinsicCarbonnanotubescanbe

5、functionalizedviaamidationandes-terificationofthenanotube-boundcarboxylicacids.Thesolubilityorinduceddefects.Thelatterrefertothecreationofofthesefunctionalizedcarbonnanotubesmakesitpossibletoterminalcarbonsintheshorteningofnanotubes,whichcharacterizeandstudythep

6、ropertiesofcarbonnanotubesusinguponoxidationareconvertedtocarboxylicacids.1,21,22solution-basedtechniques.RepresentativeresultsconcerningtheHaddonandco-workersfirstreportedtheuseoftheacidsolubility,dispersion,defunctionalization,andopticalpropertiesgroupsforatta

7、chinglongalkylchainstoSWNTsviaamideofthefunctionalizedcarbonnanotubesarepresented.Severalexamplesfortheuseoffunctionalizedcarbonnanotubesinthelinkages1orcarboxylate-ammoniumsaltionicinterac-fabricationofpolymericcarbonnanocomposites,theprobingoftions.4Sunandco-w

8、orkersshowedthattheesterificationnanotube-moleculeinteractions,andtheconjugationwithbiologi-ofthecarboxylicacidscanalsobeappliedtofunctionalizecalspeciesarehighlighte

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