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1、ChemicalSocietyReviewsMOF-BasedElectronicandOpto-ElectronicDevicesJournal:ChemicalSocietyReviewsManuscriptID:CS-REV-03-2014-000096.R1ArticleType:ReviewArticleDateSubmittedbytheAuthor:23-Apr-2014CompleteListofAuthors:Stavila,Vitalie;SandiaNationalLaboratories,Talin,A.;SandiaNationalLaboratorie
2、s,Allendorf,Mark;SandiaNationalLaboratory,Page1of46ChemicalSocietyReviewsMOF-BasedElectronicandOpto-ElectronicDevicesV.Stavila,A.A.Talin,andM.D.Allendorf*SandiaNationalLaboratories,P.O.Box969,Livermore,California94551-0969,U.S.A.AbstractMetal-OrganicFrameworks(MOFs)areaclassofhybridmaterialsw
3、ithuniqueopticalandelectronicpropertiesarisingfromrationalself-assemblyoftheorganiclinkersandmetalions/clusters,yieldingmyriadsofpossiblestructuralmotifs.Thecombinationoforderandchemicaltunability,coupledwithgoodenvironmentalstabilityofMOFs,arepromptingmanyresearchgroupstoexplorethepossibilit
4、yofincorporatingthesematerialsasactivecomponentsindevicessuchassolarcells,photodetectors,radiationdetectors,andchemicalsensors.Althoughthisfieldisonlyinitsincipiency,manynewfundamentalinsightsrelevanttointegratingMOFswithsuchdeviceshavealreadybeengained.Inthisreview,wefocusourattentionontheba
5、sicrequirementsandstructuralelementsneededtofabricateMOF-baseddevicesandsummarizethecurrentstateofMOFresearchintheareaofelectronic,opto-electronicandsensordevices.WesummarizevariousapproachestodesigningactiveMOFs,creationofhybridmaterialsystemscombiningMOFswithothermaterials,andassemblyandint
6、egrationofMOFswithdevicehardware.Criticaldirectionsoffutureresearchareidentified,withemphasisonachievingthedesiredMOFfunctionalityinadeviceandestablishingthestructure-propertyrelationshipstoidentifyandrationalizethefactorsthatimpactdeviceperformance.1ChemicalSocietyReviewsPage2of46Introductio
7、nDuringthepastdecadeMetal-OrganicFrameworks(MOFs)haveemergedasapromising1-3classofmaterialswithawidespectrumofusefulapplications.MOFsarehybridmaterials,havingbothaninorganicandanorganiccomponent.Theirstructureiscomprisedofmetalionsorclusterst
