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1、Biosurfactant姓名:吕梅玲学号:SY1227111化学与环境学院导师:江雷IntroductionBiosurfactants(amphiphiliccompounds)(synthesizedbymicroorganisms)hydrophobic(nonpolar)hydrophilic(polar)thatconferabilitytoaccumulatebetweenfluidphasessuchasoil/waterorair/water,reducingthesurfaceandinterfacialtensionsandform
2、ingemulsions.household、industryandagriculturemono-,oligo-orpolysaccharides(多糖),peptides(缩氨酸)orproteinssaturated,unsaturatedandhydroxylatedfattyacidsorfattyalcoholsPseudomonasaeruginosa(绿脓假单胞菌)Acinetobactercalcoaceticus(醋酸钙不动杆菌)emulsan(乳化剂)Candidabombicola(假丝酵母菌)sophorolipids(槐糖脂)
3、(Originally)hydrocarbonsdissolutionagentsfood,pharmaceuticalandoilindustry(recently)applicationenvironmentalfriendlyeasilybiodegradablelowtoxicityuniquestructuresRhamnolipids(鼠李糖脂).ClassificationBiosurfactantsarecategorizedbytheirchemicalcomposition,molecularweight,physico-chemic
4、alpropertiesandmodeofactionandmicrobialorigin.Basedonmolecularweighttheyaredividedintolow-molecular-massbiosurfactantsandintohigh-molecular-massbiosurfactants.Oneofthebest-studiedglycolipidsisrhamnolipid,producedbyseveralspeciesofP.seudomonads(假单胞菌),whichconsistsoftwomolesofrhamn
5、oseandtwomolesofβ-hydroxydecanoicacid.Thelowmolecularweightbiosurfactantsaregenerallyglycolipidsinwhichcarbohydratesareattachedtoalong-chainaliphaticacid(脂肪酸)orlipopeptides(脂肽).Glycolipidbioemulsifiers,suchasrhamnolipids(鼠李糖脂),trehaloselipids(海藻糖脂)andsophorolipids(槐糖脂),aredisacch
6、arides(二糖)thatareacylatedwithlong-chainfattyacidsorhydroxyfattyacids.Thehighmolecularweightsurfactantsarelesseffectiveinreducinginterfacialtension,butareefficientatcoatingtheoildropletsandpreventingtheircoalescence.Thesearehighlyefficientemulsifiersthatworkatlowconcentrations(0.0
7、1%–0.001%),representingemulsifier-to-hydrocarbonratiosof1:100–1:1000.Thehighmolecularweightbacterialsurfactantsareproducedbyalargenumberofbacterialspeciesfromdifferentgeneraandarecomposedofpolysaccharides(多糖),proteins,lipopolysaccharides(脂多糖),lipoproteins(脂蛋白)orcomplexmixturesoft
8、hesebiopolymers.otherscanalsoemulsifypur