杂化材料领域的经典之作---Functional Hybrid Materials

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1、FunctionalHybridMaterialseditedbyPedroGómez-Romero,ClémentSanchezVTableofContentsPrefaceXI1HybridMaterials,FunctionalApplications.AnIntroduction1PedroGómez-RomeroandClémentSanchez1.1FromAncientTraditionto21stCenturyMaterials11.2HybridMaterials.TypesandClassification

2、s41.3GeneralStrategiesfortheDesignofFunctionalHybrids61.4TheRoadAhead102Organic-InorganicMaterials:FromIntercalationChemistrytoDevices15EduardoRuiz-Hitzky2.1Introduction152.2TypesofHybridOrganic-InorganicMaterials182.2.1IntercalationCompounds182.2.1.1Intercalationof

3、IonicSpecies202.2.1.2IntercalationofNeutralSpecies232.2.1.3PolymerIntercalations:Nanocomposites252.2.2OrganicDerivativesofInorganicSolids272.2.3Sol-GelHybridMaterials302.3Functions&DevicesBasedonOrganic-InorganicSolids332.3.1SelectiveSorbents,ComplexingAgents&Membra

4、nes332.3.2HeterogeneousCatalysts&SupportedReagents362.3.3Photoactive,OpticalandOpto-ElectronicMaterials&Devices382.3.4ElectricalBehaviors:Ionic&ElectronicConductors412.3.5Electroactivity&ElectrochemicalDevices422.4Conclusions443BridgedPolysilsesquioxanes.Molecular-E

5、ngineeringNanostructuredHybridOrganic-InorganicMaterials50K.J.Shea,J.Moreau,D.A.Loy,R.J.P.Corriu,B.Boury3.1Introduction503.2HistoricalBackground533.3MonomerSynthesis53VITableofContents3.3.1Metallation543.3.2Hydrosilylation543.3.3FunctionalizationofanOrganotrialkoxys

6、ilane553.3.4OtherApproaches563.4Sol-GelProcessingofBridgedPolysilsesquioxanes583.4.1HydrolysisandCondensation583.4.2Gelation593.4.3AgingandDrying623.5CharacterizationofBridgedPolysilsesquioxanes623.5.1PorosityinBridgedPolysilsesquioxanes643.5.2PoreSizeControl653.5.3

7、PoreTemplating663.6InfluenceofBridgingGrouponNanostructures683.6.1SurfactantTemplatedMesoporousMaterials683.6.2MesogenicBridgingGroups683.6.3SupramolecularOrganization703.6.4MetalTemplating713.7ThermalStabilityandMechanicalProperties713.8ChemicalProperties723.9Appli

8、cations733.9.1OpticsandElectronics743.9.1.1Dyes743.9.1.2Nano-andQuantumDotsinBridgedPolysilsesquioxanes753.9.2SeparationsMedia753.9.3Catal