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1、混炼器加工的聚合物结构与性能分散相尺寸的控制特殊设备中的混合形态Pan-MillingMiniaturemixersMINI-MAXMolder无机填料对形态的影响加工的影响因素SheetFormationSundararajU,DoriY,MacoskoCW.Polymer,1995,36:1957theeffectofviscosityratioforchangingPPviscosityeffectofshearratePP3050/PS666DPan-millingmixingMorphologyof:(a
2、)PP/PA6(80/20,w/w)blend;(b)PP/PA6mouldedfrommixedPP/PA6(80/20,w/w)powderpan-milledfor20cycles.FTIRspectraof:(a)PP;(b)PPextractedfromPP/PA6(80/20,w/w)compoundpowderpan-milledfor10cycles;(c)PP/PA6(80/20,w/w)compoundpowderpan-milledfor20cyclesZheChen,Q.W.(2001)."
3、Pan-millingmixing-anovelapproachtoformingpolymerblendsandcontrollingtheirmorphology.PolymerInternational50(9):966-972.Pan-millingmixingZheChen,Q.W.(2001)."Pan-millingmixing-anovelapproachtoformingpolymerblendsandcontrollingtheirmorphology.PolymerInternational5
4、0(9):966-972.MeltMixingofPolycarbonatewithMulti-WalledCarbonNanotubesTEMmicrographsofPC/MWNTpreparedfromAPAM(a,d,g,j),MBM(b,e,h,k)andDACA(c,f,i,l).MWNTcontentis0.50wt.-%in(a),(b)and(c);0.75wt.-%in(d),(e)and(f);1.00wt.-%in(g),(h)and(i);and1.25wt.-%in(j),(k)and(
5、l).BinLin,U.S.P.P.(2006)."MeltMixingofPolycarbonatewithMulti-WalledCarbonNanotubesinMiniatureMixers.MacromolecularMaterialsandEngineering291(3):227-238MeltMixingofPolycarbonatewithMulti-WalledCarbonNanotubes(a)AFMmicrographs(left:heightimage;right:amplitudeima
6、ge)ofMWNTrecoveredaftermixingfromtheAPAM;(b)lengthdistributionoftheMWNTrecoveredaftermixingintheAPAM.MWNTwererecoveredfromacompositewith0.75wt.-%MWNTbydissolvingPCComparedtotheoriginallengthof10–15nmImprovementofagram-scalemixer(a)MINI-MAXMolderCS183MMX;(b)mel
7、tmixingwithTeflondiskandsteelballsPP/HIPS70/30MixingConditionsandAverageParticleSize(D)AfterMixingat180°Cfor5minSettingTeflonDiskandAddingSmallSteelBalls;NumberofBallsWasVariedBinYang,M.S.T.K.T.I.(2006)."Improvementofagram-scalemixerforpolymerblending.Journalo
8、fAppliedPolymerScience99(1):1-5.减小混炼器加工的聚合物结构与性能分散相尺寸的控制特殊设备中的混合形态无机填料对形态的影响NanoclayCarbonNanotube加工的影响因素Nanoclay-InducedMorphologyDevelopmentOpticalimagesofsurvivingPPCLfibrilsaft