水性纳米复合涂料的制备及其耐刮伤性研究

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1、PreparationandScratchResistantPropertiesofWaterborneNanocompositeCoatingThesisSubmittedtoFudanUniversityforMaster’SDegreeofEngineeringByChenSongwei(DepartmentofMaterialsScience)Supervisor：AssociateProfessorBoYouProfessorLimin肋May,2009目录lIll1IllllEl[1llllIII＼1967085摘要········

2、·······················································IAbstract···························································II第——章绪_}《≥·······················································11．1涂料概述·········································-·············l1．2水性涂料发展现状···········

3、····································21．2．1水性聚氨酯涂料·······-·····-·····························．21．2．2水性环氧树脂涂料·········································q1．2．3水性紫外光固化涂料·······································^41．2．4水性丙烯酸酯涂料·············--······-····················51．3纳米粒子在涂料中的应用·

4、················-·······················51．4纳米复合涂料的制备·············································61．4．1制备方法·················································62．3．3纳米A1203改性的环氧清漆·································252．4本章结论-····-·········-·········一··························-27参

5、考文献·····················一一一一一一一一·····一一一一．．一····．29第三章纳米二氧化硅改性环氧清漆··································303．1引言············-·········一“一“一一．．”一一一一一一一一·一-303．2实验部分····-················-································303．2．1原材料·············································-····"30

6、3．2．2GPTMS改性纳米Si02粒子的制备······················-····3l3．2．3环氧／Si02纳米复合涂料的制备·-···························313．2．4表征方法················································-323．3结果与讨论···················-································333．3．1GPTMS改性纳米Si02·······························

7、······333．3．2环氧／纳米Si02复合涂层的耐刮伤性及光泽······-············353．3．3‘环氧／纳米Si02复合涂层的透明性····················-······"363．3-4纳米刮擦实验····························-···············-383．3．5动态力学分析·········································-···383．4本章结论····-···················-···················

8、··········39参考文献··················································一一··一"40第