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ID:36559036
大小:3.04 MB
页数:79页
时间:2019-05-12
《锂离子电池正极材料锂锰氧的研制》由会员上传分享,免费在线阅读,更多相关内容在行业资料-天天文库。
1、昆明理工大学硕士学位论文锂离子电池正极材料锂锰氧的研制姓名:姚耀春申请学位级别:硕士专业:有色金属冶金指导教师:戴永年;杨斌20030510垦堕型.!.查兰!坚:!:堂垡丝塞垫茎却增大,粒度小且分布范围窄的材料有利于键离子的扩散。在合成材料的同时,本文还对锂离子电池的组成和制作工艺进行了探讨,分析了制浆、涂布、装配、化成几个主要工序对电池性能的影响,还重点对锂离子电池正极各物质的配料进行了优化研究。结果表明,正极极片中PVDF粘接剂和乙炔黑导电剂的添加量只有适量的时候,正极极片的充放电性能才较好。本研究中PVDF粘结剂的添加量在7~10%,
2、乙炔黑导电剂的添加量在8%左右,正极极片的性能最佳。关键词:锂离子电池、正极材料、尖晶石LiMm0。II宣型堡竖生壁墅坠兰燮苎塑耋AbstractWiththerapiddevelopmentofelectronicfacilitiesaswellasenergyandenvironmentalconcerns,peopiehavemadehighdemandsonbatteries.Li—ionbatteriesarewidelyusedfortheirfavorableadvantagesofhighvoltage,bigspecifi
3、ccapacity,longcyclinglifeandnon—pollution.TransitionmetaloxideswithhighinsertedpotentialareusedaScathodematerialofLi—ionbatteriesgeneralty.Atpresent,layeredcompoundsLiCoO?,LiNi02andspinelLiMn204areextensivelystudied.However,theapplicationofconlmercializedLiCoO.iSlimiteddue
4、tothelacknessandhighexpenseofrawmaterialCo,especiallyinpowerbatteryandlarge—scaleenergystoragedevice.TheindustrializationofLiNiOIcannotcometrue,becausetheconditionsofcontrolareoutofreachONpreparation.SpinelLiMn204isconsideredasthemostpromisingpositivematerialforLi—ionbatte
5、riesbecauseofitshighvoltage,highsafety。lowcost,easyrecycleandenvironmentalaffinity.BasedonsummarizingLi—ionBatteries,somepertinentdataandlookingintothestatusquoaboutspinelLi}dnz0。researchathomeandabroad,it’Sknownthatthedeficiencyofthematerial1iesininhomogenelty,motleyphase
6、.instabilityaswellaspoorreversibility.Now,manystudiesandmethods,suchaSsol-gel,welt—impreghationandPechinimethod,etc,havebeenmakingtosynthesizeLiMn,O·cathodematerialbyreserchers.Tosomeextent,thepropertiesofthematerialareimproved.Nevertheless,thesemethodsarenot一蛉ed.formass’p
7、roductionbecauseofcomplicatedtechnicsorhi咖cos%rSotheemphasisofourinvestigationsiStodevelopatechnicswhichcanbothbefitforindustrializationandsynthesizespinelLiMn204withexcellentelectrochemicalcharaeteristlcs.Foradaptingtotheneedot’industrializationandimprovingthepropcrticsof
8、materials.themethodofmechanicalac£jvatioahasintroducedonthebasiSoftraditionalcalcinations
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