丁酮肟应用的相关基础研究及其产业链设想

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1、浙江大学化学工程与生物工程学系硕士学位论文丁酮肟应用的相关基础研究及其产业链设想姓名：郑博予申请学位级别：硕士专业：应用化学指导教师：何潮洪20100101AbstractInthisthesis，thestate-of-artreviewfortheapplicationofmethylethylketoximewasgiven．Densitiesandviscositiesofbinarymixturescontainingmethylethylketoximeweremeasured．Methyltri(methylethyl

2、ketoxime)silanewaspreparedandthesynthesisprocesswasinvestigated．Aproductchainbasedonthestrategyofcirculareconomywasproposedformethylethylketoximeindustry．Themaincontentsareasfollows：1．Densitiesandviscositiesofmethylethylketoximewithmethylethylketone，cyclohexaneand玎一hex

3、aneweremeasuredat293．15K，298．15Kand303．15K．Grunberg—NissanequationandEyring—UNIQUACequationwereusedtocorrelatetheexperimentalviscositydata．Inaddition，theviscositydeviationAt／andexcessGibbsfreeenergyofactivationforviscousflowAG”werecal．culated．2．Areliableanalysismethodo

4、fmethyltri(methylethy’lketoxime)silaneusinggaschromatographywasproposed．Chlorosilanewasemployedtopreparemethyltri(methylethylketoxime)silane．Theeffectsofreactiontime，temperature，ratioofrawmaterial，injectingrateofchlorosilaneandthetypeofsolventonyieldofactivecompoundsan

5、dselectivityofmethyltri(methylethy7lketoxime)silanewereinvestigated，andthesynthesisprocesswasoptimized．3．Consideringthepresentsituationofmethylethylketoximeindustry,theproductchainformethylethylketoximewasdesignedadoptingthestrategyofcirculareconomy,wheresulfurdioxidea

6、ndoxynitridesfromwastegaswereusedastherawmaterials．Theprospectoftheproductchainwasalsodiscussed．Keywords：Methylethylketoxime，Viscosity,Density,Methyltri(methylethylketoxime)silane，Synthesisprocess，Circulareconomy,ProductchainIII缩写、符号清单和术语表口驴彳A,4D％Aae。mxoAby_pn妇tbfBdi2△

7、G忸MEKMEKO挖NPPECgf△Q△Qcalcd＆Qex哦lnR尺丁ySfor矾UNIQUACVMTCSvsiK％。XfJ，Z聊Aq印f，cacldrh．exptl目pIPw盯Erying—UNIQUAC方程相互作用参数Andrade方程拟合参数平均标准偏差气相谱图中甲基三丁酮肟基硅烷的峰面积，：zV．s气相谱图中副产物的峰面积，izVos多项式拟合参数，g·cm。Andrade方程拟合参数Grtmberg．Nissan方程参数过量Gibbs流动自由能，J-mol。1丁酮一MethylEthylKetone丁酮肟-MethylE

8、thylKetoneOxime多项式拟合级数实验点脉冲萃取塔．PulsedPackedExtractionColumn组分i的vailderWaals表面积待计算的过量性质拟合回归所得计算值实验数据算得过量性质组分i的vanderWa