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1、MaterialsScience(材料科学):involvesinvestigatingtherelationshipsthatexistbetweenthestructuresandpropertiesofmaterials(研究结构与性能之间的关系)MaterialsEngineering(材料工程):designingorengineeringthestructureofamaterialtoproduceapredeterminedsetofproperties,basedonthesestructure-propertycorrelations.(设计材料结构以产生预定的
2、性能)Macroscopic(宏观)Microscopic(微观)Structure(结构)Property(性能):mechanical(机械性),electrical(电性),thermal(热性),magnetic(磁性),optical(光学性),anddeteriorative(失效性)ProcessingandPerformance(加工和性能)ClassificationofMaterials(材料的分类):Basic:metals,ceramics,polymersEngineeringmaterials:composites,semiconductors,biom
3、aterialsBasicEngineeringmaterials2.2Basicconcepts(基本概念)Crystal(晶体)Itissolid.Thearrangementofatomsinthecrystalisperiodic.Incrystallinestructure,theatomsdisplaybothshort-rangeandlong-rangeorder(原子显示短程和长程有序).(metals,manyceramics,andevensomepolymers).CharacteristicofCrystals晶体的特性1.Geometricalshape
4、几何形状2.Fixedmeltingpointandboilingpoint固定的熔点和沸点3.Anisotropy(各向异性):质点在晶格各个方向排列的距离不同而形成Lattice(点阵,晶格)Aninfinitearrayofpointsinspace,inwhicheachpointhasidenticalsurroundingstoallothers(晶体点阵是晶体粒子所在位置的点在空间的排列).Athreedimensionalarrayofpointscoincidingwithatompositions(oratomicspherecenter).一个三维数组与原子的
5、位置(或原子球体中心)相吻合点。CrystalStructure(晶体结构)Itcanbedescribedbyassociatingeachlatticepointwithagroupofatoms.晶体结构=空间点阵+结构基元(原子,分子或集团)2.3Unitcells(单胞)Atomichardspheremodel.原子硬球模型Unitcells(单胞):Thesmallestcomponentofcrystal,whichwhenstackedtogetherwithpuretranslationalrepetitionreproducesthewholecrystal(
6、晶格中最小的结构重复单位)UnitCellDimensions(单胞参数)a,bandcaretheunitcelledgelengths.α,β,andγ,aretheanglesαbetweenbandcβbetweencandaγbetweenaandb2.4CrystalStructures(晶体结构)Threesimplecrystalstructuresare: Face-centeredcubic(面心立方)--FCC Body-centeredcubic(体心立方)--BCCHexagonal-close-packed(六方密堆)--HCPFCCcrystals
7、tructurehasaunitcellofcubicgeometry,withatomslocatedateachofthecornersandcentersofallthecubeface.除8个顶点外,每个面心上有一个阵点.a=b=c,α=β=γ=90oeg:Cu,Al,Au,AgForFCCstructure,atotaloffouratomsareassignedtoagivenunitcell(对FCC结构来说,每个单胞有4个完整的原子)Cornerand