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1、Chem.Rev.2004,104,2127-21982127Transition-Metal-CatalyzedReactionsinHeterocyclicSynthesisItaruNakamuraandYoshinoriYamamoto*DepartmentofChemistry,GraduateSchoolofScience,TohokuUniversity,Sendai980-8578,JapanReceivedAugust12,2003Contents6.2.Carbon-HeteroatomBondFormation21776.2.1.Intramolecula
2、rCouplingReactionwitha21771.Introduction2127Heteroatom2.IntramolecularReactionof1,ö-Dienesand21296.2.2.Amino-HeckReaction2178Enynes:Ring-ClosingMetathesis(RCM)6.2.3.InsertionofC-CUnsaturatedBondss21792.1.Ring-ClosingMetathesisforTotalSynthesis2130CouplingwithHeteroatoms2.2.TandemOlefinMetath
3、esis21306.2.4.SonogashiraCouplingofTerminal21792.3.CatalyticEnantioselectiveOlefinMetathesis2139AlkynesFollowedbyCyclization2.4.EnyneMetathesis21407.IntramolecularReactionofAllylHalides:2180Tsuji-Trost-TypeReaction3.IntramolecularReactionof1,6-Dienes,-Enynes,2140and-Diynes:Cycloisomerization
4、,Tandem7.1.Carbon-CarbonBondFormation2180Addition-Cyclization,andCycloaddition7.2.Carbon-HeteroatomBondFormation21803.1.Cycloisomerization21417.2.1.Stereo-andEnantioselectiveAllylation21803.2.TandemAddition-Cyclization21417.2.2.Intra-andIntermolecularAlkoxyallylation21813.3.Cycloaddition2143
5、ReactionsofAllylCarbonates3.3.1.[2+2+1]-Cycloaddition(Pauson-Khand21437.2.3.Intra-andIntermolecularReactionsof2182Reaction)AlkenylEpoxides,Aziridines,andThiiranes3.3.2.[2+2+2]-Cycloaddition21457.2.4.AmphiphilicAllylationvia21833.3.3.[3+2]-Cycloaddition2146Bis-ð-allylpalladium,andtheReaction3
6、.3.4.[4+2]-Cycloaddition2146throughð-AllylpalladiumAzide3.3.5.[4+2+2]-,[5+2]-,and21477.2.5.Intra-andIntermolecularReactionof2185[6+2]-CycloadditionPropargylEsters4.IntramolecularReactionofAlkenes,Allenes,and21488.Intra-andIntermolecularReactionofDiazo2186AlkynesBearingN-H,O-H,CdO,andCdNCompo
7、undsandIminoiodinanesGroups:Heterocyclization8.1.Carbon-CarbonBondFormation21874.1.Alkenes21498.1.1.IntramolecularReactionofDiazo21874.2.Allenes2151CompoundswithaC-HBond4.3.Methylenecyclopropanes21548.1.2.IntramolecularReactionofDiazo21874.4.Alkyne
