Iron-Catalyzed Reactions in Organic Synthesis.pdf

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1、Chem.Rev.2004,104,6217-62546217Iron-CatalyzedReactionsinOrganicSynthesisCarstenBolm,*JulienLegros,JacquesLePaih,andLorenzoZaniInstitutfu¨rOrganischeChemiederRheinisch-Westfa¨lischenTechnischenHochschuleAachen,Professor-Pirlet-Strasse1,D-52056Aachen,GermanyRecei

2、vedJune24,2004Contents6.1.DoubleBondIsomerizations62426.2.RingRearrangements62431.Introduction62177.Polymerizations62432.AdditionReactions62187.1.EthylenePolymerizationsandRelated62432.1.AldolReactionsandRelatedProcesses6218Processes2.2.MichaelAdditionsandOther

3、Conjugate62207.2.OlefinPolymerizationsviaATRPReactions6244AdditionReactions7.3.OtherPolymerizations62452.3.AllylationsofCarbonylCompoundsand62228.Miscellaneous6246Acetals8.1.SulfideOxidations62462.4.Carbometalations62248.2.SynthesisofSulfoximidesandSulfinimides

4、62472.5.NazarovCyclizations62248.3.NitreneandCarbeneTransferReactionsto62472.6.Barbier-TypeReactions6225Allyl-andPropargylSulfides2.7.AdditionsofHalocarbonstoDoubleBonds62268.4.IntramolecularAminochlorinationofAlkenes6248(KharaschReaction)andAlkynes2.8.Addition

5、byMeansofC-HActivation62288.5.AlkeneDiaminations62482.9.RingOpeningReactions62288.6.AllylicAminations62482.10.AcetalizationsandRelatedProtection62308.7.CyclizationsofChlorodienes6249Methodologies8.8.DealkylationsofTertiaryAmineOxides62493.SubstitutionReactions6

6、2318.9.COInsertions62493.1.ElectrophilicSubstitutions62318.10.Baeyer-VilligerReactions62503.2.NucleophilicSubstitutions62319.Conclusions62503.2.1.SNProcesses623110.Acknowledgments62503.2.2.SRNProcesses623211.NoteAddedinProof62503.3.Cross-CouplingReactions623312

7、.References62503.3.1.AlkenylDerivativesasSubstrates62343.3.2.ArylDerivativesasSubstrates62353.3.3.AlkylDerivativesasSubstrates62363.3.4.AcylDerivativesasSubstrates62361.Introduction3.4.ConversionsofEthersintoAcetates62374.Cycloadditions6237Metalcomplexesareesse

8、ntialinstrumentsinthe4.1.[2+1]-Cycloadditions6237toolboxoforganicchemists.Thecurrentrequire-4.2.[2+2]-Cycloadditions6238mentsforclean,fast,efficient,andselectiveprocesses4.3