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1、ThispageintentionallyleftblankStructureandBondinginCrystallineMaterialsOneofthemotivatingquestionsinmaterialsresearchtodayis:howcanelementsbecombinedtoproduceasolidwithspecifiedproperties?Onepartoftheanswertothisquestionliesinthefundamentalrelationshipbetweenthecompositi
2、on,structureandbondingincrystallinematerials.Thisbookisintendedtoacquaintthereaderwithestablishedprinciplesofcrystallographyandbondingthatareneededtounderstandthisrelationship.Thebookstartswithanintroductiontoperiodictrendsandthendescribestheatomicstructureofcrystalline
3、solids,theexperimentalinterrogationofcrys-tallinestructure,theoriginofthecohesiveforcesthatstabilizecrystallinestruc-tures,andhowthesecohesiveforcesvarywiththeelementsinthesolid.Thebookfinishesbydescribinganumberofmodelsforpredictingphasestabilityandstructure.Containinga
4、largenumberofworkedexamples,exercises,anddetaileddescriptionsofnumerouscrystalstructures,thisbookisprimarilyintendedasanadvancedundergraduateorgraduateleveltextbookforstudentsofmaterialssciencewhoarepreparingtoconductresearch.However,itwillalsobeusefultoscientistsandeng
5、ineerswhoworkwithsolidmaterials.GS.RisaProfessorofMaterialsScienceandEngineeringatCarnegieMellonUniversity.Prof.RohrerwasborninLancaster,PA,in1962.Hereceivedhisbachelor’sdegreeinPhysicsfromFranklinandMarshallCollegein1984andhisPh.D.inMaterialsScienceandEngine
6、eringfromtheUniversityofPennsylvaniain1989.AtCMU,Prof.RohreristhedirectoroftheNSFspon-soredMaterialsResearchScienceandEngineeringCenter.Hisresearchisdirectedtowardunderstandinghowthepropertiesofsurfacesandinternalinter-facesareinfluencedbytheirgeometricandcrystallographi
7、cstructure,theirsto-ichiometry,andtheirdefectstructure.Prof.RohrerisanassociateEditorfortheJournaloftheAmericanCeramicSocietyandhisresearchearnedaNationalScienceFoundationYoungInvestigatorAwardin1994.StructureandBondinginCrystallineMaterialsGREGORYS.ROHRER
8、ThePittBuilding,TrumpingtonStreet,Cambridge,UnitedKingdom