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1、Dr.GerdGemmeckerRoom5333aPhone2-8619e-mailgemmecker@chem.wisc.eduGerd.Gemmecker@ch.tum.deChemistry843"AdvancedNMRSpectroscopy"©GerdGemmecker,1999Thiscoursewillcoverthetheoryrequiredtounderstandandsuccessfullyimplementthemethodsofstate-of-the-artNMRspectroscopy,withthestressla
2、idonstructureelucidationbymultidimensional(essentially2D)NMRtechniques.Whatwillbecovered?ÞIntroductiontotheprinciplesofNMR(includingbuild-upofanNMRspectrometer,generalfeaturesofFouriertransform,relaxation,folding,sensitivityetc.)Þtheoryrequiredfortheunderstandingofimportantex
3、periments(Cartesianproductoperators)Þaselectionofthemostwidely-used2DNMRtechniquesÞinterpretationofthesespectraandwhatnot?ÞquantummechanicaltreatmentofNMR(althoughsomeequationswilloccur!!!)ÞsolidstateNMRÞworkingwithNMRdatabasesÞempiricalcorrelationsforchemicalshifts(increment
4、systems)Whatisrequired?Þknowledgeof1DNMR,Jcouplingpatterns,chemicalshiftetc.,e.g.,Chemistry605or626Þregular(!)attentionofthecourse,sincemost"individualsections"requireanunderstandingofthepreviousones.Þ"re-reading"(and"re-thinking"!)ofthematerialonaregularbasis,andworkingoutyo
5、urownsolutionstotheproblemsgiveninthecoursetomakesurethatyouhavereallygraspedtheconceptsanddevelopedaworkingknowledge!Credits/Grades:Forcredit,areportisrequiredonanaspectofthiscourserelevanttoone'sownresearch,oraresearchproposal.2SomeliteraturerecommendationsMonographs-A.Abra
6、gam"TheprinciplesofNuclearMagnetism",OxfordUniversityPress,1978(6.Auflage),ISBN0-198-51236-9.(physics,verygut&verydifficulttounderstand,the"oldtestament"ofNMR)-R.R.Ernst,G.Bodenhausen,A.Wokaun"PrinciplesofNMRinOneandTwoDimensions",OxfordSciencePubl.1987,ISBN0-198-55647-0.(phy
7、sicalchemistry,veryexact&verydifficult,the"newtestament")-O.W.Sørensen,G.W.Eich,M.H.Levitt,G.Bodenhausen,R.R.Ernst,Progr.NMRSpectrosc.16,163-192(1983).(theoriginalarticleaboutproductoperators,butveryreadable!ifyouskipsomeparagraphs)-R.K.Harris"NuclearMagneticResonanceSpectros
8、copy,APhysicochemicalView",LongmanScientific&Technical1986,ISBN0-582
