资源描述：
《Advanced Materials V22 I37.pdf》由会员上传分享，免费在线阅读，更多相关内容在学术论文-天天文库。
1、www.advmat.dewww.MaterialsViews.comEngineeringHomochiralMetal-OrganicFrameworksforHeterogeneousAsymmetricCatalysisandEnantioselectiveREVIEWSeparationByYanLiu,WeiminXuan,andYongCui*porousmaterialssuchaschiralzeolitesOwingtothepotentialapplicationsintechnologicala
2、reassuchasgasforproducingopticallypureÞnechemi-storage,catalysis,separation,sensingandnonlinearoptics,tremendouscalsviaasymmetriccatalysisandchiralseparationsoverthepastdecades.[5Ð7]Iteffortshavebeendevotedtothedevelopmentofporousmetal-organichasbeenfoundwidespr
3、eadapplicationsframeworks(MOFs)overthepasttenyears.HomochiralporousMOFsareincatalysis,ion-exchange,andseparationparticularlyattractivecandidatesasheterogeneousasymmetriccatalystsandforzeoliteswithregularnanoporousvoidenantioselectiveadsorbentsandseparatorsforpro
4、ductionofopticallyactivespace,[7,8]butnochiralzeolitesareavail-organiccompoundsduetothelackofhomochiralinorganicporousmaterialsableinenantiopureformtodatethoughsuchaszeolites.Inthisreview,wesummarizetherecentresearchprogresstherehavebeenbreakthroughsinthesyn-the
5、sisofzeoliteswithlargerporesbecauseinhomochiralMOFmaterials,includingtheirsyntheticstrategy,distinc-ofhigh-temperaturecalcination,whichtivestructuralfeaturesandlatestadvancesinasymmetricheterogeneousisnecessaryforremovalofthesurfactantcatalysisandenantioselectiv
6、eseparation.templatestogeneratetheporousarchitec-tureofthezeolite,inevitablydestroysthechiralityofthealuminosilicateÐsurfactant1.Introductionassemblies.[8,9]Theresultingachiralorracemiczeolitescannotbeexploredforenantioselectiveseparationsandcatalysis.ThisChiral
7、ityhasbecomeincreasinglysigniÞcantinmanyÞeldshaspromptedexplorationofnewstrategiesforthesynthesissuchaspharmaceutics,chemicalindustry,agricultureandclin-ofhomochiralporousmaterialsthatmayÞndapplicationsinicalanalysis.[1]Evenforenantiomersofthesamesubstance,itena
8、ntioselectiveprocess.hasbeenprovedtobehavedifferentlyinthebodyorenviron-MetalÐorganicframeworks(MOFs)alsoknownascoordi-ment,ortobetotallydifferentmetabolicproductsint
