紫外过硫酸盐氧化除嗅并控制消毒副产物生成的效能研究

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1、ঊ༛ᆖս䇪᮷㍡ཌ/䗽⺡䞮ⴆ≝ौ䲚௻ᒬ᧝࡬⎾∈ࢥӝ⢟⭕ᡆⲺ᭾㜳⹊ガREMOVALOFODOR-COMPOUNDSANDCONTROLOFDISINFECTIONBYPRODUCTFORMATIONBYUV/PERSULFATEOXIDATION䉒呿䎵૾ቊ┞ᐛѐཝᆜ2015ᒤ6ᴸഭ޵മҖ࠶㊫ਧ˖TU991.2ᆖṑԓ⸱˖10213ഭ䱵മҖ࠶㊫ਧ˖628.162ᇶ㓗˖ޜᔰᐕᆖঊ༛ᆖս䇪᮷㍡ཌ/䗽⺡䞮ⴆ≝ौ䲚௻ᒬ᧝࡬⎾∈ࢥӝ⢟⭕ᡆⲺ᭾㜳⹊ガঐ༡⹊ガ⭕˖䉒呿䎵ሲᐾ˖傜ߋᮉᦸ⭩䈭ᆜփ˖ᐕᆖঊ༛ᆜ〇˖ᐲ᭯ᐕ〻ᡶ൞ঋփ˖ᐲ᭯⧟ຳᐕ〻ᆖ䲒ㆊ䗟ᰛᵕ˖2015ᒤ6ᴸᦾҾᆜփঋփ˖૸ቄ

2、┘ᐕъབྷᆖClassifiedIndex˖TU991.2U.D.C.˖628.162DissertationfortheDoctorDegreeinEngineeringREMOVALOFODOR-COMPOUNDSANDCONTROLOFDISINFECTIONBYPRODUCTFORMATIONBYUV/PERSULFATEOXIDATIONCandidateφXiePengchaoSupervisorφProf.MaJunAcademicDegreeAppliedforφDoctorofEngineeringSpecialityφMunicipalEng

3、ineeringSchoolofMunicipal.&Environ.Affiliation:Eng.DateofDefenceφJun,2015Degree-Conferring-InstitutionφHarbinInstituteofTechnology᪈㾱᪎㾷௵ણ⢙䍘⭡Ҿ䰸٬⎃ᓖ䶎ᑨվˈ䳮ԕ㻛ᴹ᭸৫䲔㘼࿻㓸ᱟ侞⭘≤༴⨶Ⲵ䳮仈DŽ↔ཆˈᇼ㩕ޫॆ≤փ䙊ᑨਜ਼ᴹབྷ䟿Ⲵᴹᵪ⢙ˈ䜘࠶ᴹᵪ⢙䳮ԕ㻛ᑨ㿴Ⲵ侞⭘≤༴⨶ᐕ㢪৫䲔ˈᒦ൘≟ॆ⎸∂ᰦ⭏ᡀ⎸∂࢟ӗ⢙˄DBPs˅䘋㘼ডᇣ侞⭘≤ᆹޘDŽഐ↔ˈᔰਁਟԕ儈᭸䲔௵ᒦ߿ቁਾ㔝≟ॆ⎸∂ᰦ࢟ӗ⢙⭏ᡀⲴᢰᵟሩ؍䳌侞⭘≤ᆹޘާᴹ䟽㾱Ⲵ᜿ѹ

4、DŽᵜ⹄ウᔰਁҶ㍛ཆ/䗷⺛䞨ⴀ˄UV/PS˅儈㓗≗ॆփ㌫৫䲔≤ѝ2-⭢สᔲ㥘䞷˄2-MIB˅઼൏㠝㍐˄GSM˅䘉є⿽㠤௵⊑ḃ⢙ᒦ߿ቁਾ㔝≟ॆ⎸∂䗷〻ѝDBPs⭏ᡀⲴᢰᵟDŽUV/PS儈㓗≗ॆփ㌫ਟԕᴹ᭸䱽䀓2-MIB઼GSMˈަ䱽䀓2-MIB઼GSMⲴ᭸㜭䲿⵰PSࡍ࿻ᣅ䟿Ⲵ໎儈㘼໎ᕪ˗pH٬н㜭ⴤ᧕ᖡ૽UV/PSփ㌫䱽䀓2-MIB઼GSMⲴ᭸㜭ˈնᱟྲ᷌փ㌫޵ਜ਼ᴹ⼧䞨ṩᰦˈ2-MIB઼GSMⲴ৫䲔⦷൘䞨ᙗᶑԦлᴤ儈˗2-MIB઼GSM൘UV/PSփ㌫޵Ⲵ䱽䀓᭸㜭ࠐѾ−−нਇ৽ᓄ⑙ᓖǃ≟⿫ᆀ˄Cl˅઼⺍䞨ṩ⿫ᆀ˄NO3˅Ⲵᖡ૽˗䟽⻣䞨ṩ−˄HCO3˅઼ཙ❦ᴹᵪ⢙˄N

5、OM˅ᱟᇎ䱵≤փѝᣁࡦUV/PSփ㌫䱽䀓2-MIB઼GSMⲴѫ㾱ഐ㍐DŽԕ2-MIB઼GSMѪⴞḷ⊑ḃ⢙ˈ䙊䗷っᘱٷ䇮ᔪ・ҶUV/PS儈㓗≗ॆփ㌫䱽䀓≤փѝᗞ⊑ḃ⢙Ⲵࣘ࣋ᆖ⁑රˈᒦ傼䇱Ҷ䈕⁑ර൘н਼PSᣅ䟿ǃн−਼pH٬лⲴਟ㹼ᙗ˗↔ཆˈᖃփ㌫޵ਜ਼ᴹ⭢䞷ǃ਄б䞷ǃHCO3઼NOMᰦˈ䙊䗷⁑ර䇑㇇ᗇࠪⲴ2-MIB઼GSM䱽䀓Ⲵᤏа㓗䙏⦷ᑨᮠӖоᇎ傼㔃᷌⴨੫ਸDŽєњ≤ল└⊐ࠪ≤㻛⭘ᶕ傼䇱⁑ර൘ᇎ䱵≤փѝⲴਟ㹼ᙗDŽ••−•UV/PSփ㌫н㜭ⴤ᧕ӗ⭏HOˈն⭡ҾSO4о≤৽ᓄਟԕ⭏ᡀHOˈഐ•−•↔UV/PSփ㌫䱽䀓2-MIB઼൏㠝㍐ᰦˈSO4઼HO൷ਁᥕ⵰䟽㾱֌⭘DŽᖃ

6、փ−•−•㌫޵ਜ਼ᴹަԆᴹᵪ⢙˄⭢䞷ᡆ਄б䞷˅ǃHCO3ᡆNOMᰦˈSO4઼HOⲴっ•ᘱ⎃ᓖ൷䲿⵰䘉㊫⢙䍘⎃ᓖⲴ໎儈䗵䙏䱽վ˗⭡Ҿ䘉㊫⢙䍘ㄎҹHOⲴ㜭࣋ᴤ•−••ᕪˈф䘈ਟԕ䙊䗷ㄎҹSO4ᣁࡦHOⲴ⭏ᡀˈഐ↔HOⲴ䍑⥞൘䘉㊫⢙䍘ᆈ•−൘ᰦ䱽վⲴᑵᓖ䘌䘌བྷҾSO4ˈᒦᴰ㓸ሬ㠤UV/PSփ㌫䱽䀓ᇎ䱵≤փѝⲴ2-•−MIB઼൏㠝㍐ᰦˈSO4ᱟ䱽䀓⊑ḃ⢙Ⲵѫ㾱⍫ᙗ㠚⭡สDŽUV/PS儈㓗≗ॆփ㌫ሩNOM൘≟ॆ䗷〻ѝ⭏ᡀDBPsⲴᖡ૽䖳ሿˈަѝਜ਼≞⎸∂࢟ӗ⢙˄N-DBPs˅Ⲵ⭏ᡀ䟿൘UV/PSփ㌫≗ॆਾᴹᡰ䱽վDŽ䲿⵰≗ॆᰦ䰤Ⲵᔦ䮯ˈй≟䟋˄CH˅઼ঔԓ䞞˄HKs˅൘≟ॆ⎸∂

7、䗷〻ѝⲴ⭏ᡀ䟿੸⧠ࠪ໎儈ਾ䱽վⲴ䎻࣯ˈ㘼Ҽ≟㝸˄DCAN˅઼й≟⺍ส⭢✧-I-૸ቄ┘ᐕъབྷᆖᐕᆖঊ༛ᆖս䇪᮷˄TCNM˅Ⲵ⭏ᡀ䟿ࡉ੸⧠ࠪ䱽վਾ໎儈Ⲵ䎻࣯DŽਜ਼⻣⎸∂࢟ӗ⢙˄C-DBPs˅Ⲵ⭏ᡀ䟿䲿⵰PSᣅ䟿Ⲵ໎࣐⮕ᴹ໎࣐ˈ㘼N-DBPsⲴ⭏ᡀ䟿ࡉ൘аᇊ−ᣅ䟿л⮕ᴹ䱽վDŽUV/PSփ㌫≗ॆⲴpH٬઼ޡᆈNO3ሩDBPsⲴ⭏ᡀ䟿ᰐᱮ㪇ᖡ૽DŽᖃNOMⓦ⏢ѝਜ਼ᴹ0.5mg/L≘ᰦˈUV/PSփ㌫≗ॆ亴༴⨶ਟԕᱮ㪇ᣁࡦਾ㔝≟ॆ䗷〻ѝDBPsⲴ⭏ᡀ˗㘼ᖃᡰᴹ㠚⭡≟൷㻛䖜ॆѪ≟㜪ᰦˈཊᮠDBPsⲴ⭏ᡀ䟿൘㓿䗷UV/PSփ㌫亴༴⨶ਾᴹᡰॷ儈ˈնй≟㝸˄TCAN˅઼TCNMⲴ⭏ᡀ

8、䟿൷䱽վDŽᖃⓦ⏢ѝਜ਼ᴹⓤ⿫ᆀᰦˈ≟ॆ䗷