Supported N-heterocyclic carbene complexes in catalysis.pdf

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1、CoordinationChemistryReviews251(2007)860873ReviewSupportedN-heterocycliccarbenecomplexesincatalysisWilliamJ.Sommer,MarcusWeck∗SchoolofChemistryandBiochemistry,GeorgiaInstituteofTechnology,Atlanta,GA30332-0400,USAReceived31May2006;accepted24July2006Availableonline11September2006Co

2、ntents1.Introduction............................................................................................................8601.1.N-Heterocycliccarbeneincatalysis.................................................................................8601.2.Supportedcatalysis.......

3、........................................................................................8612.SupportedRuNHCcomplexes...........................................................................................8622.1.Polymericsupports.................................................

4、...............................................8622.1.1.Insolublepolymers........................................................................................8622.1.2.Solublepolymers.........................................................................................8642.2

5、.Silicasupports....................................................................................................8663.SupportedPdNHC.....................................................................................................8673.1.Polymersupports.......................

6、..........................................................................8673.2.Silicasupports....................................................................................................8704.MiscellaneousNHC................................................................

7、.....................................8715.Conclusions............................................................................................................872Acknowledgements....................................................................................................

8、.872References..........................