Stereochemical and structural characteristics of single- and double-site Pd(II)–N-heterocyclic carbene complexes.pdf

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1、CoordinationChemistryReviews256(2012)1787–1830ContentslistsavailableatSciVerseScienceDirectCoordinationChemistryReviewsjournalhomepage:www.elsevier.com/locate/ccrReviewStereochemicalandstructuralcharacteristicsofsingle-anddouble-sitePd(II)–N-heterocycliccarbenecomplexes:Promisingcatalystsinorga

2、nicsynthesesrangingfromCCcouplingtoolefinpolymerizationsSrinivasaBudagumpi∗,RosenaniA.Haque∗∗,AbbasWasheelSalmanSchoolofChemicalSciences,UniversitiSainsMalaysia,Penang11800,MalaysiaContents1.Introduction.............................................................................................

3、...........................................17882.Scope...............................................................................................................................................17893.Single-sitePd–NHCcomplexes..................................................................

4、..................................................17903.1.Synthesisofsingle-sitePd–NHCcomplexes...............................................................................................17903.2.Imidazole-basedPd–NHCcomplexes...................................................................

5、...................................17903.2.1.Stericandelectroniceffectsoncatalyticproperty...............................................................................17933.2.2.Sulfur-functionalizedPdcomplexes....................................................................................

6、.........17953.2.3.Nitrogen-functionalizedPdcomplexes..........................................................................................17983.2.4.Oxygen-functionalizedPdcomplexes............................................................................................18013.2.5.Phosphor

7、us-functionalizedPdcomplexes.......................................................................................18043.2.6.Ferrocene-tetheredPdcomplexes............................................................................