Graciela Nall Organic Electronics 2011.pdf

Graciela Nall Organic Electronics 2011.pdf

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1、FirstEdition,2011ISBN978-93-81157-27-5©Allrightsreserved.Publishedby:TheEnglishPress4735/22PrakashdeepBldg,AnsariRoad,DaryaGanj,Delhi-110002Email:info@wtbooks.comTableofContentsIntroductionChapter1-Active-MatrixOLEDChapter2-OrganicLight-EmittingDiodeChapter3-OrganicField-EffectTransistorCha

2、pter4-OrganicSolarCellChapter5-HybridSolarCellChapter6-ApplicationsofOrganicElectronicsIntroductionMelaninvoltage-controlledswitch,an"active"organicpolymerelectronicdevicefrom1974.Organicelectronics,plasticelectronicsorpolymerelectronics,isabranchofelectronicsthatdealswithconductivepolymers

3、,plastics,orsmallmolecules.Itiscalled'organic'electronicsbecausethepolymersandsmallmoleculesarecarbon-based,likethemoleculesoflivingthings.Thisisasopposedtotraditionalelectronics(ormetalelectronics)whichreliesoninorganicconductorssuchascopperorsilicon.Polymerelectronicsarelaminarelectronics

4、,acategorythatalsoincludestransparentelectronicpackageandpaperbasedelectronics.Inadditiontoorganicchargetransfercomplexes,technically,electricallyconductivepolymersaremostlyderivativesofpolyacetyleneblack(the"simplestmelanin").Examplesincludepolyacetylene(PA;morespecificiallyiodine-dopedtra

5、ns-polyacetylene);polyaniline(PANI),whendopedwithaprotonicacid;andpoly(dioctyl-bithiophene)(PDOT).HistoryIn1862,HenryLethebyobtainedapartlyconductivematerialbyanodicoxidationofanilineinsulfuricacid.Thematerialwasprobablypolyaniline.Inthe1950s,itwasdiscoveredthatpolycyclicaromaticcompoundsfo

6、rmedsemi-conductingcharge-transfercomplexsaltswithhalogens.Thisfindingindicatedthatorganiccompoundscouldcarrycurrent.Highconductivityof1S/cminlinearbackbonepolymers(inaniodine-"doped"andoxidizedpolypyrroleblack)wasreportedin1963.Likewise,anactualorganic-polymerelectronicdevicewasreportedint

7、hejournalSciencein1974.Thisdeviceisnowinthe"SmithsonianChips"collectionoftheAmericanMuseumofHistory(seefigure).However,AlanJ.Heeger,AlanG.MacDiarmid,andHidekiShirakawaareoftencreditedforthe"discoveryanddevelopment"ofconductivepolymersandwerejointlyawarde

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