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1、StatisticalPhysicsSecondRevisedandEnlargedEditionbyTonyGuénaultEmeritusProfessorofLowTemperaturePhysicsLancasterUniversity,UKAC.I.P.CataloguerecordforthisbookisavailablefromtheLibraryofCongress.ISBN978-1-4020-5974-2(PB)ISBN978-1-4020-5975-9(e-book)PublishedbySpringer
2、,P.O.Box17,3300AADordrecht,TheNetherlands.www.springer.comPrintedonacid-freepaperFirstedition1988Secondedition1995Reprinted1996,2000,2001,2003Reprintedrevisedandenlargedsecondedition2007AllRightsReserved©1988,1995A.M.Guénault©2007SpringerNopartofthisworkmaybereproduc
3、ed,storedinaretrievalsystem,ortransmittedinanyformorbyanymeans,electronic,mechanical,photocopying,microfilming,recordingorotherwise,withoutwrittenpermissionfromthePublisher,withtheexceptionofanymaterialsuppliedspecificallyforthepurposeofbeingenteredandexecutedonacomput
4、ersystem,forexclusiveusebythepurchaserofthework.TableofcontentsPrefaceix1Basicideas11.1Themacrostate11.2Microstates21.3Theaveragingpostulate31.4Distributions41.5Thestatisticalmethodinoutline61.6Amodelexample71.7Statisticalentropyandmicrostates101.8Summary112Distingui
5、shableparticles132.1TheThermalEquilibriumDistribution142.2Whatareαandβ?172.3Astatisticaldefinitionoftemperature182.4Theboltzmanndistributionandthepartitionfunction212.5Calculationofthermodynamicfunctions222.6Summary233Twoexamples253.1ASpin-1solid2523.2Localizedharmoni
6、coscillators363.3Summary404Gases:thedensityofstates434.1Fittingwavesintoboxes434.2Otherinformationforstatisticalphysics474.3Anexample–heliumgas484.4Summary495Gases:thedistributions515.1Distributioningroups515.2Identicalparticles–fermionsandbosons535.3Countingmicrosta
7、tesforgases555.4Thethreedistributions585.5Summary61vviTableofcontents6Maxwell–Boltzmanngases636.1ThevalidityoftheMaxwell–Boltzmannlimit636.2TheMaxwell–Boltzmanndistributionofspeeds656.3Theconnectiontothermodynamics686.4Summary717Diatomicgases737.1Energycontributionsi
8、ndiatomicgases737.2Heatcapacityofadiatomicgas757.3Theheatcapacityofhydrogen787.4Summary818Fermi–Diracgases838.1PropertiesofanidealF