Palladium-Catalyzed Aryl–Aryl Bond Formation Through Double C–H Activation.pdf

《Palladium-Catalyzed Aryl–Aryl Bond Formation Through Double C–H Activation.pdf》由会员上传分享，免费在线阅读，更多相关内容在学术论文-天天文库。

1、TopCurrChem(2010)292:165194DOI:10.1007/128_2009_18#Springer‐VerlagBerlinHeidelberg2009Publishedonline:4December2009Palladium-CatalyzedAryl–ArylBondFormationThroughDoubleC–HActivationShu-LiYouandJi-BaoXiaAbstractArylarylbondformationconstitutesoneofthemostimportantsubje

2、ctsinorganicsynthesis.Therecentlydevelopeddirectarylationreactionsfortheformationofarylarylbondhaveemergedasveryattractivealternativestotraditionalcross-couplingreactions.Particularly,thedirectarylationthroughdoubleCHactivationusingthesimplearenesasbothcouplingpartners

3、isahighlyeconomicandattractivemethod.Inthischapter,therecentprogressofPd-catalyzedarylaryloxidativecouplingreactionsthroughdoubleCHactivationispresented.KeywordsArenelPalladiumlCHactivationlOxidativecouplinglBiarylsynthesisContents1Introduction.........................

4、......................................................1662Pd-CatalyzedArylArylBondFormationviaOxidativeHomocouplingReaction.......1702.1HomocouplingReactionWithoutDirectingGroup.................................1702.2HomocouplingReactionwithDirectingGroup...............

5、......................1723Pd-CatalyzedArylArylBondFormationviaOxidativeCross-CouplingReaction......1753.1Cross-CouplingReactionWithoutDirectingGroup................................1753.2Cross-CouplingReactionwithDirectingGroup....................................1794Pd-

6、CatalyzedIntramolecularArylArylBondFormationviaDoubleCHActivation...............................................................1835ConclusionandPerspective...............................................................1896Experimental:SelectedProcedures...............

7、........................................1916.1SynthesisofCompound2,3-Dimethoxycarbazole[101]............................192References....................................................................................192S.-L.You(*)andJ.-B.XiaStateKeyLaboratoryofOrganom

8、etallicChemistry,ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,345LinglingLu,Shanghai200032,Chinae-mai