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1、物理化学学报(WuliHuaxueXuebao)1062ActaPhys.-Chim.Sin.2016,32(5),1062-1071May[Perspective]doi:10.3866/PKU.WHXB201603231www.whxb.pku.edu.cn下一代能源存储技术及其关键电极材料*杨泽张旺沈越袁利霞黄云辉(华中科技大学材料科学与工程学院,材料成型与模具技术国家重点实验室,武汉430074)摘要:由于能源危机与环境问题,全球能源的消耗正逐渐从传统化石能源转向其它清洁高效能源。高效清洁能源的存储是电动汽车和智能电网的关键技术,对新能源、
2、新材料和新能源汽车国家战略新兴产业的发展具有重要意义。锂离子电池是目前广泛应用的一种能源存储器件。电动汽车和智能电网对能量密度、功率密度、循环寿命和成本等方面的要求越来越高,传统的锂离子电池面临巨大挑战,发展下一代能源存储技术迫在眉睫。高能量密度的锂硫电池和锂空气电池,低成本、高安全性的室温钠离子电池受到了越来越多的关注。本文简要总结了近年来锂硫电池、锂空气电池和钠离子电池及其关键电极材料的研究进展,并对这些新型能源存储技术存在的问题和未来的前景做出了分析和展望。关键词:能源存储;锂硫电池;锂空气电池;钠离子电池中图分类号:O646;TM911Ne
3、xt-GenerationEnergyStorageTechnologiesandTheirKeyElectrodeMaterials*YANGZeZHANGWangSHENYueYUANLi-XiaHUANGYun-Hui(StateKeyLaboratoryofMaterialProcessingandDie&MouldTechnology,SchoolofMaterialsScienceandEngineering,HuazhongUniversityofScienceandTechnology,Wuhan430074,P.R.China)A
4、bstract:Inresponsetoenergyshortagesandenvironmentalconcerns,globalenergyconsumptionistransitioningfromarelianceonfossilfuelstomultiple,cleanandefficientpowersources.Energystorageiscentraltothedevelopmentofelectricvehiclesandsmartgrids,andhencetotheemergingnationallystrategicin
5、dustries.Today,lithium-ionbatteries(LIBs)areamongthemostwidelyusedenergystoragedevicesindailylife,buttheyfaceaseverechallengetomeettherigorousrequirementsofenergy/powerdensity,cyclelifeandcostforelectricvehiclesandsmartgrids.Thesearchfornext-generationenergystoragetechnologies
6、withlargeenergydensity,longcyclelife,highsafetyandlowcostisvitalinthepost-LIBera.Consequently,lithium-sulfurandlithium-airbatterieswithhighenergydensity,andsafe,low-costroom-temperaturesodium-ionbatteries,haveattractedincreasinginterest.Inthisarticle,webrieflysummarizerecentpr
7、ogressinnext-generationrechargeablebatteriesandtheirkeyelectrodematerials,withaparticularfocusonLi-S,Li-air,andNa-ionbatteries.Theprospectsforthefuturedevelopmentofthesenewenergystoragetechnologiesarealsodiscussed.KeyWords:Energystorage;Lithium-sulfurbattery;Lithium-airbattery
8、;Sodium-ionbattery1Introductioncyclelife,highsafety,andlowcos